Polymerizable compositions for optical articles
First Claim
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1. A brightness enhancing film comprising the reaction product of a polymerizable composition consisting essentially of:
- a) a first monomer comprising a major portion of 2-propenoic acid, (1-methylethylidene)bis[(2,6-dibromo-4,1-phenylene)oxy(2-hydroxy-3,1-propanediyl)]ester;
b) a cross linking agent selected from pentaerythritol tri(meth)acrylate, trimethylolpropane tri(meth)acrylate, and mixtures thereof;
c) phenoxyethyl(meth)acrylate; and
d) optionally a photoinitiator.
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Abstract
Polymerizable compositions particularly useful for brightness enhancing films.
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Citations
29 Claims
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1. A brightness enhancing film comprising the reaction product of a polymerizable composition consisting essentially of:
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a) a first monomer comprising a major portion of 2-propenoic acid, (1-methylethylidene)bis[(2,6-dibromo-4,1-phenylene)oxy(2-hydroxy-3,1-propanediyl)]ester;
b) a cross linking agent selected from pentaerythritol tri(meth)acrylate, trimethylolpropane tri(meth)acrylate, and mixtures thereof;
c) phenoxyethyl(meth)acrylate; and
d) optionally a photoinitiator. - View Dependent Claims (2, 3, 4, 5, 6)
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7. A brightness enhancing film comprising the reaction product of a polymerizable composition consisting essentially of:
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a) a first monomer selected from i) a monomer comprising a major portion having the structure wherein R1 is independently hydrogen or methyl; and
ii) a monomer comprising a major portion having the structure wherein R1 is independently hydrogen or methyl, and L is a linking group independently selected from the group consisting of linear C2-C12 alkyl groups, branched C2-C12 alkyl groups and —
CH2CH(OH)CH2—
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and mixtures thereof; and
b) a crosslinking agent comprising at least three (meth)acrylate functional groups;
c) at least one monofunctional (meth)acrylate diluent; and
d) optionally a photoinitiator. - View Dependent Claims (8, 9, 10, 11, 12)
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13. A brightness enhancing film comprising the reaction product of
a) at least 50 wt-% of one or more first monomers selected from the group consisting of: -
i) a monomer comprising a major portion having the structure wherein R1 is independently hydrogen or methyl; and
ii) a monomer comprising a major portion having the structure wherein R1 is independently hydrogen or methyl, and L is a linking group independently selected from linear C2-C12 alkyl groups, branched C2-C12 alkyl groups, and —
CH2CH(OH)CH2—
;
and mixtures thereof; and
b) a crosslinking agent comprising at least three (meth)acrylate functional groups. - View Dependent Claims (14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25)
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26. A polymerizable resin composition comprising
a) at least 50 wt-% of one or more first monomers selected from the group consisting of: -
i) a monomer comprising a major portion having the structure wherein R1 is independently hydrogen or methyl; and
ii) a monomer having a major portion having the structure wherein R1 is independently hydrogen or methyl, and L is a linking group independently selected from linear C2-C12 alkyl groups, branched C2-C12 alkyl groups, and —
CH2CH(OH)CH2—
;
and mixtures thereof; and
b) a crosslinking agent comprising at least three (meth)acrylate functional groups. - View Dependent Claims (27, 28, 29)
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Specification