Method, system and apparatus for testing electrochemical cells

• US 20040245100A1
• Filed: 05/14/2004
• Published: 12/09/2004
• Est. Priority Date: 05/14/2003
• Status: Abandoned Application

• Current Assignee: Hydrogenics Corporation (Cummins Incorporated)
• Original Assignee: Hydrogenics Corporation (Cummins Incorporated)
• Inventors: Abouatallah, Rami Michel
• Application Number:
  US10/845,191
• Publication Number:
  US 20040245100A1
• Time in Patent Office: Days
• US Class Current: 204/400
• CPC Class Codes: C25B 15/06 Detection or inhibition of short circuits in the cell
• CPC Class Codes: G01N 27/4163 checking the operation of, or calibrating, the measuring apparatus G01N27/3274, G01N27/4175 and G01N33/0006 take precedence
• CPC Class Codes: G01R 31/396 Acquisition or processing of data for testing or for monitoring individual cells or groups of cells within a battery
• CPC Class Codes: G01R 31/52 Testing for short-circuits, leakage current or ground faults
• CPC Class Codes: H01M 8/04246 Short circuiting means for defective fuel cells detection of defective fuel cells H01M8/04664, methods for shunting fuel cells H01M8/04955
• CPC Class Codes: H01M 8/04552 of the individual fuel cell
• CPC Class Codes: H01M 8/04582 of the individual fuel cell
• CPC Class Codes: H01M 8/04671 of the individual fuel cell
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

Embodiments of the invention relate to apparatus, systems and methods for testing for short-circuited cells within an electrochemical cell stack. In order to test for a short-circuit, each cell in the stack is supplied with a non-fuel gas at both the anode and cathode sides of the cell. A voltage is supplied across the whole electrochemical cell stack and the individual electrical potentials (ie. voltages) between the anode and cathode of each cell is measured. If the voltage measured across the anode and cathode of a cell is below a certain amount, the cell is determined to be short-circuited.

Claims

1. An apparatus for testing for a short circuit in at least one electrochemical cell, comprising:

a gas supply for supplying a non-fuel gas to an anode side and a cathode side of the at least one electrochemical cell;

a voltage supply for supplying a test voltage across the at least one electrochemical cell; and

a voltage monitor for measuring a cell voltage of each at least one electrochemical cell.

2. The apparatus of claim 1, further comprising a voltage supply system which comprises the voltage supply and a current measuring device for measuring current flowing through the at least one electrochemical cell.

3. The apparatus of claim 2, wherein the test voltage is a DC voltage.

4. The apparatus of claim 3, wherein the voltage supply system is arranged to increase the DC voltage from zero and the voltage monitor is arranged to measure the cell voltage of each at least one electrochemical cell once the current measured by the current measuring device is determined to be stable.

5. The apparatus of claim 1, wherein the voltage supply to the at least one electrochemical cell is supplied such that the highest cell voltage does not exceed a maximum voltage.

6. The apparatus of claim 5, wherein the maximum voltage is in the range of 0.5-1.2 volt.

7. The apparatus of claim 1, wherein each at least one electrochemical cell is a fuel cell and wherein the test voltage is supplied to the at least one fuel cell such that a cathode of each at least one fuel cell is at a higher voltage than an anode of the same cell.

8. The apparatus of claim 1, wherein each at least one electrochemical cell is an electrolyzer cell and wherein the test voltage is supplied to the at least one electrolyzer cell such that an anode of each at least one electrolyzer cell is at a higher voltage than a cathode of the same cell.

9. The apparatus of claim 1, further comprising a discharge circuit for discharging the at least one electrochemical cell after the cell voltage has been measured.

10. The apparatus of claim 9, wherein said discharge circuit comprises a discharge resistor connectable across the at least one electrochemical cell.

11. The apparatus of claim 10, wherein said discharge circuit comprises a switch for connecting the discharge resistor across the at least one electrochemical cell.

12. The apparatus of claim 1, wherein the non-fuel gas consists substantially of inert gas or air.

13. The apparatus of claim 1, wherein the gas supply further comprises a gas storage tank for storing and supplying said non-fuel gas to the anode side and cathode side of the at least one electrochemical cell.

14. The apparatus of claim 1, wherein the at least one electrochemical cell comprises part of an electrochemical cell stack having a plurality of electrochemical cells.

15. The apparatus of claim 1, wherein the voltage monitor comprises a multiplexer for selecting each at least one electrochemical cell for measuring a cell voltage thereof.

16. The apparatus of claim 15, wherein the multiplexer is adapted to select each at least one electrochemical cell in a rapidly repeating sequence.

17. The apparatus of claim 1, wherein the voltage monitor comprises a display for displaying the measured cell voltage of each at least one electrochemical cell.

18. The apparatus of claim 15, wherein the voltage monitor is arranged to determine that the at least one electrochemical cell is short-circuited if the measured cell voltage of the respective electrochemical cell is less than a threshold voltage.

19. The apparatus of claim 18, wherein the threshold voltage is a predetermined voltage.

20. The apparatus of claim 18, wherein the threshold voltage is based on the measured cell voltages of the electrochemical cells.

