System and method for sample detection based on low-frequency spectral components

• US 20050176391A1
• Filed: 04/01/2005
• Published: 08/11/2005
• Est. Priority Date: 04/19/2002
• Status: Active Grant

• Current Assignee: Nativis, Inc.
• Original Assignee: Nativis, Inc.
• Inventors: Butters, Bennett M.
• Granted Patent: US 7,412,340 B2
• Time in Patent Office: Days
• US Class Current: 455/180.300
• CPC Class Codes: G01N 37/005 Measurement methods not based on established scientific theories
• CPC Class Codes: H01Q 1/22 by structural association with other equipment or articles
• CPC Class Codes: H01Q 7/08 Ferrite rod or like elongated core

Abstract

Method and apparatus for detecting a selected material in a sample are disclosed. In the method, the sample is placed adjacent a detector coil, for generating an electromagnetic time-domain signal composed of sample source radiation. The signal is first conditioned to convert the signal to an amplified conditioned signal from which frequency components above a selected frequency have been removed, then filtered to selectively pass low-frequency spectral components that are (i) in a frequency range between dc and 50 khz, and (ii) characteristic of the selected material. The filtered signal is cross-correlated with a data set of low-frequency spectral components that are (i) in a frequency range between dc and 50 khz, and (ii) characteristic of a selected material, to produce a frequency-domain spectrum in the frequency range within DC to 50 khz. This spectrum is then used to determine whether the frequency-domain spectrum contains one or more low-frequency signal components that are characteristic of the selected material, and diagnostic of the presence or absence of such material in the sample.

Claims

1-21. -21. (canceled)

22. A method for detecting a selected material in a sample, comprising

holding the sample while shielding the sample from ambient electrical and magnetic energy;

introducing noise into the sample to induce stochastic resonance;

storing, for each of one or more preselected materials including the selected material, a data set containing low-frequency spectral components that are of a selected frequency range approximately above DC;

wherein the data set contains low-frequency spectral components that are of a selected frequency approximately below 50 kHz, and characteristic of the selected material;

producing, adjacent to the sample, a time-domain signal having signal components related to low-frequency electromagnetic radiation produced by the selected material in the sample;

converting the produced signal to an amplified signal from which frequency components above a selected frequency are substantially omitted;

retrieving a data set of low-frequency spectral components characteristic of the selected material;

filtering the produced signal to selectively pass low-frequency spectral components corresponding to low-frequency spectral components of the retrieved data set;

cross-correlating the produced signal with the retrieved data set of low-frequency spectral components to produce a frequency-domain signal, wherein the frequency-domain signal has a frequency approximately above DC;

wherein the frequency-domain signal has a frequency approximately below 50 kHz;

determining whether the frequency-domain signal contains one or more low-frequency signal components that are characteristic of the selected material, and diagnostic of a presence or absence of the selected material in the sample; and

displaying an output associated with whether the frequency-domain signal contains one or more low-frequency signal components that are characteristic of the selected material.

23. The method of claim 22, for use in detecting a material in a fluid sample, wherein the method further comprises directing the sample through a tube having a detector coil wound about the tube in a winding direction substantially perpendicular to the direction of sample flow in the tube for performing the producing, and wherein a toroidal ferrite core has the tube disposed about at least a portion of the circumference of the core, and the detector coil is wound around the tube and core in a radial winding direction.

24. The method of claim 22, for use in detecting a material in a fluid sample, wherein the method further comprises directing the sample through a tube having a detector coil wound about the tube in a winding direction substantially perpendicular to the direction of sample flow in the tube for performing the producing.

25. The method of claim 22, wherein introducing noise includes introducing Gaussian noise.

26. The method of claim 22, for use in detecting gaseous or particulate material in a gaseous-stream sample, wherein the method further comprises trapping the selected material as the sample passes through a filter.

27. The method of claim 22, further comprising identifying frequencies of low-frequency signal components whose cross-spectral correlations have a selected statistical measure above background spectral noise.

