Fuel cell bipolar separator plate

• US 20050064270A1
• Filed: 09/24/2003
• Published: 03/24/2005
• Est. Priority Date: 09/24/2003
• Status: Abandoned Application

• Current Assignee: Gas Technology Institute
• Original Assignee: Gas Technology Institute
• Inventors: Marianowski, Leonard G.
• Application Number:
  US10/669,242
• Publication Number:
  US 20050064270A1
• Time in Patent Office: Days
• US Class Current: 429/434
• CPC Class Codes: H01M 8/0206 Metals or alloys
• CPC Class Codes: H01M 8/021 Alloys based on iron
• CPC Class Codes: H01M 8/0228 in the form of layered or coated products
• CPC Class Codes: H01M 8/0247 characterised by the form characterised by a channel configuration H01M8/0258
• CPC Class Codes: H01M 8/0254 corrugated or undulated
• CPC Class Codes: H01M 8/0258 characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
• CPC Class Codes: H01M 8/026 characterised by grooves, e.g. their pitch or depth
• CPC Class Codes: H01M 8/0267 having heating or cooling means, e.g. heaters or coolant flow channels
• CPC Class Codes: H01M 8/0297 Arrangements for joining electrodes, reservoir layers, heat exchange units or bipolar separators to each other H01M8/0271 takes precedence
• CPC Class Codes: H01M 8/1007 with both reactants being gaseous or vaporised H01M8/12 takes precedence
• CPC Class Codes: H01M 8/241 with solid or matrix-supported electrolytes
• CPC Class Codes: H01M 8/2483 characterised by internal manifolds
• CPC Class Codes: H01M 8/249 comprising two or more groupings of fuel cells, e.g. modular assemblies
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A bipolar separator plate for a fuel cell stack constructed of at least two coextensive sheet metal elements shaped to promote the distribution of reactant gases to the electrodes of the fuel cell units of the fuel cell stack. The coextensive sheet metal elements are corrugated and fitted together to form at least one coolant flow channel between corresponding peaks, or valleys, of the corrugations of the sheet metal elements.

Claims

1. In a fuel cell stack comprising a plurality of substantially planar fuel cell units, each said fuel cell unit having an anode electrode, a cathode electrode, and an electrolyte disposed therebetween, and a separator plate disposed between said anode electrode of one said fuel cell unit and said cathode electrode of an adjacent said fuel cell unit, said separator plate comprising guide means for distributing fuel and oxidant to said anode electrode and said cathode electrode, respectively, the improvement comprising:

said separator plate constructed of at least two substantially coextensive sheet metal elements having a substantially flat peripheral region and a central region comprising a plurality of substantially uniform corrugations, said corrugations of a first of said sheet metal elements and a second of said sheet metal elements having substantially equal peak-to-peak distances and said corrugations of said first of said sheet metal elements having a peak-to-valley distance greater than said corrugations of said second of said sheet metal elements; and

said sheet metal elements aligned whereby each corrugation valley of each said corrugation of said first of said sheet metal elements contacts a corresponding corrugation valley of said second of said sheet metal elements, forming a coolant flow channel between each corrugation peak of said corrugations of said first of said sheet metal elements and a corresponding corrugation peak of said corrugations of said second of said sheet metal elements.

2. A fuel cell stack in accordance with claim 1, wherein said fuel cell unit is a fuel cell type selected from the group consisting of molten carbonate, solid oxide, phosphoric acid and polymer electrolyte membrane.

3. A fuel cell stack in accordance with claim 1, wherein said at least two sheet metal elements are constructed of a material selected from the group consisting of nickel, stainless steel, high alloy steel, titanium and metals coated to prevent corrosion.

4. A fuel cell stack in accordance with claim 2, wherein said fuel cell unit is a polymer electrolyte membrane fuel cell.

5. A fuel cell stack in accordance with claim 4, wherein said at least two sheet metal elements are constructed of a chromium-nickel austenitic alloy comprising on a combined basis at least about 50% by weight chromium and nickel.

6. A fuel cell stack in accordance with claim 1 further comprising a plurality of internal manifolds for supplying said fuel and oxidant to each of said fuel cell units and for removal of exhaust gases therefrom and for providing coolant to said coolant flow channels.

