Sample matrix for infrared spectroscopy

• US 20040251414A1
• Filed: 06/10/2003
• Published: 12/16/2004
• Est. Priority Date: 06/10/2003
• Status: Abandoned Application

• Current Assignee: Goodyear Tire & Rubber Company
• Original Assignee: Goodyear Tire & Rubber Company
• Inventors: Rodewald, Stephan
• Application Number:
  US10/457,971
• Publication Number:
  US 20040251414A1
• Time in Patent Office: Days
• US Class Current: 250/339.07
• CPC Class Codes: B01L 2300/0681 Filter
• CPC Class Codes: B01L 2300/0829 Multi-well plates; Microtitration plates
• CPC Class Codes: B01L 3/50255 Multi-well filtration
• CPC Class Codes: B01L 3/5085 for multiple samples, e.g. microtitration plates
• CPC Class Codes: B01L 3/50857 using arrays or bundles of open capillaries for holding samples
• CPC Class Codes: G01N 1/2813 Producing thin layers of samples on a substrate, e.g. smearing, spinning-on G01N1/30 takes precedence
• CPC Class Codes: G01N 21/03 Cuvette constructions
• CPC Class Codes: G01N 21/253 for batch operation, i.e. multisample apparatus analytical automats G01N35/00
• CPC Class Codes: G01N 21/3563 for analysing solids; Preparation of samples therefor
• CPC Class Codes: G01N 21/3577 for analysing liquids, e.g. polluted water

Abstract

The utilization of the sample holder of this invention in infrared spectroscopy overcomes some of the major problems typically encountered with sample holders used in traditional techniques. More specifically, the utilization of the sample holder of this invention eliminates interference fringes typically encountered with films which are prepared from the sample. Traditional sample preparation is frequently a highly labor intensive, multi-step process. The present invention offers a significant advance in the state of sample preparation by virtue of being a simple and robust technique requiring relatively little labor in a single, easy step. Sometimes there is a desire to procure the infrared spectrum of samples that are not film forming. The sample holder of the present invention can be used equally well with samples that do not form solid films, such as low molecular weight crystalline materials, oils and amorphous solid materials. The present invention more specifically discloses in an infrared spectrometer which includes (1) an infrared source, (2) an optical array, (3) an infrared detector and (4) a means for recording transmitted spectrum over a range of wave numbers; the improvement which comprises the infrared spectrometer including a sample carrier which is comprised of a mesh which is opaque or totally transparent to infrared light, wherein the mesh size is within the range of about 20 to about 700.

Claims

1. In an infrared spectrometer which includes (1) an infrared source, (2) an optical array, (3) an infrared detector and (4) a means for recording transmitted spectrum over a range of wave numbers;

the improvement which comprises the infrared spectrometer including a sample carrier which is comprised of a mesh which is opaque or totally transparent to infrared light, wherein the mesh size is within the range of about 20 to about 700.

6. The infrared spectrometer as specified in claim 1 wherein the mesh has a mesh size within the range of 40 to 500.

7. The infrared spectrometer as specified in claim 1 wherein the mesh has a mesh size within the range of 100 to 400.

8. The infrared spectrometer as specified in claim 6 wherein the mesh is a woven metal wire cloth.

9. The infrared spectrometer as specified in claim 8 wherein the wire cloth is comprised of wires having a diameter of about 0.001 inches to about 0.002 inches.

17. The infrared spectrometer specified in claim 1 wherein the mesh is opaque to infrared light.

2. A process for determining the infrared spectrum of a sample which comprises:

transmitting infrared light through said sample over a range of wave numbers and recording the signal of the transmitted infrared light over the range of wave numbers, wherein the sample is held by a mesh which is opaque or totally transparent to infrared light, wherein the mesh size is within the range of about 20 to about 700.

10. A process as specified in claim 2 wherein the mesh has a mesh size within the range of 40 to 500.

11. A process as specified in claim 2 wherein the mesh has a mesh size within the range of 100 to 400.

12. A process as specified in claim 2 wherein the mesh is a woven metal wire cloth.

13. A process as specified in claim 2 wherein the wire cloth is comprised of wires having a diameter of about 0.05 inches to about 0.001 inches.

16. A process as specified in claim 2 wherein the mesh is opaque to infrared light.

3. A sample carrier for holding a sample during infrared spectroscopic analysis, said sample carrier being comprised of a frame, a mask in microtiter plate format, and a mesh which is affixed to the mask, wherein the mesh is opaque or totally transparent to infrared light, and wherein the mesh size is within the range of about 20 to about 700.

4. A sample carrier as specified in claim 3 wherein the mask contains a plurality of positions, and wherein the mesh occupies the positions.

5. A sample carrier as specified in claim 3 wherein the mesh is a woven metal wire cloth.

14. A sample carrier as specified in claim 3 wherein the mask contains 96 positions.

15. A sample carrier as specified in claim 14 wherein the 96 positions are arranged in 8 rows of 12 positions.

18. A sample carrier as specified in claim 3 wherein the mask contains 384 positions.

19. A sample carrier as specified in claim 3 wherein the mask contains 1,536 positions.

20. A sample carrier as specified in claim 5 wherein the mesh has a mesh size within the range of 40 to 500.