Highlightable and highlighted mixtures, marking instruments, and methods of using the same

• US 20050120919A1
• Filed: 10/01/2004
• Published: 06/09/2005
• Est. Priority Date: 10/07/2003
• Status: Active Grant

• Current Assignee: Sanford LP (Newell Brands Inc.)
• Original Assignee: Sanford LP (Newell Brands Inc.)
• Inventors: Sum, Vincent Wing, Davies-Smith, Leighton
• Granted Patent: US 7,427,318 B2
• Time in Patent Office: Days
• US Class Current: 106/487
• CPC Class Codes: C09D 11/037 characterised by the pigment
• CPC Class Codes: C09D 11/17 characterised by colouring agents
• CPC Class Codes: C09D 11/18 specially adapted for ball-point writing instruments
• CPC Class Codes: C09D 11/32 characterised by colouring agents

Abstract

A highlightable mixture, such as an ink, including a colored pigment, an eradicable colorant, and a non-eradicable colorant; a kit including the highlightable mixture and an eradicator solution; colorant complex including a colorless or substantially colorless eradicable dye selected from the group consisting of diarylmethane derivatives, triarylmethane derivatives, and methine dyes, and a colored pigment; and methods of applying an eradicator to at least a portion of a marking made with a highlightable mixture, are described herein.

Claims

1. A mixture, comprising water, a colored pigment, a non-eradicable dye, and an eradicable dye selected from the group consisting of diarylmethane derivatives, triarylmethane derivatives, methine dyes, and combinations thereof.

2. The mixture of claim 1, wherein the color of said colored pigment is substantially unaffected by a reducing agent.

3. The mixture of claim 2, wherein said reducing agent comprises a compound selected from the group consisting of a sulfite reducing agent, a bisulfite reducing agent, and combinations thereof.

4. The mixture of claim 1, wherein said mixture is black.

5. The mixture of claim 1,.wherein said eradicable dye is selected from the group consisting of Basic Yellow 2, Basic Yellow 11, Basic Yellow 13, Basic Yellow 21, Basic Yellow 28, Basic Yellow 29, Basic Yellow 40, Acid Blue 22, Acid Blue 93, Acid Green, Acid Green 5, Acid Violet 17, Acid Violet 19, Basic Blue 8, Basic Blue 15, Basic Blue 20, Basic Blue 26, Basic Green 4, Basic Red 9, Basic Red 14, Basic Red 15, Basic Red 29, Basic Red 46, Basic Violet 2, Basic Violet 3, Basic Violet 4, Basic Violet 14, Food Green 3, and combinations thereof.

6. The mixture of claim 1, wherein said eradicable dye is present in an amount at least about 0.01% and up to about 40% by weight based on the total weight of the mixture.

7. The mixture of claim 6, wherein said eradicable dye is present in an amount at least about 0.1 % and up to about 10% by weight based on the total weight of the mixture.

8. The mixture of claim 1, wherein said colored pigment is present in an amount at least about 0.01% and up to about 50% by weight based on the total weight of the mixture.

9. The mixture of claim 8, wherein said colored pigment is present in an amount at least about 0.1 % and up to about 20% by weight based on the total weight of the mixture.

10. The mixture of claim 1, wherein said non-eradicable dye is selected from the group consisting of non-eradicable blue dyes, non-eradicable red dyes, non-eradicable violet dyes, non-eradicable yellow dyes, non-eradicable orange dyes, and combinations of the foregoing.

11. The mixture of claim 10, wherein said non-eradicable dye is selected from the group consisting of Acid Blue 1, Acid Blue 104, Acid Blue 182, Acid Blue 204, Acid Blue 74, Acid Blue 9, Acid Blue 90, Basic Blue 1, Basic Blue 7, Basic Blue 9, Basic Blue 33, Direct Blue 199, Direct Blue 281, Disperse Blue 73, Reactive Blue 19, Reactive Blue 21, Acid Red 18, Acid Red 249, Acid Red 52, Acid Red 87, Acid Red 92, Basic Red 22, Basic Red 28 Basic Red 46, Direct Red 236, Direct Red 252, Acid Violet 12, Acid Violet 126, Acid Violet 17, Acid Violet 49, Basic Violet 1, Basic Violet 10, Basic Violet 3, Acid Yellow 17, Acid Yellow 118, Acid Yellow 23, Acid Yellow 3, Acid Yellow 32, Acid Yellow 36, Basic Yellow 21, Basic Yellow 28, Basic Yellow 37, Basic Yellow 40, Basic Yellow 291, Acid Orange 10, Reactive Orange 16, and combinations thereof.

