Process for preparing a diether-based catalyst component

• US 20040235643A1
• Filed: 02/05/2004
• Published: 11/25/2004
• Est. Priority Date: 03/08/2002
• Status: Active Grant

• Current Assignee: Basell Poliolefine Italia Srl (Lyondellbasell Industries NV)
• Original Assignee: Basell Poliolefine Italia Srl (Lyondellbasell Industries NV)
• Inventors: Vitale, Gianni, Morini, Giampiero, Cimarelli, Massimo, Cabrini, Leo
• Granted Patent: US 7,033,970 B2
• Time in Patent Office: Days
• US Class Current: 502/102
• CPC Class Codes: C08F 110/06 Propene
• CPC Class Codes: C08F 2500/12 Melt flow index or melt flow ratio
• CPC Class Codes: C08F 4/651 Pretreating with non-metals or metal-free compounds

Abstract

A process for preparing a diether-based catalyst component in which: a) a slurry is obtained by contacting a solid support comprising a magnesium halide or a precursor thereof, one or more 1,3-diethers and a liquid phase containing a titanium compound, and b) the obtained slurry is then subjected to a solid/liquid separation step in order to isolate a diether-based catalyst component; said separation step b) being characterized in that the ratio between the solid/liquid separation velocity and the final amount of separated solid must be higher than 0.5 liter/(min.Kg).

Claims

1. A process for preparing a diether-based catalyst component comprising steps of:

a) contacting

a solid support comprising a magnesium halide or a precursor thereof, one or more 1,3-diethers and

a liquid phase containing a titanium compound, thereby forming a slurry

b) separating the slurry in a solid/liquid separation step, thereby isolating a diether-based solid catalyst component, wherein the solid/liquid separation step has a solid/liquid separation velocity,

wherein a ratio between the solid/liquid separation velocity and the final amount of the separated solid catalyst component is higher than 0.5 liter/(min.Kg).

2. The process according to claim 1, wherein the ratio between the solid/liquid separation velocity and the final amount of the separated solid catalyst component is in the range from 0.7 to 2 liter/(min.Kg).

3. The process according to claim 1 wherein the separation step b) is carried out by filtration.

4. The process according to claim 3, wherein the filtration is carried out by using filters which are vessels containing one or more filtering units having openings between 1 to 200 μ

m and wherein a differential pressure applied on the filter ranges from 50 to 1000 Kpa.

5. The process according to claim 4, wherein the filters are selected from Nutsche filters and centrifugal-discharge filters.

6. The process according to claim 1, wherein step a) takes place in a reactor situated upstream of a filter.

7. The process according to claim 1, wherein both step a) and step b) take place in a filter.

8. The process according to claim 1, wherein in step a), an initial temperature of the liquid phase containing the Ti compound is in the range from −

20°

C. to 25°

C. and then gradually raised to a second temperature range from 80°

C. to 135°

C.

9. The process according to claim 1, wherein the molar ratio of Mg to 1,3-diether is between 0.5 and 50.

10. The process according to claim 1, wherein steps a) and step b) are repeated more times in sequence and finally the separated solid component is washed with a solvent selected from a hydrocarbon or a halogenated hydrocarbon.

11. The process according to claim 1, wherein the titanium compound to be fed in step a) is selected from TiCl₄, TiCl₃ and Ti-haloalcoholates of formula Ti(OR)_n-yX_y, where n is the valence of titanium, y is a number between 1 and n-1, X is halogen and R is a hydrocarbon radical having from 1 to 10 carbon atoms.

12. The process according to claim 11, wherein the titanium compound is TiCl₄.

13. The process according to claim 1, wherein the solid support to be fed in step a) is a magnesium halide or a Mg compound that yields MgCl₂ by reaction with a chlorinating agent.

14. The process according to claim 13, wherein the solid support is a spheriform adduct of formula MgCl₂•

pROH, where p is a number between 0.1 and 6 and R is a hydrocarbon radical having 1-18 carbon atoms.

15. The process according to claim 14, wherein the solid support is a MgCl₂/ethanol adduct.

16. The process according to claim 1, wherein the 1,3-diethers to be fed in step a) have formula (I):

17. The process according to claim 16, wherein the 1,3 diethers are compounds of formula:

18. The process according to claim 17, wherein the 1,3 diethers are selected from:

9,9-bis(methoxymethyl)fluorene,9,9-bis(methoxymethyl)-2,3,6,7-tetramethylfluorene,-bis(methoxymethyl)-2,3,4,5,6,7-hexafluorofluorene,-bis(methoxymethyl)-2,3-benzofluorene, 9,9-bis(methoxymethyl)-2,3,6,7-dibenzofluorene, -bis(methoxymethyl)-2,7-diisopropylfluorene,-bis(methoxymethyl)-1,8-dichlorofluorene,-bis(methoxymethyl)-2,7-dicyclopentylfluorene,-bis(methoxymethyl)-1,8-difluorofluorene,-bis(methoxymethyl)-1,2,3,4-tetrahydrofluorene,-bis(methoxymethyl)-1,2,3,4,5,6,7,8-octahydrofluorene,9,9-bis(methoxymethyl)-4-tert-butylfluorene.

20. The process according to claim 17 wherein the halogens are selected from the group consisting of Cl and F.

19. A process for the homo- or co-polymerization of α

-olefins of formula CH₂═

CHR, wherein R is hydrogen or an alkyl, cycloalkyl, aryl, arylalkyl or alkylaryl radical with 1 to 12 carbon atoms, said process comprising a polymerization step carried out in the presence of catalyst systems comprising the solid catalyst component obtained by steps comprising;

a) contacting a solid support comprising a magnesium halide or a precursor thereof, one or more 1,3-diethers and a liquid phase containing a titanium compound, thereby forming a slurry;

b) separating the slurry in a solid/liquid separation step, thereby isolating a diether-based solid catalyst component, wherein the solid/liquid separation step has a solid/liquid separation velocity,

wherein a ratio between the solid/liquid separation velocity and the final amount of the separated solid catalyst component is higher than 0.5 liter/(min.Kg).