21. The apparatus of claim 20, wherein the threshold voltage is based on a fraction of the average of the measured voltages.

22. A method for testing for a short circuit in at least one electrochemical cell, comprising:

supplying a non-fuel gas to an anode side and a cathode side of the at least one electrochemical cell;

supplying a test voltage across the at least one electrochemical cell; and

measuring a cell voltage of the at least one electrochemical cell.

23. The method of claim 22, further comprising measuring a current flowing to the at least one electrochemical cell.

24. The method of claim 23, wherein the test voltage is a DC voltage.

25. The method of claim 24, further comprising increasing the test voltage from zero and the step of measuring comprises measuring the cell voltage of each at least one electrochemical cell once the measured current is determined to be substantially stable.

26. The method of claim 22, wherein the step of supplying a test voltage is performed such that the highest cell voltage does not exceed a maximum cell voltage.

27. The method of claim 26, wherein the maximum cell voltage is in the range of 0.5-1.2 volts.

28. The method of claim 22, wherein each at least one electrochemical cell is a fuel cell and the test voltage is applied to the at least one fuel cell such that a cathode of each at least one fuel cell is at a higher voltage than an anode of the same cell.

29. The method of claim 22, wherein each at least one electrochemical cell is an electrolyzer cell and the test voltage is applied to the at least one electrolyzer cell such that an anode of each at least one electrolyzer cell is at a higher voltage than a cathode of the same cell.

30. The method of claim 22, further comprising discharging the at least one electrochemical cell through a discharge circuit after said step of measuring.

31. The method of claim 22, wherein the non-fuel testing gas consists substantially of inert gas or air.

32. The method of claim 22, further comprising purging the anode side and cathode side of each at least one electrochemical cell before supplying the non-fuel gas.

33. The method of claim 22, wherein the at least one electrochemical cell comprises part of an electrochemical stack having a plurality of electrochemical cells.

34. The method of claim 22, wherein the step of measuring comprises selecting each at least one electrochemical cell in a rapidly repeating sequence and measuring each selected electrochemical cell in said sequence.

35. The method of claim 22, further comprising the step of displaying the measured cell voltage of each at least one electrochemical cell.

36. The method of claim 22, further comprising, for each at least one electrochemical cell, the step of determining that the electrochemical cell is short-circuited if the measured cell voltage of the electrochemical cell is less than a threshold voltage.

37. A system for testing a plurality of electrochemical cells connected in series, the system comprising:

a gas supply for supplying a non-fuel gas to an anode side and a cathode side of each at least one electrochemical cell of the plurality of electrochemical cells;

a voltage supply for supplying a first voltage across the plurality of electrochemical cells; and

a voltage monitor for measuring a second voltage between respective electrodes at the anode side and cathode side of each electrochemical cell.

38. The system of claim 37, further comprising a voltage supply system which comprises the voltage supply and a current measuring device for measuring current flowing to the electrochemical cells.

39. The system of claim 38, wherein the voltage supply system is arranged to increase the first voltage from zero and the voltage monitor is arranged to measure the second voltage of each electrochemical cell once the current measured by the current measuring device is determined to be stable.

40. The system of claim 37, wherein the voltage supply to the electrochemical cells is supplied such that the highest cell voltage does not exceed a maximum cell voltage.

41. The system of claim 40, wherein the maximum cell voltage is in the range of 0.5-1.2 volt.

42. The system of claim 37, wherein each electrochemical cell is a fuel cell.

43. The system of claim 37, wherein each electrochemical cell is an electrolyzer cell.

44. The system of claim 37, further comprising a discharge circuit for discharging the plurality of electrochemical cells after the respective second voltages have been measured.

45. The system of claim 44, wherein said discharge circuit comprises a discharge resistor connectable across the plurality of electrochemical cells.

46. The system of claim 45, wherein said discharge circuit comprises a switch for connecting the discharge resister across the plurality of electrochemical cells.

47. The system of claim 37, wherein the non-fuel gas consists substantially of inert gas or air.

48. The system of claim 37, wherein the gas supply further comprises a gas storage tank for storing and supplying said non-fuel gas to the plurality of electrochemical cell.

49. The system of claim 37, wherein the voltage monitor comprises a multiplexer for selecting each electrochemical cell for measuring the second respective voltage thereof.

50. The system of claim 49, wherein the multiplexer selects each electrochemical cell in a rapidly repeating sequence.

51. The system of claim 37, wherein the voltage monitor comprises a display for displaying the measured cell voltage of each electrochemical cell.

52. The system of claim 37, wherein, for each electrochemical cell, the voltage monitor indicates that the electrochemical cell is short-circuited if the measured second voltage of the electrochemical cell is less than a threshold voltage.

53. The system of claim 52, wherein the threshold voltage is a predetermined voltage.

54. The system of claim 52, wherein the threshold voltage is based on the measured second voltages of the plurality of electrochemical cells.

55. The system of claim 54, wherein the threshold voltage is based on a fraction of the average of the measured second voltages.