Water purification cartridge, water purifier and method for cleaning water purifier

• US 20040245174A1
• Filed: 03/04/2004
• Published: 12/09/2004
• Est. Priority Date: 09/05/2001
• Status: Abandoned Application

• Current Assignee: Mitsubishi Rayon Company Limited (Mitsubishi Chemical Holdings Corporation)
• Original Assignee: Mitsubishi Rayon Company Limited (Mitsubishi Chemical Holdings Corporation)
• Inventors: Takayama, Hitoshi, Taneike, Masahiko, Katou, Tatsuhiro, Uehara, Masaru, Yanou, Manabu
• Application Number:
  US10/488,607
• Publication Number:
  US 20040245174A1
• Time in Patent Office: Days
• US Class Current: 210/636
• CPC Class Codes: B01D 2313/06 External membrane module supporting or fixing means
• CPC Class Codes: B01D 2313/40 Adsorbents within the flow path
• CPC Class Codes: B01D 2313/44 Cartridge types
• CPC Class Codes: B01D 2313/90 Additional auxiliary systems integrated with the module or apparatus
• CPC Class Codes: B01D 2313/902 Integrated cleaning device
• CPC Class Codes: B01D 2321/04 Backflushing
• CPC Class Codes: B01D 2321/162 Use of acids
• CPC Class Codes: B01D 2321/168 Use of other chemical agents
• CPC Class Codes: B01D 61/18 Apparatus therefor
• CPC Class Codes: B01D 63/024 with a single potted end
• CPC Class Codes: B01D 63/0241 being U-shaped
• CPC Class Codes: B01D 65/00 Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
• CPC Class Codes: B01D 65/02 Membrane cleaning or sterilisation ; Membrane regeneration
• CPC Class Codes: C02F 1/28 by sorption using ion-exchange C02F1/42; sorbent compositions B01J
• CPC Class Codes: C02F 1/444 by ultrafiltration or microfiltration
• CPC Class Codes: C02F 2201/006 Cartridges
• CPC Class Codes: C02F 2307/06 Mounted on or being part of a faucet, shower handle or showerhead

Abstract

An object of the present invention is to provide a water purification cartridge in which the decreased function of the hollow fiber membranes is restored by cleaning and of which the operating cost of a purification treatment of raw water decreases. The present invention provides a water purification cartridge comprising a hollow fiber membrane element comprising a plurality of hollow fiber membranes bent in a U-shape and a potting material for binding both ends of the hollow fiber membranes so as to maintain the open states of the hollow fiber membranes and a cylindrical hollow fiber membrane case for covering the hollow fiber membranes, wherein the hollow fiber membrane element is detachably installed in the hollow fiber membrane case so that a fluid-tight state is maintained between the primary side and the secondary side of the hollow fiber membranes.

Claims

1. A water purification cartridge comprising:

a hollow fiber membrane element comprising a plurality of hollow fiber membranes bent in a U-shape and a potting material for binding both ends of the hollow fiber membranes so as to maintain the open states of the hollow fiber membranes; and

a cylindrical hollow fiber membrane case for covering the hollow fiber membranes,

wherein the hollow fiber membrane element is detachably installed in the hollow fiber membrane case so that a fluid-tight state is maintained between the primary side and the secondary side of the hollow fiber membranes.

2. A water purification cartridge according to claim 1, wherein a connection device is provided at the hollow fiber membrane case, and one connection member which is one of a screw type connection member, a bayonet type connection member, and a flange type connection member, and which engages the connection device, is provided at the side surface of the potting material.

3. A water purification cartridge according to claim 2, wherein an adsorbent filter, which comprises an adsorbent case and an adsorbent installed in the adsorbent case, is detachably connected to one end of the hollow fiber membrane case, and a detachable cover is provided to the adsorbent case such that the adsorbent installed in the adsorbent case is freely changed.

4. A water purification cartridge according to claim 3, wherein the adsorbent is installed in the adsorbent case while the adsorbent is filled in a package through which water passes.

5. A water purifier comprising the water purification cartridge according to claim 1.

6. A water purifier comprising:

a hollow fiber membrane module in which the ends of the hollow fiber membranes are fixed to one end of a cylindrical vessel while the ends of the hollow fiber membranes are maintained in open states,

wherein the hollow fiber membrane module has a hollow fiber membrane filling percentage in a range from 20 to 60%, and wherein the cylindrical vessel comprises a cleaning solvent inlet and a cleaning solvent outlet for cleaning the exterior surface of the hollow fiber membranes.

7. A water purifier according to claim 6, wherein the cleaning solvent inlet is a raw water inlet.

8. A water purifier according to claim 6, wherein the cleaning solvent inlet is provided in the side surface of the cylindrical vessel at a location near the portion at which hollow fiber membranes are fixed.

