Apparatus for continuous carbon dioxide absorption

• US 20040250684A1
• Filed: 08/10/2004
• Published: 12/16/2004
• Est. Priority Date: 10/08/2001
• Status: Abandoned Application

• Current Assignee: Canterprise Limited (University of Canterbury)
• Original Assignee: Canterprise Limited (University of Canterbury)
• Inventors: Brill, Matthew Lloyd, Brown, Michael Asher, Green, Matthew Donald, Cleland, James Richard, Marsh, Kenneth Neil, Wallace, Jamie Stuart, Krumdieck, Susan Pran
• Application Number:
  US10/491,932
• Publication Number:
  US 20040250684A1
• Time in Patent Office: Days
• US Class Current: 96/290
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/18 Absorbing units; Liquid distributors therefor B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32
• CPC Class Codes: B01J 2219/30223 Cylinder
• CPC Class Codes: H01M 8/0668 Removal of carbon monoxide or carbon dioxide
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

Apparatus for removing carbon dioxide from a stream of air or other gas, which includes a vertical gas absorption reactor containing loosely packed mixing units submerged in a carbon dioxide absorbent liquid; gas to be treated is admitted at or near this base of the rector, is broken into small bubbles by the mixing units, and passes through the absorbent liquid to remove a high percentage of carbon dioxide; treated gas leaves from the top of the reactor, a regenerator associated with the reactor continually or intermittently regenerates the absorbent liquid and is arranged to receive absorbent liquid to be treated through an outlet from the reactor which is located higher up the wall of the reactor than the inlet for returning treated liquid to the reactor.

Claims

1. Apparatus for removing carbon dioxide from a stream of air or other gas, said apparatus including:

a substantially vertical gas absorption reactor which contains a plurality of loosely packed mixing units submerged in a carbon dioxide absorbent liquid;

a gas inlet into the reactor, said inlet being arranged to admit in use an incoming stream of gas at or near the base of the reactor, and a gas outlet at or adjacent the top of the reactor through which the outgoing stream of treated gas leaves the reactor in use;

said reactor further being provided with a liquid outlet and a liquid inlet in the wall of the reactor, the liquid outlet being located higher up the wall of the reactor than the liquid inlet;

a regenerator which incorporates heating means and which is provided with an inlet and the outlet and a carbon dioxide vent;

the regenerator inlet being connected to the liquid outlet from the reactor, and the regenerator outlet being connected to the liquid inlet to the reactor.

2. Apparatus as claimed in claim 1, wherein said reactor is internally divided into four portions:

a first portion adjacent the base of the reactor which provides a reservoir of absorbent liquid and which does not contain mixing units;

a second portion extending from the top of said first portion to approximately the level of the liquid outlet, said second portion containing mixing units and in use being filled with the absorbent liquid;

a third portion immediately above said second portion which contains mixing units and which provides an overflow zone in use; and

a fourth portion at the top of the reactor in communication with the gas outlet.

3. The apparatus as claimed in claim 2 wherein said fourth portion contains means for removing droplets of absorbent liquid from gas leaving the reactor.

4. The apparatus as claimed in claim 3 wherein said means for removing droplets comprises one or more sheets of wire mesh.

5. The apparatus as claimed in any one of the preceding claims wherein the gas inlet terminates inside the reactor in a plurality of spaced spigots at or just below the junction between said first and second portions.

6. The apparatus as claimed in claim 1 wherein each mixing unit comprises an open-ended cylinder the walls which are pierced by multiple cutouts which are bent into the interior of the cylinder, forming multiple curved walls within the cylinder.

7. The apparatus as claimed in any one of the claims 1-4 wherein said regenerator comprises a container which incorporates heating means in the base and/or walls thereof.

8. The apparatus as claimed in any one of claims 1-4 wherein the heating means of said regenerator comprises an electrically heated plate arranged relative to the liquid outlet from the reactor such that in use liquid entering the regenerator from the reactor flows over the surface of said plate.

9. The apparatus as claimed in claim 8 wherein said plate is cylindrical.

10. The apparatus as claimed in claim 8 wherein said plate is a flat plate arranged substantially vertically in the regenerator.

11. The apparatus as claimed in claim 8 wherein said plate comprises one or more flat plates formed with surface projections, the or each said plate being arranged at an acute angle to the horizontal.

12. The apparatus as claimed in any one of claims 1-4 wherein said regenerator incorporates a heat exchanger.