12. The mixture of claim 11, wherein said non-eradicable dye is selected from the group consisting of Basic Blue 1, Basic Yellow 291, and combinations thereof.

13. The mixture of claim 1, wherein the color of said colored pigment is substantially unaffected by an oxidizing agent.

14. The mixture of claim 1, wherein the color of said colored pigment is substantially unaffected by a change in pH.

15. The mixture of claim 1, further comprising a reducing agent.

16. The mixture of claim 1, further comprising an oxidizing agent.

17. The mixture of claim 1, further comprising a binder resin.

18. The mixture of claim 17, wherein said binder resin is selected from the group consisting of polyethylene glycol, polyvinylpyrrolidone and copolymers and salts thereof, polyvinylacetate and copolymers and salts thereof, polyacrylic acid and copolymers and salts thereof, and combinations of the foregoing.

19. The mixture of claim 1, further comprising an organic solvent.

20. The mixture of claim 19, wherein said organic solvent is selected from the group consisting of glycols, ureas, fatty alcohols, dimethylformamide, formamide, dimethylsulfoxide, high molecular weight hydrocarbons, low molecular weight hydrocarbons, and combinations thereof.

21. The mixture of claim 19, wherein said organic solvent is selected from the group consisting of acetone, methyl ethyl ketone, methanol, ethanol, isopropanol, and combinations thereof.

22. The mixture of claim 19, wherein said organic solvent is present in an amount at least about 5% and up to about 30% by weight based on the total weight of the mixture.

23. The mixture of claim 1, further comprising an additive selected from the group consisting of pH buffers, surfactants, biocides, anti-corrosive agents, sequestering agents, anti-crusting agents, rehology control agents, binder resins, film-forming agents, and combinations thereof.

25. A marking instrument, comprising a writing instrument containing the mixture of claim 1.

26. An marking instrument comprising an ink-jet cartridge containing the mixture of claim 1.

27. A marking instrument, comprising a continuous ink-jet printhead containing the mixture of claim 1.

28. A marking instrument, comprising a drop-on-demand ink-jet printhead containing the mixture of claim 1.

29. The instrument of claim 28, wherein said drop-on-demand ink-jet printhead comprises a printhead selected from the group consisting of a piezoelectric ink-jet printhead, and a thermal, ink-jet printhead.

30. A method of highlighting, comprising the steps of contacting the mixture of claim 1 and a substrate to make a mark, and applying an eradicator fluid to at least a portion of said mark.

31. The method of claim 30, wherein said substrate is paper.

32. The method of claim 31, wherein said paper comprises non-porous paper.

33. The method of claim 30, wherein said eradicator fluid comprises a compound selected from the group consisting of a sulfite, a bisulfite, and combinations thereof.

34. A highlighting kit, comprising the mixture of claim 1 and an eradicator fluid.

35. The highlighting kit of claim 34, wherein said eradicator fluid comprises a reducing agent.

36. The highlighting kit of claim 35, wherein said reducing agent comprises a compound selected from the group consisting of a sulfite reducing agent, a bisulfite reducing agent, and combinations thereof.

37. The highlighting kit of claim 34, wherein said eradicator fluid comprises an oxidizing agent.

24. A mixture, comprising water, a colored pigment in an amount at least about 0.01% and up to about 50% by weight based on the total weight of the mixture, a non-eradicable dye, an eradicable dye in an amount at least about 0.01% and up to about 40% by weight based on the total weight of the mixture, said eradicable dye selected from the group consisting of diarylmethane derivatives, triarylmethane derivatives, methine dyes, and combinations thereof, and a binder resin, wherein the color of said colored pigment is substantially unaffected by one or more of an oxidizing agent, a reducing agent, and a change in pH.

38. A highlighted complex, comprising a mixture of a colorless or substantially colorless eradicable dye selected from the group consisting of diarylmethane derivatives, triarylmethane derivatives, methine dyes, and combinations thereof, a non-eradicable dye, and a colored pigment.