9. A water purifier according to claim 6, wherein an adsorbent is installed at the upstream with respect to the hollow fiber membrane module.

10. A water purifier according to claim 6, wherein the water purifier comprises a cleaning solvent flow device for making a cleaning solvent flow on at least a part of the exterior surface of the hollow fiber membranes in a circumferential direction with respect to the axis of the cylindrical vessel.

11. A water purifier according to claim 10, wherein the cleaning solvent flow device is a plate member comprising at least one cleaning solvent passage which is diagonally disposed across the plate member.

12. A water purifier according to claim 11, wherein the plate member is provided at at least one position of the upstream and the circumference of the hollow fiber membranes.

13. A water purifier according to claim 6, wherein a pre-filter having a mesh larger than the mesh of the hollow fiber membranes is provided at the upstream of the hollow fiber membrane module.

14. A water purifier according to claim 13, wherein the pre-filter is installed detachably.

15. A water purifier according to claim 6, wherein a plurality of the hollow fiber membrane modules are arranged in a line, and while one of the hollow fiber membrane modules is being cleaned, another hollow fiber membrane module filters.

16. A water purifier according to claim 6, wherein the water purifier comprises at least one measuring device for measuring total filtration time, total filtered amount, a filtration flow rate, and a filtration pressure.

17. A water purifier comprising a cleaning solvent flow device for making a cleaning solvent flow on at least a part of the exterior surface of hollow fiber membranes of a hollow fiber membrane module installed in a cylindrical vessel, in a circumferential direction with respect to the axis of the cylindrical vessel.

18. A method for cleaning a water purifier which comprises a hollow fiber membrane module in which the ends of hollow fiber membranes are fixed to one end of a cylindrical vessel while the ends of the hollow fiber membranes are maintained in open states, the hollow fiber membrane module has a hollow fiber membrane filling percentage in a range from 20 to 60%, and the cylindrical vessel comprises a cleaning solvent inlet and a cleaning solvent outlet for cleaning the exterior surface of the hollow fiber membranes, the method comprising the steps of:

supplying raw water from the cleaning solvent inlet, and after the raw water passes through the hollow fiber membranes, discharging the raw water from the cleaning solvent outlet.

19. A method for cleaning a water purifier according to claim 18, wherein the cleaning solvent is allowed to flow on the exterior surface of at least a part of the hollow fiber membranes in the circumferential direction with respect to the axis of the cylindrical vessel.

20. A method for cleaning a water purifier according to claim 19, wherein the cleaning solvent is allowed to flow in the circumferential direction of the cylinder vessel by passing through cleaning solvent passages which are diagonally disposed across the plate member.

24. A method for cleaning a water purifier according to one of claims 18 and 21, wherein a pre-filter having a mesh larger than the mesh of the hollow fiber membranes is provided at the upstream of the hollow fiber membrane module.

25. A method for cleaning a water purifier according to claim 24, wherein the pre-filter is installed detachably and is detached to be cleaned.

26. A method for cleaning a water purifier according to one of claims 18 and 21, wherein at least one of total filtration time, total filtered amount, filtration flow rate, and filtration pressure is measured, and an automatic cleaning is conducted when the at least one reaches to a predetermined fixed value.

27. A method for cleaning a water purifier according to one of claims 18 and 21, wherein the cleaning solvent is supplied from the cleaning solvent inlet, the cleaning solvent is allowed to flow through the hollow fiber membranes, and the cleaning solvent is discharged from the cleaning solvent outlet, and thereby cleaning of the hollow fiber membranes is conducted, while filtration is also conducted, and total filtered amount or filtration flow rate is measured from the beginning of the cleaning, the cleaning is terminated when the total filtered amount or the filtration flow rate reaches a predetermined fixed value.

21. A method for cleaning a water purifier which comprises a hollow fiber membrane module in which the ends of hollow fiber membranes are fixed to one end of a cylindrical vessel while the ends of the hollow fiber membranes are maintained in open states, the hollow fiber membrane module has a hollow fiber membrane filling percentage in a range from 20 to 60%, and the cylindrical vessel comprises a cleaning solvent inlet and a cleaning solvent outlet for cleaning the exterior surface of the hollow fiber membranes, the method comprising the steps of:

supplying chemical from the cleaning solvent inlet;

maintaining the conditions for a fixed time; and

discharging the chemical from the cleaning solvent outlet.

22. A method for cleaning a water purifier according to claim 21, wherein the chemical is an aqueous solution containing one of hydrochloric acid, citric acid, acetic acid, household detergents, and hypochlorites.

23. A method for cleaning a water purifier according to claim 21, wherein after discharging the chemical from the cleaning solvent outlet, raw water is further supplied from the cleaning solvent inlet and is then allowed to flow through the hollow fiber membranes, and the raw water is then discharged from the cleaning solvent outlet.