Detergent cosmetic compositions comprising at least one silicone and at least one drawing polymer, and use thereof

• US 20050176600A1
• Filed: 01/07/2005
• Published: 08/11/2005
• Est. Priority Date: 01/07/2004
• Status: Abandoned Application

• Current Assignee: L'Oreal SA
• Original Assignee: L'Oreal SA
• Inventors: Paul, Laurence, Samain, Henri, Giroud, Franck, Fack, Geraldine
• Application Number:
  US11/030,308
• Publication Number:
  US 20050176600A1
• Time in Patent Office: Days
• US Class Current: 510/119
• CPC Class Codes: A61K 2800/5426 cationic
• CPC Class Codes: A61K 2800/5428 amphoteric or zwitterionic
• CPC Class Codes: A61K 8/463 containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
• CPC Class Codes: A61K 8/8158 Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/817 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
• CPC Class Codes: A61K 8/891 saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• CPC Class Codes: A61K 8/898 containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
• CPC Class Codes: A61Q 19/10 Washing or bathing preparations
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair
• CPC Class Codes: A61Q 5/12 Preparations containing hair conditioners

Abstract

Disclosed herein are novel washing compositions, for example hair compositions, comprising, in a cosmetically acceptable medium, at least one nonaminated silicone with a viscosity lower than 100,000 cSt, at least one anionic, nonionic, or amphoteric detergent surfactant, and at least one drawing polymer. These compositions may have an improved styling effect.

Claims

1. A composition for washing keratin materials comprising, in a cosmetically acceptable aqueous medium, at least one nonaminated silicone with a viscosity lower than 100,000 mm²/s (cSt), at least one detergent surfactant chosen from anionic, nonionic, and amphoteric detergent surfactants, and at least one drawing polymer with a drawing power of greater than 5 cm.

2. The composition according to claim 1, wherein the at least one detergent surfactant is chosen from anionic surfactants.

3. The composition according to claim 1, wherein the at least one detergent surfactant is present in an amount ranging from 4% to 50% by weight, relative to the total weight of the composition.

4. The composition according to claim 3, wherein the atleast one detergent surfactant is present in an amount ranging from 8% to 25% by weight, relative to the total weight of the composition.

5. The composition according to claim 1, wherein the drawing polymer is chosen from:

(a1) dispersions of particles of at least one water-soluble cationic polymer with a weight-average molecular mass of greater than 10⁶ in a saline aqueous solution, obtained by heterogeneous free-radical polymerization of water-soluble monomers with precipitation of the polymer formed, and (a2) aqueous solutions of at least one water-soluble cationic polymer with a weight-average molecular mass of greater than 10⁶, obtained by heterogeneous free-radical polymerization of water-soluble monomers with precipitation of the polymer formed.

6. The composition according to claim 5, wherein the at least one water-soluble monomer is chosen from at least one of cationic and nonionic monomers comprising at least one ethylenic double bond.

7. The composition according to claim 6, wherein the nonionic monomers are chosen from acrylamide, methacrylamide, N-vinylformamide, N-vinylacetonamide, hydroxypropyl acrylate, and hydroxypropyl methacrylate.

8. The composition according to claim 6, wherein the cationic monomers are chosen from di(C_1-4 alkyl)diallylammonium salts and compounds of formula (I)

9. The composition according to claim 8, wherein the anionic counterion is chosen from halide and sulphate ions.

10. The composition according to claim 5, wherein the at least one water-soluble cationic polymer is polymerized using at least one cationic monomer of formula (I)

11. The composition according to claim 10, wherein the at least one water-soluble cationic polymer is polymerized using a monomer mixture comprising from 0 to 95.5 mol % of acrylamide and from 4.5 to 100 mol % of at least one cationic monomer of formula (I).

12. The composition according to claim 10, wherein the at least one water-soluble cationic polymer is polymerized using a monomer mixture comprising acrylamide and a cationic monomer of formula (I), the number of moles of the cationic monomer of formula (I) being greater than the number of moles of acrylamide.

13. The composition according to claim 10, wherein the at least one water-soluble cationic polymer is polymerized using a monomer mixture comprising 10 mol % of acryloyloxyethyldimethylbenzylammonium chloride and 90 mol % of acrylamide.

14. The composition according to claim 10, wherein the at least one water-soluble cationic polymer is polymerized using a monomer mixture comprising 30 mol % of acryloyloxytrimethylammonium chloride, 50 mol % of acryloyloxyethyldimethylbenzylammonium chloride, and 20 mol % of acrylamide.

15. The composition according to claim 10, wherein the at least one water-soluble cationic polymer is polymerized using 10 mol % of acryloyloxyethyltrimethylammonium chloride and 90 mol % of acrylamide.

