Piezoelectric ceramic-reinforced metal matrix composites

• US 20050073222A1
• Filed: 05/21/2004
• Published: 04/07/2005
• Est. Priority Date: 05/23/2003
• Status: Active Grant

• Current Assignee: Virginia Tech Intellectual Properties, Inc. (Virginia Polytechnic Institute and State University)
• Original Assignee: Virginia Tech Intellectual Properties, Inc. (Virginia Polytechnic Institute and State University)
• Inventors: Schultz, Jeffrey Patrick, Goff, Adam, Kampe, Stephen L., Franklin, Jennifer, Aning, Alexander O.
• Granted Patent: US 7,126,257 B2
• Time in Patent Office: Days
• US Class Current: 310/358
• CPC Class Codes: C22C 32/00 Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
• CPC Class Codes: G10K 11/165 Particles in a matrix
• CPC Class Codes: H10N 30/852 Composite materials, e.g. having 1-3 or 2-2 type connectivity

Abstract

Composite materials comprising piezoelectric ceramic particulates dispersed in a metal matrix are capable of vibration damping. When the piezoelectric ceramic particulates are subjected to strain, such as the strain experienced during vibration of the material, they generate an electrical voltage that is converted into Joule heat in the surrounding metal matrix, thereby dissipating the vibrational energy. The piezoelectric ceramic particulates may also act as reinforcements to improve the mechanical properties of the composites. The composite materials may be used in various structural components in vehicles, aircraft, spacecraft, buildings and tools.

Claims

1. A composite material comprising a metal matrix and piezoelectric ceramic particulates dispersed in the metal matrix.

2. The composite material of claim 1, wherein the piezoelectric ceramic particulates comprise at least one oxide of a metal comprising Ba, Sr, Ca, Pb, Ti, Zr and/or Nb.

3. The composite material of claim 1, wherein the piezoelectric ceramic particulates comprise BaTiO₃, ZnO, PbTiO₃, Pb(Ti,Zr)O₃, Pb(Mg⅓

Nb⅔

)O₃ and/or Pb(La,Ti,Zr)O₃.

4. The composite material of claim 1, wherein the piezoelectric ceramic particulates comprise BaTiO₃.

5. The composite material of claim 1, wherein the piezoelectric ceramic particulates comprise from about 5 to about 65 volume percent of the composite.

6. The composite material of claim 1, wherein the piezoelectric ceramic particulates comprise from about 20 to about 50 volume percent of the composite.

7. The composite material of claim 1, wherein the piezoelectric ceramic particulates are substantially equiaxed.

8. The composite material of claim 1, wherein the piezoelectric ceramic particulates are substantially elongated.

9. The composite material of claim 1, wherein the piezoelectric ceramic particulates are substantially disc shaped.

10. The composite material of claim 1, wherein the piezoelectric ceramic particulates have an average particle size of from about 0.5 microns to about 2 mm.

11. The composite material of claim 1, wherein the piezoelectric ceramic particulates have an average particle size of from about 0.5 microns to about 100 microns.

12. The composite material of claim 1, wherein the piezoelectric ceramic particulates have a piezoelectric coefficient, d, greater than 2×

10<sup>−

12</sup> V·

m<sup>−

1</sup>.

13. The composite material of claim 1, wherein the piezoelectric ceramic particulates have an electromechanical coupling factor, k, greater than 0.1.

14. The composite material of claim 1, wherein the metal matrix comprises Cu, Al, Fe, Pb, Mg, Ni, Ti, Co, Mo, Ta, Nb, W, Ni and/or Sn.

15. The composite material of claim 1, wherein the metal matrix comprises Cu, Sn, Ti, Al, Fe, Ni and/or Co.

16. The composite material of claim 1, wherein the metal matrix comprises from about 35 to about 95 volume percent of the composite.

17. The composite material of claim 1, wherein the metal matrix comprises from about 50 to about 80 volume percent of the composite.

18. The composite material of claim 1, wherein the metal matrix has a thermal conductivity of at least 5 W/m·

K.

19. The composite material of claim 1, wherein the metal matrix has a yield strength of at least 20 MPa.

20. The composite material of claim 1, wherein the metal matrix has a fracture toughness of at least 8 MPa{square root}m.

21. The composite material of claim 1, wherein the composite material has a vibration damping loss coefficient of greater than 1×

10<sup>−

4</sup>.

22. The composite material of claim 1, wherein the piezoelectric ceramic particulates have polarization vectors that are randomly oriented in each particulate.

23. The composite material of claim 1, wherein the piezoelectric ceramic particulates have polarization vectors that are at least partially aligned within each particulate.

24. The composite material of claim 23, wherein the piezoelectric ceramic particulates are randomly oriented within the metal matrix.

25. The composite material of claim 23, wherein the polarization vectors of the piezoelectric ceramic particulates are at least partially aligned with respect to the composite.

26. A vibration damping structural component comprising a composite material including a metal matrix and piezoelectric ceramic particulates dispersed in the metal matrix.

27. A method of making a vibration damping composite material comprising dispersing piezoelectric ceramic particulates in a metal matrix.

28. A method of damping vibrations in a structural component comprising forming at least a part of the structural component from a composite material comprising a metal matrix and piezoelectric ceramic particulates in the metal matrix.