High-strength dental restorations

• US 20050127544A1
• Filed: 10/08/2004
• Published: 06/16/2005
• Est. Priority Date: 06/12/1998
• Status: Abandoned Application

• Current Assignee: Ardent, Inc. (Ivoclar Vivadent AG)
• Original Assignee: Ardent, Inc. (Ivoclar Vivadent AG)
• Inventors: Panzera, Paul, Zammarieh, Elie, Brodkin, Dmitri, Panzera, Carlino, Karmaker, Ajit, Prasad, Arun, Schulman, Martin L., Daskalon, Gregg
• Application Number:
  US10/961,307
• Publication Number:
  US 20050127544A1
• Time in Patent Office: Days
• US Class Current: 264/16
• CPC Class Codes: A61C 13/26 Dentures without palates; Partial dentures, e.g. bridges
• CPC Class Codes: A61K 6/71 Fillers
• CPC Class Codes: A61K 6/807 comprising magnesium oxide
• CPC Class Codes: A61K 6/816 comprising titanium oxide
• CPC Class Codes: A61K 6/818 comprising zirconium oxide
• CPC Class Codes: A61K 6/822 comprising rare earth metal oxides
• CPC Class Codes: A61K 6/833 Glass-ceramic composites
• CPC Class Codes: A61K 6/887 Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C03B 19/06 by sintering, e.g. by cold isostatic pressing of powders and subsequent sintering, by hot pressing of powders, by sintering slurries or dispersions not undergoing a liquid phase reaction
• CPC Class Codes: C03B 32/02 Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles C03B27/012 takes precedence
• CPC Class Codes: C03C 10/0027 containing SiO2, Al2O3, Li2O as main constituents
• CPC Class Codes: C03C 3/097 containing phosphorus, niobium or tantalum
• CPC Class Codes: C03C 3/112 containing fluorine
• CPC Class Codes: C03C 3/118 containing aluminium
• CPC Class Codes: C03C 4/0021 for dental use
• CPC Class Codes: C04B 37/042 in a direct manner
• CPC Class Codes: C08L 33/02 Homopolymers or copolymers of acids; Metal or ammonium salts thereof

Abstract

Lithium disilicate based glass-ceramics contain high strength ceramic components for use in the manufacture of dental products. The glass-ceramics have good pressability, i.e., the ability to be formed into dental products by heat-pressing using commercially available equipment. The strength of the dental articles is increased with the inclusion of the high strength ceramic components.

Claims

1. A lithium disilicate dental product made with glass-ceramic blanks formed by the process comprising:

melting a starting glass composition at temperatures within the range of about 1200 to about 1600°

C.;

forming the molten glass into shaped blanks;

annealing the glass blanks at temperatures in the range of 300°

to about 600°

C. for a time in the range of about 15 minutes to about 8 hours;

subjecting the glass blanks to one or more heat treatments in the temperature range of from about 400°

to about 1100°

C. to convert the glass blanks into glass-ceramic blanks; and

wherein the dental restoration comprises a high strength reinforcing bar.

2. The dental product of claim 1 wherein the high strength reinforcing bar comprises zirconia, alumina, SIALON, mullite, titanium oxide, magnesium oxide and composites or mixtures thereof.

3. The dental product of claim 2 wherein the high strength reinforcing bar comprises a mixture of zirconia and yttria.

4. The dental product of claim 1 wherein the blank comprises a 3-point flexure strength exceeding about 350 MPa.

5. The dental product of claim 4 wherein the 3-point flexure strength is greater than about 370 MPa.

6. The dental product of claim 1 wherein the bar is square, rectangular, triangular, rhomboidal, ovoidal, or cylindrical.

7. The dental product of claim 1 wherein the blank is pressed into the dental product around the high strength reinforcing bar.

8. The dental product of claim 1 wherein crystallization of lithium disilicate is effected in the glass blanks after annealing when subjected to one or more heat treatments in the temperature range of from about 400°

to about 1100°

C.

9. The dental product of claim 1 wherein subjecting the glass blanks to one or more heat treatments in the temperature range of from about 400°

to about 1100°

C. comprises a first nucleation step and a second crystal growth step.

10. The dental product of claim 9 wherein the first nucleation step comprises heating the molten glass to a temperature in the range of about 450°

to about 700°

C.

11. The dental product of claim 9 wherein the second crystal growth step comprises heating the nucleated glass in the range of about 800°

to about 1000°

C.

12. The dental product of claim 9 wherein the first nucleation step comprises heating the molten glass to a temperature in the range of about 500°

to about 650°

C.

13. The dental product of claim 9 wherein the second crystal growth step comprises heating the nucleated glass in the range of about 830°

to about 930°

C.

14. The dental product of claim 9 wherein the first nucleation step comprises about a one hour soak at about 645°

C. and wherein the second crystal growth step comprises about a four hour soak at about 850°

C.

15. The dental product of claim 1 comprising machining the glass-ceramic blanks into the dental products.

16. The dental product of claim 1 wherein the dental product is a dental core and is provided with one or more coatings.

17. The dental product of claim 16 wherein the one or more coatings is selected from a ceramic, a sintered ceramic, a glass-ceramic, a porcelain, a glass, a glaze, a composite and mixtures thereof.

18. The product of claim 16 wherein the one or more coatings has a firing temperature in the range of about 700°

to about 900°

C. and a coefficient of thermal expansion (measured from room temperature to its transition temperature) of within about +2.0×

10<sup>−

6</sup>/°

C. of the dental product (measured at the same temperature range).

19. The dental product of claim 1 formed into a component selected from the group consisting of orthodontic appliances, bridges, space maintainers, tooth replacement appliances, splints, crowns, partial crowns, dentures, posts, teeth, jackets, inlays, onlays, facing, veneers, facets, implants, abutments, cylinders, and connectors.

20. The dental product of claim 1 wherein the high strength reinforcing bar has a shape that approximates the near-net-shape of the final restoration.

21. A lithium silicate dental restoration made with glass-ceramic powder formed by the process comprising:

melting a starting glass composition at temperatures within the range of about 1200°

C. to about 1600°

C.;

quenching the glass melt;

subjecting the quenched glass to one or more heat treatments in the temperature range of from about 400°

C. to about 1100°

C. to convert the glass into a glass-ceramic;

comminuting the glass ceramic to a powder;

forming the powder onto a die to form a dental restoration, wherein the die has a high strength reinforcing bar positioned thereon; and

sintering the formed dental restoration having the high strength reinforcing bar therein.

22. A lithium disilicate dental product made by the process comprising:

melting a starting glass composition at temperatures within the range of about 1200°

C. to about 1600°

C.;

quenching the glass melt;

subjecting the quenched glass to one or more heat treatments in the temperature range of from about 400°

C. to about 1100°

C. to convert the glass into a glass-ceramic;

comminuting the glass ceramic to a powder;

compacting the powder to a starting blank;

sintering the blank; and

wherein the dental product comprises a high strength reinforcing bar.