Polymer, electroluminescent device, and light emitting device

• US 20040241494A1
• Filed: 12/23/2003
• Published: 12/02/2004
• Est. Priority Date: 12/25/2002
• Status: Abandoned Application

• Current Assignee: Semiconductor Energy Laboratory Co., Ltd.
• Original Assignee: Semiconductor Energy Laboratory Co., Ltd.
• Inventors: Nomura, Ryoji, Seo, Satoshi, Takasu, Takako
• Application Number:
  US10/743,337
• Publication Number:
  US 20040241494A1
• Time in Patent Office: Days
• US Class Current: 428/690
• CPC Class Codes: C08G 61/124 with a five-membered ring containing one nitrogen atom in the ring
• CPC Class Codes: C08G 61/126 with a five-membered ring containing one sulfur atom in the ring
• CPC Class Codes: C09K 11/06 containing organic luminescent materials
• CPC Class Codes: C09K 2211/14 Macromolecular compounds
• CPC Class Codes: C09K 2211/1416 Condensed systems
• CPC Class Codes: C09K 2211/1425 Non-condensed systems
• CPC Class Codes: C09K 2211/1458 containing sulfur as the only heteroatom
• CPC Class Codes: C09K 2211/1466 containing nitrogen as the only heteroatom
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 59/35 comprising red-green-blue [RGB] subpixels
• CPC Class Codes: H10K 71/125 using electrolytic deposition e.g. in-situ electropolymerisation
• CPC Class Codes: H10K 85/113 Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
• CPC Class Codes: H10K 85/115 Polyfluorene; Derivatives thereof
• CPC Class Codes: H10K 85/151 Copolymers
• CPC Class Codes: H10K 85/40 Organosilicon compounds, e.g. TIPS pentacene
• CPC Class Codes: H10K 85/615 Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
• CPC Class Codes: Y10S 428/917 Electroluminescent

Abstract

A novel electroluminescent polymer is represented by the general formula (I).

A is (a-1) or the like, and B or B′ is either the following (b-1) or (b-2). A film of the polymer represented by the general formula (I) can be formed by electrolytic polymerization, and further emits light in a different color by an electric field when a substituent thereof is changed. Therefore, a light-emitting device that is capable of multicolor displaying can be easily obtained.

Claims

1. A polymer having the following general formula as a repeating unit.

3. The light-emitting device according to claim 1 or 2, wherein the layer including the polymer is a layer formed by electrolytic polymerization.

2. An electroluminescent device having a layer including a polymer having a repeating unit represented by the following general formula (I) between a pair of electrodes.

4. A light-emitting device having a plurality of electroluminescent devices,

wherein each of the plurality of electroluminescent devices has an opposed pair of electrodes and a layer including a polymer, which is formed between the pair of electrodes, and

wherein the polymer is a compound having a repeating unit represented by the following general formula (D).

[In the general formula (I), m and n are 1 or 2, A is any of the following (a-1) to (a-20), and B and B′

are identical or different, and are either (b-1) or (b-2).

(R₁ and R₂ of (a-1) and R₅ and R₆ of (a-20) are identical or different, and R₁ to R₆ are a hydrogen atom, a hologen atom, or an organic substituent that may include an oxygen atom, a sulfur atom or a nitrogen atom.)

(R₇ and R₈ of (b1)) and R₉ and R₁₀ of (b-2) are respectively identical or different, and R₇ to R₁₀ are a hydrogen atom, a hologen atom, or an organic substituent that may include an oxygen atom, a sulfur atom or a nitrogen atom.)]

5. The light-emitting device according to claim 4, wherein at least one of the plurality of electroluminescent devices has the polymer which is different from those of the other electroluminescent devices.

6. A light-emitting device having:

a substrate having an insulating surface;

a plurality of stripe-shaped first electrodes formed at the insulating surface of the substrate;

a layer including a polymer, which is formed on each of the plurality of first electrodes; and

a plurality of stripe-shaped second electrodes arranged to be orthogonal to the first electrodes, which are formed on the plurality of layers including the polymer,

wherein the polymer is a compound having a repeating unit represented by the following general formula (I).

