LINERLESS DOUBLE-SIDED PRESSURE SENSITIVE ADHESIVE TAPE

• US 20040260024A1
• Filed: 06/20/2003
• Published: 12/23/2004
• Est. Priority Date: 06/20/2003
• Status: Active Grant

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Momchilovich, Bradley S., Stark, Peter A., Gehlsen, Mark D.
• Granted Patent: US 6,864,322 B2
• Time in Patent Office: Days
• US Class Current: 525/227
• CPC Class Codes: C09J 2301/124 the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
• CPC Class Codes: C09J 2301/1242 the opposite adhesive layers being different
• CPC Class Codes: C09J 2433/00 Presence of (meth)acrylic polymer
• CPC Class Codes: C09J 2433/006 in the substrate
• CPC Class Codes: C09J 7/22 Plastics; Metallised plastics
• CPC Class Codes: C09J 7/26 Porous or cellular plastics
• CPC Class Codes: C09J 7/38 Pressure-sensitive adhesives [PSA]
• CPC Class Codes: Y10T 428/1457 Silicon
• CPC Class Codes: Y10T 428/28 Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• CPC Class Codes: Y10T 428/2887 including nitrogen containing polymer [e.g., polyacrylonitrile, polymethacrylonitrile, etc.]
• CPC Class Codes: Y10T 428/2891 including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof

Abstract

The present invention relates to a double-sided pressure sensitive adhesive foam tape. In certain embodiments the foam tape does not require the use of a release liner. Elimination of the release liner reduces the cost of the tape and also avoids problems associated with damage to the liner during traditional tape manufacturing from exposure to e-beam radiation.

Claims

1. A double-sided foam tape, the foam tape comprising:

a foam core having first and second opposed surfaces, the foam core comprising an acidic polymer derived from a first group of monomers comprising at least one acidic monomer, and a basic polymer derived from a second group of monomers comprising at least one basic monomer;

a first pressure sensitive adhesive applied to the first surface of the foam core; and

a second pressure sensitive adhesive applied to the second surface of the foam core.

2. The double-sided foam tape of claim 1, wherein the acidic polymer is a homopolymer and the basic polymer is a copolymer.

3. The double-sided foam tape of claim 1, wherein the acidic polymer is a copolymer and the basic polymer is a homopolymer.

4. The double-sided foam tape of claim 1, wherein the acidic polymer is a copolymer and the basic polymer is a copolymer.

5. The double-sided foam tape of claim 1, wherein the first and second pressure sensitive adhesives do not substantially adhere to one another.

6. The double-sided foam tape of claim 1, wherein at least one of the first and second group of monomers comprises at least one (meth)acrylate monomer.

7. The double-sided foam tape of claim 1, wherein each of the first and second group of monomers comprises at least one (meth)acrylate monomer.

8. The double-sided foam tape of claim 1, wherein the first group of monomers comprises at least one basic monomer.

9. The double-sided foam tape of claim 1, wherein the second group of monomers comprises at least one acidic monomer.

10. The double-sided foam tape of claim 1, wherein the first group of monomers is essentially free of basic monomers.

11. The double-sided foam tape of claim 1, wherein the second group of monomers is essentially free of acidic monomers.

12. The double-sided foam tape of claim 1, wherein the basic monomer is selected from the group consisting of N,N-dimethylaminopropyl methacrylamide (DMAPMAm), N,N-diethylaminopropyl methacrylamide (DEAPMAm), N,N-dimethylaminoethyl acrylate (DMAA), N,N-diethylaminoethyl acrylate (DEAEA), N,N-dimethylaminopropyl acrylate (DMAPA), N,N-diethylaminopropyl acrylate (DEAPA), N,N-dimethylaminoethyl methacrylate (DMAEMA), N,N-diethylaminoethyl methacrylate (DEAEMA), N,N-dimethylaminoethyl acrylamide (DMAEAm), N,N-dimethylaminoethyl methacrylamide (DMAEMAm), N,N-diethylaminoethyl acrylamide (DEAEAm), N,N-diethylaminoethyl methacrylamide (DEAEMAm), 4-(N,N-dimethylamino)-styrene (DMAS), 4-(N,N-diethylamino)-styrene (DEAS), N,N-dimethylaminoethyl vinyl ether (DMAEVE), N,N-diethylaminoethyl vinyl ether (DEAEVE), vinylpyridine, vinylimidazole, and mixtures thereof.

13. The double-sided foam tape of claim 1, wherein the acidic monomer is selected from the group consisting of an ethylenically unsaturated carboxylic acid, an ethylenically unsaturated sulfonic acid, an ethylenically unsaturated phosphonic acid, and mixtures thereof.

14. The double-sided foam tape of claim 1, wherein at least one of the first and second group of monomers comprises a vinyl monomer.

15. The double-sided foam tape of claim 1, wherein the second group of monomers comprises greater than 15% by weight of basic monomers.

16. The double-sided foam tape of claim 4, wherein one of the acidic copolymer and the basic copolymer comprises up to about 5% by weight of the blend.