17. The composition according to claim 5, wherein the concentration of particles the at least one water-soluble cationic polymer as a dispersion in a saline aqueous solution in (a1) ranges from 0.01% to 20% by weight, relative to the total weight of the dispersion.

18. The composition according to claim 5, wherein the concentration of the at least one water-soluble polymer as a solution in (a2) ranges from 0.01% to 20% by weight, relative to the total weight of the solution.

19. The composition according to claim 5, wherein the aqueous solution in (a1) or (a2) comprises at least one anionic salt.

20. The composition according to claim 19, wherein the at least one anionic salt is chosen from ammonium sulphate, ammonium hydrogen sulphate, ammonium chloride, sodium sulphate, sodium hydrogen sulphate, magnesium sulphate, magnesium hydrogen sulphate, aluminium sulphate, and aluminium hydrogen sulphate.

21. The composition according to claim 1, wherein the at least one drawing polymer is present in the composition in an amount ranging from 0.01% to 10% by weight, relative to the total weight of the composition.

22. The composition according to claim 21, wherein the at least one drawing polymer is present in the composition in an amount ranging from 0.05% to 5% by weight, relative to the total weight of the composition.

23. The composition according to claim 1, wherein the at least one nonaminated silicone has a viscosity ranging from 1,000 to 100,000 mm²/s (cSt).

24. The composition according to claim 23, wherein the at least one nonaminated silicone has a viscosity ranging from 10,000 to 80,000 mm²/s (cSt).

25. The composition according to claim 1, wherein the at least one nonaminated silicone is a nonvolatile polyorganosiloxane chosen from at least one of polyalkylsiloxanes, polydialkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, silicone resins, polyorganosiloxanes modified with at least one organofunctional group.

26. The composition according to claim 25, wherein the polydialkylsiloxanes are chosen from:

polydimethylsiloxanes containing trimethylsilyl end groups;

polydimethylsiloxanes containing dimethylsilanol end groups; and

poly(C₁-C₂₀)alkylsiloxanes.

27. The composition according to claim 25, wherein the polyalkylarylsiloxanes are chosen from:

polydimethylmethylphenylsiloxanes, and linear and/or branched polydimethyldiphenylsiloxanes with a viscosity ranging from 1×

10<sup>−

5</sup> to 5×

10<sup>−

2</sup> m²/s at 25°

C.

28. The composition according to claim 25, wherein the polyorganosiloxanes modified with at least one organofunctional group are chosen from silicones comprising in their structure at least one organofunctional group attached via a hydrocarbon-based radical.

29. The composition according to claim 25, wherein the polyorganosiloxanes modified with at least one organofunctional group are chosen from the polyorganosiloxanes comprising at least one group chosen from:

a) polyethyleneoxy groups;

b) thiol groups;

c) alkoxylated groups;

d) hydroxylated groups;

e) acyloxyalkyl groups;

f) alkylcarboxylic groups;

g) 2-hydroxyalkylsulphonate groups;

h) 2-hydroxyalkylthiosulphonate groups; and

i) polypropyleneoxy groups.

30. The composition according to claim 1, wherein the at least one nonaminated silicone is chosen from polydialkylsiloxanes containing trimethylsilyl end groups, polydialkylsiloxanes containing dimethylsilanol end groups, and polyalkylarylsiloxanes.

31. The composition according to claim 1, wherein the at least one nonaminated silicone is chosen from polyorganosiloxanes that are insoluble in the composition.

32. The composition according to claim 1, wherein the at least one nonaminated silicone is present in an amount ranging from 0.001% to 20% by weight, relative to the total weight of the composition.

33. The composition according to claim 32, wherein the at least one nonaminated silicone is present in an amount ranging from 0.01% to 10% by weight, relative to the total weight of the composition.

34. The composition according to claim 1, further comprising at least one cationic polymer.

35. The composition according to claim 1, further comprising at least one aminated silicone.

36. The composition according to claim 1, wherein the composition has a pH ranging from 3 to 10.

16. The composition according to caim 10, wherein the at least one water-soluble cationic polymer is polymerized using 30 mol % of diallyldimethylammonium chloride and 70 mol % of acrylamide.

37. A method of using a cosmetic composition for cleaning, caring for, conditioning, and/or styling hair comprising applying the composition to hair, wherein said composition comprises, in a cosmetically acceptable aqueous medium, at least one nonaminated silicone with a viscosity lower than 100,000 mm²/s (cSt), at least one detergent surfactant chosen from anionic, nonionic, and amphoteric detergent surfactants, and at least one drawing polymer with a drawing power of greater than 5 cm.