28. The method of claim 22, further comprising, at least once:

receiving an additional frequency-domain signal for a given sample;

adding the additional signal to the frequency domain signal; and

, averaging the added spectra until components in the summed and averaged signal have a selected statistical measure above background noise.

29. An apparatus for detecting a selected material in a sample, comprising:

means for placing the sample adjacent a detector coil;

means for introducing noise into the sample to induce stochastic resonance;

means for detecting an electromagnetic time-domain signal produced in the detector coil by the sample;

means for processing the time-domain signal to selectively pass low-frequency spectral components that are of a frequency approximately above DC;

wherein the means for processing the time-domain signal selectively pass low-frequency spectral components that are of a frequency approximately below 50 kHz, and characteristic of the selected material;

means for cross-correlating the time-domain signal with a data set of low-frequency spectral components that are of a frequency approximately above DC, and of a frequency approximately below 50 kHz, and characteristic of a selected material, to produce a frequency-domain signal in the frequency range of approximately DC to 50 kHz; and

means for determining whether the frequency-domain signal contains one or more low-frequency signal components that are characteristic of the selected material, and diagnostic of a presence or absence of the selected material in the sample.

30. The apparatus of claim 29, for use in detecting a material in a fluid sample, wherein the means for placing includes means for flowing the sample through a sample tube having sample inlet and outlet ports, and the detector coil is wound about the tube in a winding direction substantially perpendicular to the direction of sample flow in the tube, wherein the sample tube is disposed adjacent a toroidal ferrite core, the detector coil is wound around the tube and core in a radial winding direction, and which further includes means for injecting Gaussian noise into the sample for generation of the time-domain signal.

31. The apparatus of claim 29, for use in detecting a material in a fluid sample, wherein the means for placing includes means for flowing the sample through a sample tube having sample inlet and outlet ports, and the detector coil is wound about the tube in a winding direction substantially perpendicular to the direction of sample flow in the tube.

32. The apparatus of claim 29, wherein the detector coil includes a Helmholz coil having a pair of opposed coil elements, and the means for placing includes means for placing the sample between the coil elements.

33. The apparatus of claim 29, for use in detecting gaseous or particulate material in a gaseous-stream sample, wherein the means for placing includes means for passing the sample through a means for filtering effective to trap such material, as the sample passes through the means for filtering, and the detector coil has a winding direction substantially parallel to a plane of the means for filtering.

34. The apparatus of claim 29, wherein the means for determining includes means for identifying frequencies of low-frequency signal components in the frequency domain signal whose cross-spectral correlations have a selected statistical measure above background spectral noise.

35. The apparatus of claim 29, wherein the means for determining includes means for receiving an additional frequency-domain signal for a given sample, means for adding the additional signal to the frequency domain signal, and means for averaging the added spectra, and means for repeating the receiving and adding until components in summed and averaged spectra have a selected statistical measure above background noise.

36. A method for detecting a selected material in a sample, comprising:

holding the sample adjacent a detector coil, and introducing noise into the sample, to thereby generate an electromagnetic time-domain signal composed of sample source radiation via stochastic resonance;

processing the electromagnetic time-domain signal to amplify the electromagnetic time-domain signal, and selectively pass low-frequency spectral components that are in a frequency range of approximately DC to 50 kHz, and characteristic of the selected material;

cross-correlating the electromagnetic time-domain signal with a data set of low-frequency spectral components that are in a frequency range of approximately DC to 50 kHz, and characteristic of a selected material, to produce a frequency-domain signal in the frequency range of approximately DC to 50 kHz; and

,

determining whether the frequency-domain signal contains one or more low-frequency signal components that are characteristic of the selected material, and diagnostic of the presence or absence of such material in the sample.

37. The method of claim 36, further comprising automatically extracting the sample from an environment surrounding the system, and wherein the sample is air or gas.

38. The method of claim 36, further comprising detecting an electromagnetic signal from the sample via a toroidal detector.