Nanophase multilayer barrier and process

• US 20050051763A1
• Filed: 09/04/2004
• Published: 03/10/2005
• Est. Priority Date: 09/05/2003
• Status: Abandoned Application

• Current Assignee: Helicon Research LLC
• Original Assignee: Helicon Research LLC
• Inventors: Affinito, John David, Hilliard, Donald Bennett
• Application Number:
  US10/934,530
• Publication Number:
  US 20050051763A1
• Time in Patent Office: Days
• US Class Current: 257/3
• CPC Class Codes: G02F 1/133305 Flexible substrates, e.g. plastics, organic film
• CPC Class Codes: G02F 1/133345 Insulating layers G02F1/1335, G02F1/1337, G02F1/135, G02F1/136 take precedence
• CPC Class Codes: H10K 2102/311 Flexible OLED
• CPC Class Codes: H10K 50/8445 multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers
• CPC Class Codes: H10K 59/8731 multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers

Abstract

A thin film barrier structure and process is disclosed, which is seen as particularly useful for use in devices that require protection from such common environmental species as oxygen and water. The disclosed barrier structure is of particular utility for such devices as implemented on flexible substrates, such as may be desirable for OLED-based or LCD-based devices. The disclosed barrier structure provides superior barrier properties, flexibility, as well as commercial-scale reproducibility, through the use of a novel organic/inorganic nanocomposite structure formed by infiltration of a porous inorganic layer by an organic material. The composite structure is produced by vacuum deposition techniques in the first preferred embodiment.

Claims

1. A barrier layer, the layer comprising:

a.) a porous inorganic material deposited onto a substrate; and

,

b.) an organic material infiltrated into the porous inorganic material, so that a continuous layer is formed, the layer having barrier properties.

2. The barrier layer of claim 1, wherein the layer is repeated to form a multilayer barrier structure.

3. The barrier layer of claim 1, wherein the layer has a graded composition.

4. The barrier layer of claim 1, wherein the layer may be subjected to increased bending of the structure without degradation of barrier properties.

5. The barrier layer of claim 1, wherein the layer provides improved fracture resistance over previous barriers.

6. The barrier layer of claim 1, wherein the layer may be subjected to an increased number of flexing cycles without degradation of barrier properties.

7. The barrier layer of claim 1, wherein the layer may be subjected to an increased humidity cycling without degradation of barrier properties.

8. The barrier layer of claim 1, wherein the layer may be subjected to an increased thermal cycling without degradation of barrier properties.

9. The barrier layer of claim 1, wherein the layer provides improved adhesion to a subsequent layer.

10. The barrier layer of claim 1, wherein surface mobility of a condensable species is substantially reduced.

11. The barrier layer of claim 1, wherein permeation is limited by eliminating surface states residing within the inorganic layer.

12. The barrier layer of claim 1, wherein the structure contains an amorphous phase, a crystalline phase, or mixtures thereof.

13. The barrier layer of claim 1, wherein the porous inorganic material comprises at least one compound selected from the following:

oxides, nitrides, fluorides, carbides, borides, phosphates, sulfates, silicates, selenides, lanthanides, cuprates, cobaltites, magnatites, tellurides, and arsenates.

14. The barrier layer of claim 1, wherein the layer possesses feature sizes between several angstroms and hundreds of angstroms.

15. The barrier layer of claim 1, wherein the organic material is an electrically conducting polymer.

16. The barrier layer of claim 1, wherein the inorganic material is electrically conducting.

17. The barrier layer of claim 1, wherein the layer is used for manufacture of flexible displays.

18. A process for forming a barrier layer, comprising the steps:

a.) providing a substrate;

b.) depositing a porous inorganic material onto the substrate;

c.) infiltrating the porous inorganic material with a monomer; and

d.) providing curing means for polymerizing the monomer, thereby transforming the porous material and the monomer into the barrier layer, so that the layer has low-permeability characteristics.

19. The process of claim 18, further comprising a smoothing step, wherein excess condensed monomer is re-volatilized as a result of not sharing inorganic-organic bonds.

20. The process of claim 18, further comprising means to repeat the process for producing a multilayer barrier structure.

21. The process of claim 18, further comprising activation means, the activation means for increasing infiltration of the porous material.

22. The process of claim 18, further comprising means for depositing a polymer layer over the barrier layer.

23. The process of claim 18, further comprising means for cooling the substrate.

24. The process of claim 18, further comprising means for positioning the substrate.

25. The process of claim 18, wherein the substrate is a thin flexible polymer.

26. The process of claim 18, wherein the process is used in the manufacture of flexible displays.

27. An organic semiconductor device, comprising:

a.) a substrate;

b.) a semiconductor material deposited onto the substrate,

c.) a porous inorganic material deposited over the semiconductor material; and

,

d.) an organic material infiltrated into the porous inorganic material so that a continuous barrier layer is formed over the semiconductor material, the layer thereby having barrier properties.

28. The organic semiconductor device of claim 27, wherein the device is an organic light-emitting diode.

29. The organic semiconductor device of claim 27, wherein the device is an organic switching device.

30. The organic semiconductor device of claim 27, wherein the barrier layer is part of a multilayer barrier.

31. The organic semiconductor device of claim 27, wherein the substrate includes a substrate layer, the substrate layer formed similarly to the barrier layer.

32. The organic semiconductor device of claim 27, wherein the substrate is a flexible material.

33. The organic semiconductor device of claim 27, wherein additional layers are formed between the semiconductor material and the barrier layer.

34. The organic semiconductor device of claim 27, wherein the substrate comprises a multitude of substrate layers that are each formed similarly to the barrier layer.

35. The organic semiconductor device of claim 27, wherein the device is a flexible display device.