17. The double-sided foam tape of claim 1, wherein the first pressure sensitive adhesive comprises acrylic acid.

18. The double-sided foam tape of claim 1, wherein the second pressure sensitive adhesive comprises acrylic acid and acrylonitrile.

20. The double-sided foam tape of claim 16, wherein the foam core comprises an acidic copolymer derived from a first group of monomers comprising at least one acidic monomer, and a basic copolymer derived from a second group of monomers comprising at least one basic monomer.

21. The double-sided foam tape of claim 16, wherein at least one of the first and second group of monomers comprises a vinyl monomer.

22. The double-sided foam tape of claim 16, wherein each of the first and second group of monomers comprises at least one (meth)acrylate monomer.

23. The double-sided foam tape of claim 17, wherein the acidic monomer is selected from the group consisting of an ethylenically unsaturated carboxylic acid, an ethylenically unsaturated sulfonic acid, an ethylenically unsaturated phosphonic acid, and mixtures thereof.

24. The double-sided foam tape of claim 17, wherein the basic monomer is selected from the group consisting of N,N-dimethylaminopropyl methacrylamide (DMAPMAm), N,N-diethylaminopropyl methacrylamide (DEAPMAm), N,N-dimethylaminoethyl acrylate (DMAA), N,N-diethylaminoethyl acrylate (DEAEA), N,N-dimethylaminopropyl acrylate (DMAPA), N,N-diethylaminopropyl acrylate (DEAPA), N,N-dimethylaminoethyl methacrylate (DMAEMA), N,N-diethylaminoethyl methacrylate (DEAEMA), N,N-dimethylaminoethyl acrylamide (DMAEAm), N,N-dimethylaminoethyl methacrylamide (DMAEMAm), N,N-diethylaminoethyl acrylamide (DEAEAm), N,N-diethylaminoethyl methacrylamide (DEAEMAm), 4-(N,N-dimethylamino)-styrene (DMAS), 4-(N,N-diethylamino)-styrene (DEAS), N,N-dimethylaminoethyl vinyl ether (DMAEVE), N,N-diethylaminoethyl vinyl ether (DEAEVE), vinylpyridine, vinylimidazole, and mixtures thereof.

25. The double-sided foam tape of claim 17, wherein the first and second pressure sensitive adhesives do not substantially adhere to one another.

27. The double-sided foam tape of claim 23, wherein the acidic monomer is selected from the group consisting of an ethylenically unsaturated carboxylic acid, an ethylenically unsaturated sulfonic acid, an ethylenically unsaturated phosphonic acid, and mixtures thereof.

28. The double-sided foam tape of claim 23, wherein the basic monomer is selected from the group consisting of N,N-dimethylaminopropyl methacrylamide (DMAPMAm), N,N-diethylaminopropyl methacrylamide (DEAPMAm), N,N-dimethylaminoethyl acrylate (DMAA), N,N-diethylaminoethyl acrylate (DEAEA), N,N-dimethylaminopropyl acrylate (DMAPA), N,N-diethylaminopropyl acrylate (DEAPA), N,N-dimethylaminoethyl methacrylate (DMAEMA), N,N-diethylaminoethyl methacrylate (DEAEMA), N,N-dimethylaminoethyl acrylamide (DMAEAm), N,N-dimethylaminoethyl methacrylamide (DMAEMAm), N,N-diethylaminoethyl acrylamide (DEAEAm), N,N-diethylaminoethyl methacrylamide (DEAEMAm), 4-(N,N-dimethylamino)-styrene (DMAS), 4-(N,N-diethylamino)-styrene (DEAS), N,N-dimethylaminoethyl vinyl ether (DMAEVE), N,N-diethylaminoethyl vinyl ether (DEAEVE), vinylpyridine, vinylimidazole, and mixtures thereof.

19. A double-sided foam tape, the foam tape comprising:

a foam core having first and second opposed surfaces;

a first pressure sensitive adhesive applied to the first surface of the foam core, the first pressure sensitive adhesive comprising acrylic acid; and

a second pressure sensitive adhesive applied to the second surface of the foam core, the second pressure sensitive adhesive comprising acrylic acid and acrylonitrile;

wherein the first and second pressure sensitive adhesives do not substantially adhere to one another; and

wherein the foam core is configured to bond to the first pressure sensitive adhesive and the second pressure sensitive adhesive.

26. A double-sided foam tape, the foam tape comprising:

a foam core having first and second opposed surfaces, the foam core comprising an acidic copolymer derived from a first group of monomers comprising at least one acidic monomer, and a basic copolymer derived from a second group of monomers comprising at least one basic monomer;

a first pressure sensitive adhesive applied to the first surface of the foam core, the first pressure sensitive adhesive comprising acrylic acid; and

a second pressure sensitive adhesive applied to the second surface of the foam core, the second pressure sensitive adhesive comprising acrylic acid and acrylonitrile;

wherein the first and second pressure sensitive adhesives do not substantially adhere to one another.