[In the general formula (I), m and n are 1 or 2, A is any of the following (a-1) to (a-20), and B and B′

are identical or different, and are either (b-1) or (b-2).

(R₁ and R₂ of (a-1) and R₅ and R₆ of (a-20) are identical or different, and R₁ to R₆ are a hydrogen atom, a hologen atom, or an organic substituent that may include an oxygen atom, a sulfur atom or a nitrogen atom.)

(R₇ and R₈ of (b-1) and R₉ and R₁₀ of (b-2) are respectively identical or different, and R₇ to R₁₀ are a hydrogen atom, a hologen atom, or an organic substituent that may include an oxygen atom, a sulfur atom or a nitrogen atom.)]

7. The light-emitting device according to claim 6, wherein at least one of the plurality of layers including the polymer has the polymer which is different from those of the other layers including the polymer.

8. The light-emitting device according to claim 6 or 7, wherein the layers including the polymer are layers formed by electrolytic polymerization.

9. A light-emitting device having:

a substrate having an insulating surface;

a plurality of first electrodes formed at the insulating surface of the substrate;

a layer including a polymer, which is formed on each of the plurality of first electrodes; and

a second electrode opposed to each of the plurality of first electrodes with the plurality of layers including the polymer interposed in between, wherein polymer is a compound having a repeating unit represented by the following general formula (I).

[In the general formula (I), m and n are 1 or 2, A is any of the following (a-1) to (a-20), and B and B′

are identical or different, and are either (b1) or (b-2).

(R₁ and R₂ of (a-1) and R₅ and R₆ of (a-20) are identical or different, and R₁ to R₆ are a hydrogen atom, a hologen atom, or an organic substituent that may include an oxygen atom, a sulfur atom or a nitrogen atom.)

(R₇ and R₈ of (b-1) and R₉ and R₁₀ of (b-2) are respectively identical or different, and R₇ to R₁₀ are a hydrogen atom, a hologen atom, or an organic substituent that may include an oxygen atom, a sulfur atom or a nitrogen atom.)]

10. The light-emitting device according to claim 9, wherein at least one of the plurality of layers including the polymer has the included polymer which is different from those of the other layers including the polymer.

12. The light-emitting device according to any one of claims 9 to 11, wherein the layer including the polymer is a layer formed by electrolytic polymerization.

11. A light-emitting device having a plurality of first to third pixels that emit light in different colors from each other on a substrate having an insulating surface, having:

a plurality of first electrodes;

a layer including a polymer, which is formed on each of the plurality of first electrodes; and

a second electrode opposed to the plurality of first electrodes, which is formed on the layer including the polymer,

wherein the first electrode is provided with respect to each of the plurality of first to third pixels, and the second electrode is provided in common with the plurality of first to third pixels, and

wherein the polymer is a compound that has a repeating unit represented by the following general formula (I), and the polymer of the layer including the polymer is different from each other in the first to third pixels.

[In the general formula (I), m and n are 1 or 2, A is any of the following (a-1) to (a-20), and B and B′

are identical or different, and are either (b-1) or (b-2).

(R₁ and R₂ of (a-1) and R₅ and R₆ of (a-20) are identical or different, and R₁ to R₆ are a hydrogen atom, a hologen atom, or an organic substituent that may include an oxygen atom, a sulfur atom or a nitrogen atom.)

(R₇ and R₈ of (b-1) and R₉ and R₁₀ of (b-2) are respectively identical or different, and R₇ to R₁₀ are a hydrogen atom, a hologen atom, or an organic substituent that may include an oxygen atom, a sulfur atom or a nitrogen atom.)]

13. The light-emitting device according to any one of claim 9 to claim 11, has a plurality of data signal lines, the plurality of scan signal lines, and a plurality of nonlinear elements connected to one of the data signal lines and one of the scan signal lines, wherein the plurality of first electrodes are respectively the nonlinear elements.

14. The light-emitting device according to claim 13, wherein at least a thin film transistor is used as the nonlinear elements.