REGENERATIVE FUEL CELL SYSTEM AND METHOD OF OPERATION THEREOF

• US 20050181244A1
• Filed: 02/12/2004
• Published: 08/18/2005
• Est. Priority Date: 02/12/2004
• Status: Abandoned Application

• Current Assignee: Proton Energy Systems, Inc. (NEL ASA)
• Original Assignee: Proton Energy Systems, Inc. (NEL ASA)
• Inventors: Speranza, A. John, Nomikos, Spyridon, Cardin, Michael Kevin, Halter, Dean Edwin, Lillis, Mark Andrew, Shiroma, Iris Liane, Porter, Stephen Charles
• Application Number:
  US10/708,165
• Publication Number:
  US 20050181244A1
• Time in Patent Office: Days
• US Class Current: 429/425
• CPC Class Codes: F17C 13/025 having the pressure as the parameter
• CPC Class Codes: F17C 13/084 for small-sized storage vessels, e.g. compressed gas cylinders or bottles, disposable gas vessels, vessels adapted for automotive use
• CPC Class Codes: F17C 2201/0104 cylindrical
• CPC Class Codes: F17C 2201/032 with substantially vertical main axis
• CPC Class Codes: F17C 2201/054 medium (>1 m3)
• CPC Class Codes: F17C 2203/0617 with one layer
• CPC Class Codes: F17C 2203/0639 Steels
• CPC Class Codes: F17C 2203/0663 in form of fibers or filaments
• CPC Class Codes: F17C 2205/0107 Frames
• CPC Class Codes: F17C 2205/0111 Boxes
• CPC Class Codes: F17C 2205/0126 One vessel
• CPC Class Codes: F17C 2205/013 Two or more vessels
• CPC Class Codes: F17C 2205/0142 bundled in parallel
• CPC Class Codes: F17C 2205/0146 with details of the manifold
• CPC Class Codes: F17C 2205/0176 with ventilation
• CPC Class Codes: F17C 2205/0332 Safety valves or pressure relief valves
• CPC Class Codes: F17C 2205/0341 Filters
• CPC Class Codes: F17C 2221/012 Hydrogen
• CPC Class Codes: F17C 2223/0123 gaseous, e.g. CNG, GNC
• CPC Class Codes: F17C 2223/035 High pressure (>10 bar)
• CPC Class Codes: F17C 2223/036 : Very high pressure (>80 bar)
• CPC Class Codes: F17C 2225/0123 : gaseous, e.g. CNG, GNC
• CPC Class Codes: F17C 2225/035 : High pressure, i.e. between 10 and 80 bars
• CPC Class Codes: F17C 2225/036 : Very high pressure, i.e. above 80 bars
• CPC Class Codes: F17C 2250/032 : using computers
• CPC Class Codes: F17C 2250/043 : Pressure
• CPC Class Codes: F17C 2260/042 : Reducing risk of explosion
• CPC Class Codes: F17C 2265/012 : by filtering
• CPC Class Codes: F17C 2270/0763 : Fuel cells
• CPC Class Codes: F17C 7/00 : Methods or apparatus for discharging liquefied, solidified, or compressed gases from pressure vessels, not covered by another subclass
• CPC Class Codes: H01M 16/003 : of fuel cells with other electrochemical devices, e.g. capacitors, electrolysers
• CPC Class Codes: H01M 8/04089 : of gaseous reactants
• CPC Class Codes: H01M 8/04201 : Reactant storage and supply, e.g. means for feeding, pipes
• CPC Class Codes: H01M 8/04208 : Cartridges, cryogenic media or cryogenic reservoirs
• CPC Class Codes: H01M 8/18 : Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
• CPC Class Codes: Y02E 60/32 : Hydrogen storage
• CPC Class Codes: Y02E 60/50 : Fuel cells

Abstract

A regenerative fuel cell system is provided having at least one hydrogen storage container fluidly coupled to at least one hydrogen generator and at least one power generator. Each power generator further includes a fuel cell fluidly coupled to the hydrogen storage container, an electric energy storage device, and an unregulated dc bus electrically connected to said fuel cell and said electric storage device. The system further provides for a health monitoring system for determining the occurrence of critical events which may necessitate the disabling of the system.

