Thermosettable compositions useful for producing structural adhesive foams
First Claim
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1. A storage-stable one-part expandable thermosettable composition useful for producing a structural adhesive foam comprising:
- (a) at least one adduct of at least one isocyanate resin and at least one epoxy resin bearing at least one isocyanate-reactive functional group per molecule;
(b) one or more blowing agents, wherein said blowing agents are latent blowing agents which are only activated upon heating to an elevated temperature but which remain inactive at normal storage temperatures; and
(c) one or more epoxy curatives, wherein said epoxy curatives are latent curatives that activate only upon heating to an elevated temperature but which do not catalyze curing of the thermosettable composition to any significant extent at normal storage temperatures.
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Abstract
The use of an adduct of an isocyanate resin and an isocyanate-reactive epoxy resin in an expandable thermosettable composition helps to reduce the tackiness of the composition and also increases its dimensional stability, as compared to compositions in which only non-adducted epoxy resins are present.
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Citations
31 Claims
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1. A storage-stable one-part expandable thermosettable composition useful for producing a structural adhesive foam comprising:
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(a) at least one adduct of at least one isocyanate resin and at least one epoxy resin bearing at least one isocyanate-reactive functional group per molecule;
(b) one or more blowing agents, wherein said blowing agents are latent blowing agents which are only activated upon heating to an elevated temperature but which remain inactive at normal storage temperatures; and
(c) one or more epoxy curatives, wherein said epoxy curatives are latent curatives that activate only upon heating to an elevated temperature but which do not catalyze curing of the thermosettable composition to any significant extent at normal storage temperatures. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 29, 30)
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21. A storage-stable one-part expandable thermosettable composition useful for producing a structural adhesive foam comprising:
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(a) at least one adduct of at least one isocyanate resin having at least two isocyanate groups per molecule and at least one liquid or semi-solid epoxy resin bearing at least one hydroxyl group per molecule, wherein said at least one liquid or semi-solid epoxy resin is a glycidyl ether of bisphenol A;
(b) one or more blowing agents, wherein said blowing agents are latent blowing agents which are only activated upon heating to an elevated temperature but which remain inactive at normal storage temperatures;
(c) one or more epoxy curatives, wherein said epoxy curatives are latent curatives that activate only upon heating to an elevated temperature but which do not catalyze curing of the thermosettable composition to any significant extent at normal storage temperature; and
(d) one or more additional components selected from the group consisting of;
(i) urethane catalysts;
(ii) hollow glass microspheres;
(iii) rubbers;
(iv) adhesion promoters;
(v) fillers;
(vi) thixotropic agents; and
(vii) epoxy resins other than said at least one liquid or semi-solid epoxy resin adducted with said isocyanate resin. - View Dependent Claims (22, 23, 24, 25, 26, 27)
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28. A storage-stable one-part expandable thermosettable composition useful for producing a structural adhesive foam comprising;
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(a) 40 to 70 wt % of one or more epoxy resins;
(b) 0.5 to 8 wt % of one or more blowing agents, wherein said blowing agents are latent blowing agents which are only activated upon heating to an elevated temperature but which remain inactive at normal storage temperatures;
(c) 0.5 to 5 wt % of one or more isocyanate resins;
(d) 1 to 10 wt % of one or more epoxy curatives, wherein said epoxy curatives are latent curatives that activate only upon heating to an elevated temperature but which do not catalyze curing of the thermosettable composition to any significant extent at normal storage temperature;
(e) 1 to 10 wt % of one or more rubbers;
(f) 0.01 to 1 wt % of one or more adhesion promoters;
(g) 0.01 to 0.5 wt % of one or more urethane catalysts;
(h) 0 to I wt % of one or more blowing agent accelerators;
(i) 10 to 40 wt % of hollow glass microspheres;
(j) 1 to 20 wt % of one of more fillers; and
(k) 0.1 to 5 wt % of one or more thixotropic agents;
wherein at least a portion of the epoxy resins are liquid or semi-solid epoxy resins having at least one isocyanate-reactive functional group per molecule which have been reacted with at least a portion of the isocyanate resins to form an adduct.
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31. A method of making a storage-stable one-part expandable thermosettable composition useful for producing a structural adhesive foam, said method comprising:
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(a) combining at least one liquid or semi-solid epoxy resin bearing at least one isocyanate-reactive functional group, one or more blowing agents, wherein said blowing agents are latent blowing agents which are only activated upon heating to an elevated temperature but which remain inactive at normal storage temperature, and one or more epoxy curatives, wherein said epoxy curatives are latent curatives that activate only upon heating to an elevated temperature but which do not catalyze curing of the thermosettable composition to any significant extent at normal storage temperature, to form a uniform mixture; and
(b) reacting at least a portion of the liquid or semi-solid epoxy resin in said mixture with at least one isocyanate resin to form an adduct.
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Specification