7. A fuel cell stack in accordance with claim 1, wherein said corrugation valleys have an arcuate profile.

8. In a fuel cell stack comprising a plurality of fuel cell units, each said fuel cell unit having an electrolyte-electrode-assembly with an anode electrode on one face and a cathode electrode on an opposite face, an anode current collector on said anode electrode side of said electrolyte-electrode-assembly and a cathode current collector on said cathode side of said electrolyte-electrode-assembly, and a separator plate disposed between said anode electrode side of said electrolyte-electrode-assembly of one said fuel cell unit and said cathode electrode side of said electrolyte-electrode-assembly of an adjacent said fuel cell unit having guide means for distributing fuel and oxidant gases to said anode electrode side and said cathode electrode side and forming an anode chamber between the anode electrode facing face of said separator plate and said anode electrode and forming a cathode chamber between the opposite cathode electrode facing face of said separator plate and the cathode electrode of an adjacent said fuel cell unit, said anode chamber in gas communication with a fuel gas supply and outlet and said cathode chamber in gas communication with an oxidant gas supply and outlet, the improvement comprising:

said separator plate constructed of at least two substantially coextensive sheet metal elements having a substantially fiat peripheral region and a central region comprising a plurality of substantially uniform corrugations, said corrugations of a first of said sheet metal elements and a second of said sheet metal elements having substantially equal peak-to-peak distances and said corrugations of said first of said sheet metal elements having a peak-to-valley distance greater than said corrugations of said second of said sheet metal elements;

said sheet metal elements aligned whereby each corrugation valley of each said corrugation of said first of said sheet metal elements contacts a corresponding corrugation valley of said second of said sheet metal elements, forming a coolant flow channel between each corrugation peak of said corrugations of said first of said sheet metal elements and a corresponding corrugation peak of said corrugations of said second of said sheet metal elements;

said separator plates having a flattened peripheral seal structure extending to contact one of said electrolyte-electrode-assemblies and said current collectors on each face of said separator plates completely around said anode chamber and said cathode chamber, respectively, forming a peripheral seal under cell operating conditions;

said electrolyte-electrode-assemblies and said separator plates each having a plurality of aligned perforations, said perforations in said separator plates being surrounded on said anode electrode facing face and said cathode electrode facing side by a flattened manifold seal structure extending to contact one of said electrolyte-electrode-assemblies and said current collectors on said anode electrode facing sides and said cathode electrode facing sides of said separator plates, forming a manifold seal under cell operating conditions to form a plurality of fuel gas and oxidant gas manifolds extending through said cell stack;

fuel conduits through said flattened manifold seal structure providing fuel gas communication between said fuel gas manifolds and said anode chambers on said anode electrode facing side of said separator plates, thereby providing fully internal manifolding of fuel to and from each said fuel cell unit in said fuel cell stack; and

oxidant conduits through said flattened manifold seal structure providing oxidant gas communication between said oxidant gas manifolds and said cathode chambers on said cathode electrode facing side of said separator plates, thereby providing fully internal manifolding of oxidant to and from each said fuel cell unit in said fuel cell stack.

9. A fuel cell stack in accordance with claim 8, wherein said separator plates and said electrolyte-electrode-assemblies form a plurality of aligned coolant fluid openings, said openings in said separator plates being surrounded on said anode electrode facing face and said cathode electrode facing side by a flattened coolant fluid manifold seal structure extending to contact one of said electrolyte-electrode-assemblies and said current collectors on said anode electrode facing sides and said cathode electrode facing sides of said separator plates, forming a coolant fluid manifold seal under cell operating conditions to form a plurality of coolant fluid manifolds extending through said cell stack.

10. A fuel cell stack in accordance with claim 8, wherein said fuel cell unit is a fuel cell type selected from the group consisting of molten carbonate, solid oxide, phosphoric acid and polymer electrolyte membrane.

11. A fuel cell stack in accordance with claim 8, wherein said at least two sheet metal elements are constructed of a material selected from the group consisting of nickel, stainless steel, high alloy steel, titanium and metals coated to prevent corrosion.

12. A fuel cell stack in accordance with claim 10, wherein said fuel cell unit is a polymer electrolyte membrane fuel cell.

13. A fuel cell stack in accordance with claim 12, wherein said at least two sheet metal elements are constructed of a chromium-nickel austenitic alloy comprising on a combined basis at least about 50% by weight chromium and nickel.

14. A fuel cell stack in accordance with claim 8, wherein said corrugation valleys have an arcuate profile.