Dual emitting dyads of heavy metal complexes as broad band emitters for organic LEDs
First Claim
1. A compound, comprising:
- a first metal center and a second metal center, wherein each metal has an atomic weight greater than 40; and
a bridging ligand coordinated to the first metal center and the second metal center; and
at least one photoactive ligand bound to the first metal center, and at least one photoactive ligand bound to the second metal center; and
wherein the transition dipole moment of the first photoactive ligand is orthogonal to the transition dipole moment of the second photoactive ligand.
3 Assignments
0 Petitions
Accused Products
Abstract
An organic light emitting device is provided. The device has an anode, a cathode, and an emissive layer disposed between and electrically connected to the anode and the cathode. The emissive layer further comprises a compound having two metal centers, in which each metal has an atomic weight greater than 40. A bridging ligand, small molecule, or polymer is coordinated to both metal centers, and at least one photoactive ligand is bound to each metal. In one embodiment, the transition dipole moment of the photoactive ligand bound to the first metal is orthogonal to the photoactive ligand bound to the second metal. In another embodiment, the first metal center and the atoms of the bridging ligand that are coordinated to the first metal center form a plane and the atoms of the bridging ligand that are coordinated to the second metal center form another plane, and the planes form an angle that is between about 80 degrees and 100 degrees. In another embodiment, the bridging ligand is diacetylacetonate. In another embodiment, a polymer or small molecule is coordinated to both metals, and the metal-ligand complex for the first metal center is different from the metal-ligand complex for the second metal center.
29 Citations
110 Claims
-
1. A compound, comprising:
-
a first metal center and a second metal center, wherein each metal has an atomic weight greater than 40; and
a bridging ligand coordinated to the first metal center and the second metal center; and
at least one photoactive ligand bound to the first metal center, and at least one photoactive ligand bound to the second metal center; and
wherein the transition dipole moment of the first photoactive ligand is orthogonal to the transition dipole moment of the second photoactive ligand. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17)
-
-
18. A compound, comprising:
-
a first metal center and a second metal center, wherein each metal has an atomic weight greater than 40;
a bridging ligand coordinated to the first metal center and the second metal; and
at least one photoactive ligand bound to the first metal center, and at least one photoactive ligand bound to the second metal center; and
wherein the first metal center and the atoms of the bridging ligand that are coordinated to the first metal center define a first plane, and the second metal center and the atoms of the bridging ligand that are coordinated to the second metal center define a second plane, and wherein the first plane and the second plane form an angle that is between about 80 degrees and 100 degrees. - View Dependent Claims (19, 20, 21, 22, 23, 24, 25)
-
-
26. A compound, comprising:
-
a first metal center and a second metal center, wherein each metal has an atomic weight greater than 40;
a bridging ligand coordinated to the first metal center and the second metal center further comprising the structure at least one photoactive ligand bound to the first metal center, and at least one photoactive ligand bound to the second metal center. - View Dependent Claims (27, 28, 29, 30, 31, 32)
-
-
33. A compound, comprising
a first metal center and a second metal center, wherein each metal has an atomic weight greater than 40; -
a polymer or small molecule coordinated to the first metal center and the second metal; and
at least one photoactive ligand bound to the first metal center, and at least one photoactive ligand bound to the second metal center, wherein the first metal-ligand complex is different from the second metal-ligand complex. - View Dependent Claims (34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53)
-
-
54. An organic light emitting device, comprising:
an anode, a cathode, and an emissive layer disposed between and electrically connected to the anode and the cathode, wherein the emissive layer further comprises a compound, comprising;
a first metal center and a second metal center, wherein each metal has an atomic weight greater than 40; and
a bridging ligand coordinated to the first metal center and the second metal center; and
at least one photoactive ligand bound to the first metal center, and at least one photoactive ligand bound to the second metal center; and
wherein the transition dipole moment of the first photoactive ligand is orthogonal to the transition dipole moment of the second photoactive ligand. - View Dependent Claims (55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71)
-
72. An organic light emitting device, comprising:
an anode, a cathode, and an emissive layer disposed between and electrically connected to the anode and the cathode, wherein the emissive layer further comprises a compound, comprising;
a first metal center and a second metal center, wherein each metal has an atomic weight greater than 40;
a bridging ligand coordinated to the first metal center and the second metal; and
at least one photoactive ligand bound to the first metal center, and at least one photoactive ligand bound to the second metal center; and
wherein the first metal center and the atoms of the bridging ligand that are coordinated to the first metal center define a first plane, and the second metal center and the atoms of the bridging ligand that are coordinated to the second metal center define a second plane, and wherein the first plane and the second plane form an angle that is between about 80 degrees and 100 degrees. - View Dependent Claims (73, 74, 75, 76, 77, 78, 79, 80)
-
81. An organic light emitting device, comprising:
an anode, a cathode, and an emissive layer disposed between and electrically connected to the anode and the cathode, wherein the emissive layer further comprises a compound, comprising;
a first metal center and a second metal center, wherein each metal has an atomic weight greater than 40;
a bridging ligand coordinated to the first metal center and the second metal center further comprising the structure at least one photoactive ligand bound to the first metal center, and at least one photoactive ligand bound to the second metal center. - View Dependent Claims (82, 83, 84, 85, 86, 87, 88)
-
89. An organic light emitting device, comprising:
an anode, a cathode, and an emissive layer disposed between and electrically connected to the anode and the cathode, wherein the emissive layer further comprises a compound, comprising;
a first metal center and a second metal center, wherein each metal has an atomic weight greater than 40;
a polymer or small molecule coordinated to the first metal center and the second metal; and
at least one photoactive ligand bound to the first metal center, and at least one photoactive ligand bound to the second metal center, wherein the first metal-ligand complex is different from the second metal-ligand complex. - View Dependent Claims (90, 91, 92, 93, 94, 95, 96, 97, 98, 99, 100, 101, 102, 103, 104, 105, 106, 107, 108, 109, 110)
Specification