Articles comprising aqueous dispersions of polyureaurethanes
First Claim
1. A film prepared from a urea/urethane polymer comprising (a) repeating units derived from a hydroxy-terminated copolymer prepared from tetrahydrofuran and one or both of an alkylene oxide and a cyclic acetal and (b) repeating units derived from a polyisocyanate;
- wherein the urea/urethane polymer contains less than about 2 mole percent of urea units described by the formula —
R—
N(R2)—
C(O)—
N(R2)—
R1 —
;
wherein R is an aromatic hydrocarbon radical, R1 is an aliphatic hydrocarbon radical, and R2 is H or an amide group that is described by the formula —
C(O)—
N(R 2)—
R —
; and
wherein the tetrahydrofuran is described by the formula in which any one of the R4s may be a C1 to C4 alkyl radical with the remaining R4s being hydrogen.
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Accused Products
Abstract
Stable aqueous poly(urea/urethane) polymers and dispersions are made that do not require the inclusion of chain extenders, curing agents or crosslinking agents. The disclosed poly(urea/urethane) dispersions can be used to make articles such as films and gloves with reduced chance of chemical and biological allergic reaction to skin, and which exhibit improved puncture and tear resistance when compared to such articles made with other materials.
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Citations
29 Claims
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1. A film prepared from a urea/urethane polymer comprising (a) repeating units derived from a hydroxy-terminated copolymer prepared from tetrahydrofuran and one or both of an alkylene oxide and a cyclic acetal and (b) repeating units derived from a polyisocyanate;
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wherein the urea/urethane polymer contains less than about 2 mole percent of urea units described by the formula —
R—
N(R2)—
C(O)—
N(R2)—
R1 —
;
wherein R is an aromatic hydrocarbon radical, R1 is an aliphatic hydrocarbon radical, and R2 is H or an amide group that is described by the formula —
C(O)—
N(R 2)—
R —
; and
wherein the tetrahydrofuran is described by the formula in which any one of the R4s may be a C1 to C4 alkyl radical with the remaining R4s being hydrogen. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 28, 29)
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10. A film prepared from an ionomeric urea/urethane polymer comprising (a) repeating units derived from an aliphatic polyether polyol having a molecular weight of about 700 to about 1500, and (b) repeating units derived from a polyisocyanate,
wherein the urea/urethane polymer contains less than about 2 mole percent of urea units described by the formula — - R—
N(R2)—
C(O)—
N(R2)—
R1—
;
wherein R is an aromatic C6-C20 hydrocarbon radical, R1 is an aliphatic C1-C20 hydrocarbon radical, and R2 is H or an amide group that is described by the formula —
C(O)—
N(R2)—
R —
. - View Dependent Claims (11, 12, 13, 14, 15, 16, 17, 18, 19)
- R—
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20. A film prepared from an ionomeric urea/urethane polymer comprising (a) repeating units derived from an aliphatic polyester polyol, and (b) repeating units derived from a polyisocyanate,
wherein the urea/urethane polymer contains less than about 2 mole percent of urea units described by the formula — - R—
N(R2)—
C(O)—
N(R2)—
R1;
wherein R is a C6-C20 aromatic hydrocarbon radical, R1 is a C1-C20 aliphatic hydrocarbon radical, and R2 is H or an amide group that is described by the formula C(O)—
N(R2)—
R —
. - View Dependent Claims (21, 22, 23, 24, 25, 26, 27)
- R—
Specification