Method of non-contact measuring electrical conductivity of electrolytes with using primary measuring transformer

• US 20050156604A1
• Filed: 07/23/2004
• Published: 07/21/2005
• Est. Priority Date: 07/25/2003
• Status: Active Grant

• Current Assignee: Enerize Corporation
• Original Assignee: Elena Shembel
• Inventors: Novak, Peter, Khandetskyy, Volodymyr, Shembel, Elena, Red'ko, Volodymyr
• Granted Patent: US 7,071,684 B2
• Time in Patent Office: Days
• US Class Current: 324/439
• CPC Class Codes: G01N 27/023 where the material is placed in the field of a coil
• CPC Class Codes: G01N 27/06 of a liquid involving electrolysis G01N27/26
• CPC Class Codes: G01N 27/07 Construction of measuring vessels; Electrodes therefor
• CPC Class Codes: G01R 27/22 Measuring resistance of fluids

Abstract

A method of noncontact measuring the electrical conductivity of electrolytes using a primary measuring transformer includes placing the electrolyte in a sampler, exciting an alternating magnetic field using an axisymmetrical eddy current sensor, switching to the sensor a capacitor of variable capacitance, tuning of the formed circuit in resonance with the frequency of the generator of harmonic oscillations, and recording the change in the introduced active resistance of the parametric eddy current sensor rated against its own inductive resistance.

Claims

1. A method of noncontact measuring the electric conductivity of electrolytes by means of a primary measuring transducer comprises the steps of:

placing the electrolyte in a sampler, exciting an alternating magnetic field while using an axisymmetrical eddy current sensor, switching a capacitor of variable capacitance to the sensor, tuning of the formed circuit in resonance with the frequency of the generator of harmonic oscillations, fixing the own sensor parameters at the resonant frequency, placing the sampler with the electrolyte on the operating end face of the eddy current sensor co-axially thereof, calculating the components of the introduced sensor impedance, wherein a change is recorded of the introduced active resistance of the parametric eddy current sensor rated relative to its own inductance resistance while varying the geometry of the eddy current sensor—

sampler system, the number of sensor turns and the frequency of its magnetic field by comparing the corrected values of the introduced active the range of frequencies is determined at which the electrolyte conductance does not depend on the frequency, while calculating the value of the specific electrical conductance.

2. A method according to claim 1, wherein is performed measuring of the frequency characteristic of the Q-factor of the sensor, fixing of the first operating frequency that corresponds to the maximum of the Q-factor, at which measuring is carried out of the relative active introduced resistance of the sensor with the sample.

3. A method according to claim 1, wherein after measuring at the first operating frequency the sensor diameter is increased by q times while reducing by q² times the first operating frequency, fixing in this manner the zero operating frequency at which measuring is performed of the introduced resistance of the sensor with the sample.

4. A method according to claim 1, wherein after measuring at the first and zero operating frequencies the sensor diameter is reduced relative to the initial diameter by q times while increasing by q² times the first operating frequency, fixing in this manner the second operating frequency at which measuring is performed of the introduced resistance of the sensor with the sample.

5. A method according to claim 1, wherein the values are compared of the active introduced resistance rated relative to the sensor own reactive resistance at the first operating frequency with the similar resistance at the zero operating frequency multiplied by the relations of the own inductance values of the sensors at the zero and the operating frequencies and by the value 1/q, as well as with the similar resistance at the second operating frequency multiplied by the relation of the own inductance values of the sensors at the second and the first operating frequencies and by the value q, also taking into regard the corrections of the incomplete compensation of the clearance at the zero and second operating frequencies.

6. A method according to claim 1, wherein the value of the electrolyte specific electrical conductance is determined according to the value of the relative active introduced resistance at the first operating frequency if the values that were compared in p. 5 coincide with an accuracy to 10%.

7. A method according to claim 1, wherein the value of q is selected within the 1.3-1.8 range.

8. A method according to claim 1, wherein the number of turns in the eddy current sensor coil is changed if the corrected values of the relative introduced resistance values measured at the zero and the second operating frequencies, and also the value of the introduced resistance at the first operating frequency differ from each other more than by 10%, whereupon the new value of the first operating frequency is then determined.

9. A method according to claim 1, wherein the minimum number of turns in the eddy current sensor are set to be equal to two.

10. A method according to claim 1, wherein the maximum number of turns in the eddy current sensor is selected so that it exceeds by two times the value corresponding to the maximum sensitivity of the sensor with a dielectric core.

11. A method according to claim 1, wherein as the material for the core of the sensor coil is selected a dielectric with a dielectric loss tangent angle not exceeding 5.10⁻

4 within the range from the least value of the zero till the maximum value of the second operating frequency.

12. A method according to claim 1, wherein the minimum wire diameter of the sensor winding coil is set not less than one tenth of the coil diameter, while the maximum diameter is not more than 1.5 mm.

13. A method according to claim 1, wherein the coil wire diameter and the winding pitch are selected to correspond to the maximum sensitivity of measurements while the own resonant frequency of the eddy current sensor that is determined by the values of its inductance and parasitic inter-turn capacitance should be not less than by an order higher of the value of the second operating frequency.

14. A method according to claim 1, wherein each triple of the eddy frequency sensors with an equal number of turns that operate at the zero, first and second operating frequencies are integrated relative to a common axis into a single structure of the primary measuring transducer while the sampler with the electrolyte is placed on the operating end face of the transducer with the symmetry center of the sampler base is to be coincident with the symmetry axis of the primary transducer.

15. A method according to claim 1, wherein the coil wire diameter and the winding pitch are maintained constant for each triple of sensors of different diameters but with an equal number of turns.

16. A method according to claim 1, wherein the distance between the nearest to the electrolyte surface turn of each sensor of the primary measuring transducer and the electrolyte surface in the sampler are set proportional to the sensor radius.

17. A method according to claim 1, wherein during calculations the self-induction coefficients between all paired combinations of turns of the corresponding eddy current sensor are taken into consideration when calculating the value of the specific electric conductance of the electrolyte at the first operating frequency.

18. A method according to claim 1, wherein the sampler is produced of a dielectric material whose dielectric losses tangent angle does not exceed 10⁻

3.

19. A method according to claim 1, wherein the minimum radial dimensions of the electrolyte sample in the sampler should be not less than two times higher of the maximum diameter of the eddy current sensor from the triple of sensors of the primary measuring transducer.