Thermoplastic/fiber material composites, composite/metallic articles and methods for making composite/metallic articles

• US 20040224590A1
• Filed: 03/31/2004
• Published: 11/11/2004
• Est. Priority Date: 03/31/2003
• Status: Abandoned Application

• Current Assignee: GREENE, TWEED OF DELAWARE, INC.
• Original Assignee: GREENE, TWEED OF DELAWARE, INC.
• Inventors: Rawa, George, Gabriel, Jason F., Toto, Christopher D., Fortunato, Kevin D., Brand, Keith Robert
• Application Number:
  US10/814,523
• Publication Number:
  US 20040224590A1
• Time in Patent Office: Days
• US Class Current: 442/176
• CPC Class Codes: B29C 70/088 and with one or more layers of non-plastics material or non-specified material, e.g. supports
• CPC Class Codes: B29C 70/345 using matched moulds
• CPC Class Codes: B29C 70/885 with incorporated metallic wires, nets, films or plates as lost heating elements B29C35/0272, B29C61/0625
• CPC Class Codes: B32B 15/14 next to a fibrous or filamentary layer
• CPC Class Codes: B32B 2262/106 Carbon fibres, e.g. graphite fibres
• CPC Class Codes: B32B 2305/08 Reinforcements
• CPC Class Codes: B32B 2305/10 Fibres of continuous length
• CPC Class Codes: B32B 2307/734 Dimensional stability
• CPC Class Codes: B32B 2311/00 Metals, their alloys or their compounds
• CPC Class Codes: B32B 2371/00 Polyethers, e.g. PEEK, i.e. polyether-etherketone; PEK, i.e. polyetherketone
• CPC Class Codes: B32B 37/06 characterised by the heating method
• CPC Class Codes: B32B 37/10 characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
• CPC Class Codes: Y10T 442/2959 Coating or impregnation contains aldehyde or ketone condensation product
• CPC Class Codes: Y10T 442/2984 Coated or impregnated carbon or carbonaceous fiber fabric
• CPC Class Codes: Y10T 442/3179 Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
• CPC Class Codes: Y10T 442/3415 Preformed metallic film or foil or sheet [film or foil or sheet had structural integrity prior to association with the woven fabric]

Abstract

Metallic/composite articles and methods for making such articles as well as thermoplastic/fiber material composites are provided herein. Composites include a woven fiber material such as carbon fiber material and a thermoplastic selected from a group consisting of polyarylene ether ketone, polyarylene ether ketone ketone, polyarylene ether ether ketone, and derivatives thereof. Articles include such composites and a base metal, wherein the composite is directly adhered to a first surface of the base metal. Articles may be made by contacting a thermoplastic/fiber material composite with a first surface of a base metal; contacting a release sheet with a top of the thermoplastic/fiber material composite; contacting a first surface of a mold with the release sheet and applying heat and pressure to the thermoplastic/fiber material composite sufficient to directly adhere the thermoplastic/fiber material composite to the first surface of the base metal to form an article; and removing the release sheet from the article.

Claims

1. A composite comprising a continuous fiber material and a thermoplastic, wherein the composite is capable of being directly adhered to a base metal and the composite has a coefficient of thermal expansion substantially the same as a coefficient of thermal expansion of the base metal.

2. The composite according to claim 1, wherein the continuous fiber material is a carbon fiber material.

3. The composite according to claim 2, wherein the carbon fiber material is woven carbon fiber.

4. The composite according to claim 2, wherein the carbon fibers are at least 6 millimeters in length as measured longitudinally.

5. The composite according to claim 1, wherein the woven carbon fiber material is selected from a group consisting of 5-Harness Satin, 2×

2 Twill and plain weave.

6. The composite according to claim 1, wherein the thermoplastic comprises about 70% to about 30% by volume of the composite based on a total volume of the composite.

7. The composite material according to claim 6, wherein the thermoplastic comprises about 60% to about 40% by volume of the composite based on the total volume of the composite.

8. The composite material according to claim 1, wherein the thermoplastic is selected from a group consisting of polyarylene ether ketone, polyarylene ether ketone ketone, polyarylene ether ether ketone, and derivatives thereof

9. An article comprising,

(a) a composite comprising a continuous fiber material and a thermoplastic;

and

(b) a base metal, wherein the composite is directly adhered to a first surface of the base metal and the thermoplastic has a coefficient of thermal expansion substantially the same as a coefficient of thermal expansion of the base metal.

10. The article according to claim 9, wherein the continuous fiber material is a continuous carbon fiber material.

11. The article according to claim 9, wherein the article is selected from the group consisting of a mechanical seal face, thrust bearing pad, a journal bearing, and a segmented journal bearing pad.

12. The article according to claim 9, wherein the thermoplastic is selected from a group consisting of polyarylene ether ketone, polyarylene ether ketone ketone, polyarylene ether ether ketone, and derivatives thereof.

13. A method of making an article, comprising

(a) contacting a thermoplastic/fiber material composite with a first surface of a base metal;

(b) contacting a release sheet with a top of the thermoplastic/fiber material composite;

(c) contacting a first surface of a mold with the release sheet and applying heat and pressure to the thermoplastic/fiber material composite sufficient to directly adhere the thermoplastic/fiber material composite to the first surface of the base metal to form an article; and

(d) removing the release sheet from the article.

14. The method according to claim 13, wherein the thermoplastic is selected from a group consisting of polyarylene ether ketone, polyarylene ether ketone ketone, polyarylene ether ether ketone and derivatives thereof.

15. The method according to claim 13, further comprising preparing the first surface of the base metal and a second surface of the base metal to provide a substantially uniform finish to the first and second surfaces of the base metal prior to step (a).

16. The method according to claim 13, further comprising cutting the thermoplastic/fiber material composite such that it has the same transverse cross section as the first surface of the base metal.

17. The method according to claim 16, wherein the thermoplastic/fiber material composite further has the same transverse cross section as a second surface of the base metal.

18. The method according to claim 13, wherein the mold comprises a second metal.

19. The method according to claim 18, wherein the second metal is the same as the base metal.

20. The method according to claim 13, wherein a transverse cross section of the first surface of the base metal is substantially the same configuration as a transverse cross section of the mold.

21. The method according to claim 13, wherein heat and pressure are applied to the thermoplastic/fiber material composite via a heated press which contacts a second surface of the mold and a second surface of the base metal.

22. The method according to claim 13, wherein the pressure is at least about 60 bars.

23. The method according to claim 13, wherein the heat is applied at a temperature which is at least about 400°

C.

24. The method according to claim 13, further comprising removing the mold, the release sheet and the article from the heat, and cooling the mold, the release sheet and the article, prior to removing the release sheet.

25. The method according to claim 24, wherein the cooling is effected by placing the mold, the release sheet and the article in a cold press such that at least about 60 bars of pressure is applied until the mold reaches a temperature of about 20°

C.

26. The method according to claim 13, wherein the fiber material is a woven carbon fiber material.

27. A composite comprising a fiber material and a thermoplastic, wherein the composite is capable of being directly adhered to a base metal and the composite has a coefficient of thermal expansion substantially the same as a coefficient of thermal expansion of the base metal, wherein the composite is directly adhered to the base metal using compression molding.

28. The composite according to claim 27, wherein the material is a carbon fiber material which is a chopped carbon fiber.

29. The composite according to claim 27, wherein the carbon fiber is continuous carbon fiber material.

30. The composite according to claim 27, wherein the carbon fiber material is continuous woven carbon fiber material.