Electro-convective diffractive device

• US 20040263772A1
• Filed: 06/27/2003
• Published: 12/30/2004
• Est. Priority Date: 06/27/2003
• Status: Active Grant

• Current Assignee: Kent State University
• Original Assignee: Kent State University
• Inventors: Martin, Joshua S., Gleeson, James T.
• Granted Patent: US 7,315,345 B2
• Time in Patent Office: Days
• US Class Current: 349/201
• CPC Class Codes: G02F 1/13743 based on electrohydrodynamic instabilities or domain formation in liquid crystals
• CPC Class Codes: G02F 2201/305 diffraction grating

Abstract

A method for producing a diffraction grating is provided. First, a mixture including nematic liquid crystal, dopant, and polymerizable precursor is introduced between two electrically conductive substrates having alignment layers for inducing orientation of the liquid crystal director. A potential difference is applied across the liquid crystal to cause a spontaneous self-assembly of the liquid crystal into an array of convective rolls. Thereafter, the roll structure is stabilized by the creation of a polymeric network through polymerization and/or cross-linking of the polymerizable precursor. The convective roll structure serves as a template for the formation of the polymeric network.

Claims

1. A tunable diffraction grating comprising:

a cell with a first cell wall spaced from a second cell wall;

electrodes disposed on facing surfaces of the first and second cell walls; and

an array of nematic liquid crystal convective rolls, wherein said convective rolls are arranged periodically in a space between said first cell wall and said second cell wall; and

a polymeric network stabilizing said array of nematic liquid crystal convective rolls.

2. The tunable diffraction grating of claim 1, wherein the convective rolls are arranged with a grating spacing approximately twice the separation distance between said first and second cell walls.

3. The tunable diffraction grating of claim 1, further comprising:

a power source connected to said electrodes to apply an electric field, wherein said convective rolls are arranged with a structure factor, and said structure factor is adjusted by application of an electric field though said power source.

4. A method for producing a diffraction grating comprising the steps of:

introducing a polymerizable mixture including nematic liquid crystal, dopant, and polymerizable precursor between two electrically conductive substrates;

applying a potential difference across the polymerizable mixture to cause the nematic liquid crystal to assemble into an array of convective rolls; and

stabilizing the convective roll structure by forming a polymer network from the polymerizable precursor, wherein the polymer network is bounded by the convective roll structure.

5. The method according to claim 4, wherein the polymerizable mixture further includes an initiator, said initiator being activated in said step of stablizing to initiate the formation of the polymer network from the polymerizable precursor.

6. The method according to claim 5, wherein the initiator is a photoinitiator and said step of stabilizing includes photoinitiation of the photoinitiator.

7. The method according to claim 4, wherein said convective rolls are arranged with a structure factor after said step of stabilizing, and the method further comprises, after said step of stabilizing:

adjusting the structure factor by application of an electric field though at least one of the electrically conductive substrates.