Carbon dioxide nanoelectronic sensor

• US 20050129573A1
• Filed: 09/13/2004
• Published: 06/16/2005
• Est. Priority Date: 09/12/2003
• Status: Abandoned Application

• Current Assignee: Nanomix Incorporated (CJY Holdings Ltd.)
• Original Assignee: Nanomix Incorporated (CJY Holdings Ltd.)
• Inventors: Gruner, George, Gabriel, Jean-Christophe P., Stetter, Joseph R., Star, Alexander
• Application Number:
  US10/940,324
• Publication Number:
  US 20050129573A1
• Time in Patent Office: Days
• US Class Current: 422/58
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: B82Y 15/00 Nanotechnology for interacting, sensing or actuating, e.g. quantum dots as markers in protein assays or molecular motors
• CPC Class Codes: G01N 27/4141 specially adapted for gases
• CPC Class Codes: G01N 27/4146 involving nanosized elements, e.g. nanotubes, nanowires
• CPC Class Codes: G01N 33/004 for CO, CO2
• CPC Class Codes: Y10T 436/204998 Inorganic carbon compounds

Abstract

An electronic system and method for detecting carbon dioxide is provided, using a nanostructure sensing device (CO₂ sensor). The CO₂ sensor is made up of a substrate and a nanostructure disposed over the substrate. The nanostructure may comprise a carbon nanotube, or a network of nanotubes. Two conductive elements are disposed over the substrate and electrically connected to the nanotube. A gate electrode may be positioned opposite the nanostructure. A functionalization material reactive with carbon dioxide is disposed on CO₂ sensor, and in particular, on the nanotube. The CO₂ sensor may be connected to an electrical circuit, which will respond to changes in CO₂ concentration in the ambient sensor environment.

Claims

1. A nanostructure sensor for sensing carbon dioxide, comprising:

a substrate;

a first nanostructure over the substrate;

at least two conducting elements in electrical communication with the first nanostructure; and

at least one recognition material operatively associated with the first nanostructure, the at least one recognition material configured for interacting with carbon dioxide.

2. The nanostructure sensor of claim 1, wherein the first nanostructure is selected from the group consisting of nanotubes, nanowires, nanofibers, and nanorods.

3. The nanostructure sensor of claim 1, wherein the first nanostructure comprises at least one element selected from the group consisting of carbon, boron, boron nitride, and carbon boron nitride, silicon, germanium, gallium nitride, zinc oxide, indium phosphide, molybdenum disulphide, and silver.

4. The nanostructure sensor of claim 1, wherein the first nanostructure comprises a single-wall carbon nanotube.

5. The nanostructure sensor of claim 1, wherein the conducting elements comprise metal electrodes.

6. The nanostructure sensor of claim 1, wherein the conducting elements are in direct physical contact with the first nanostructure.

7. The nanostructure sensor of claim 1, wherein the at least one recognition material comprises a metallic carbonate.

8. The nanostructure sensor of claim 1, wherein the at least one recognition material is selected from the group consisting of lithium carbonate, sodium carbonate, potassium carbonate, cesium carbonate, barium carbonate, calcium carbonate, and silver carbonate.

9. The nanostructure sensor of claim 1, wherein the at least one recognition material comprises a pH-sensitive polymer.

10. The nanostructure sensor of claim 1, wherein the at least one recognition material is selected from the group consisting of polyaniline, poly(ethyleneimine), poly(o-phenylenediamine), poly(3-methylthiophene), and polypyrrole.

11. The nanostructure sensor of claim 1, wherein the at least one recognition material comprises an aromatic compound.

12. The nanostructure sensor of claim 1, wherein the at least one recognition material is selected from the group consisting benzylamine, naphthalenemethylamine, antracene amine, and pyrene amine.

13. The nanostructure sensor of claim 1, wherein the at least one recognition material comprises a polymeric material.

14. The nanostructure sensor of claim 1, wherein the at least one recognition material is selected from the group consisting of polyethylene glycol, poly(vinyl alcohol), polysaccharides, and starches.

15. The nanostructure sensor of claim 1, wherein the at least one recognition material comprises a substantially continuous layer over the nanostructure.

16. The nanostructure sensor of claim 1, wherein the at least one recognition material comprises a plurality of different materials.

17. The nanostructure sensor of claim 1, further comprising a gate electrode in proximity to the nanostructure.

18. The nanostructure sensor of claim 1, further comprising a layer of inhibiting material covering regions of the sensor adjacent to the connections between the conductive elements.

19. The nanostructure sensor of claim 1, wherein the nanostructure further comprises a two-dimensional nanostructure network disposed over the substrate between the two conduction elements.

20. The nanostructure sensor of claim 19, wherein the nanostructure network comprises a plurality of randomly-oriented carbon nanotubes.

21. The nanostructure sensor of claim 1, wherein at least one recognition material is selected from the group consisting of a metal, a metal oxide, and a metal hydroxide.

22. The nanostructure sensor of claim 1, wherein at least one recognition material comprises a layer of metal disposed adjacent the first nanostructure.

23. The nanostructure sensor of claim 22, wherein the recognition material includes a layer of polymeric material disposed adjacent the layer of metal.

24. The nanostructure sensor of claim 17, wherein at least one recognition material comprises a layer of metal disposed adjacent the gate electrode.

25. The nanostructure sensor of claim 24, wherein the recognition material includes a layer of polymeric material disposed adjacent the layer of metal.

26. The nanostructure sensor of claim 1, wherein the recognition material comprises poly(ethylene imine) in mixture with a starch.

27. The nanostructure sensor of claim 26, wherein the starch comprises at least one of amylose and amylopectin.