Claims

1. A system for generating high pressure hydrogen comprising:

a storage tank;

a low pressure high volume hydrogen generator fluidly coupled to said storage tank; and

,

a high pressure low volume hydrogen generator fluidly coupled to said storage tank.

2. The system for generating high pressure hydrogen of claim 1 wherein said low pressure hydrogen generator generates hydrogen gas between 20 psi and 400 psi.

3. The system for generating high pressure hydrogen of claim 2 wherein said low pressure hydrogen generator generates hydrogen gas at 200 psi.

4. The system for generating high pressure hydrogen of claim 1 wherein said high pressure hydrogen generator generates hydrogen gas between 1000 psi and 10,000 psi.

5. The system for generating high pressure hydrogen of claim 4 wherein said high pressure hydrogen generator generates hydrogen gas at 2400 psi.

6. The system for generating high pressure hydrogen of claim 1 where said low pressure hydrogen generator is an electrochemical cell.

7. The system for generating high pressure hydrogen of claim 6 where said high pressure hydrogen generator is an electrochemical cell.

8. The system for generating high pressure hydrogen of claim 1 where said low pressure hydrogen generator is a hydrocarbon reformer.

9. The system for generating high pressure hydrogen of claim 1 wherein said low pressure hydrogen generator generates hydrogen gas at a rate between 10 scfh and 80 scfh.

10. The system for generating high pressure hydrogen of claim 9 wherein said high pressure hydrogen generator generates hydrogen gas at a rate between 100 standard cubic centimeters per minute and 40 scfh.

11. A method for generating and storing high pressure hydrogen comprising:

generating hydrogen at a first pressure with a first hydrogen generator;

storing hydrogen at said first pressure in a storage tank;

generating hydrogen with a second hydrogen generator at a second pressure higher than said first pressure until said storage tank reaches said second pressure.

12. A method for generating and storing high pressure hydrogen of claim 11 wherein said first pressure is between 20 psi and 400 psi.

13. A method for generating and storing high pressure hydrogen of claim 12 wherein said first pressure is 200 psi.

14. A method for generating and storing high pressure hydrogen of claim 12 wherein said second pressure is between 1000 psi and 10,000 psi.

15. A method for generating and storing high pressure hydrogen of claim 11 further comprising the steps of draining a hydrogen-water phase separator prior to the purging of a hydrogen gas dryer.

16. A regenerative fuel cell system comprising:

at least one hydrogen storage container;

a first hydrogen generator fluidly coupled to said storage container;

a second electrochemical hydrogen generator fluidly coupled to said storage container, said second hydrogen generator generating hydrogen at a higher pressure than said first hydrogen generator; and

, at least one power generator fluidly coupled to said storage container.

17. The regenerative fuel cell system of claim 16 further comprising:

a water storage unit fluidly coupled to said first and second hydrogen generator.

18. The regenerative fuel cell system of claim 16 wherein said first and second hydrogen generators include means for recovering water and returning the recovered water to said water storage unit.

19. The regenerative fuel cell system of claim 18 further comprising:

a user interface electrically connected to said first and second hydrogen generator, said power generator, and said hydrogen storage container.

20. The regenerative fuel cell system of claim 19 wherein said user interface includes means for disabling the first and second hydrogen generators, said power generator and said hydrogen storage container.

21. The regenerative fuel cell system of claim 20 wherein said at least one power generator includes a fuel cell.

22. The regenerative fuel cell system of claim 21 wherein said first hydrogen generator includes an electrochemical cell.

23. The regenerative fuel cell system of claim 21 wherein said first hydrogen generator includes a hydrocarbon reformer.

24. The regenerative fuel cell system of claim 21 wherein said second hydrogen generator includes an electrochemical cell.

25. A regenerative fuel cell system comprising:

at least one hydrogen storage container;

at least one hydrogen generator fluidly coupled to said storage container; and

,

at least one power generator, each power generator including a fuel cell fluidly coupled to said storage container, an electric storage device, an unregulated dc bus electrically connected to said fuel cell and said electric storage device, and a DC/DC converter electrically connected to said unregulated dc bus.

26. The regenerative fuel cell system of claim 25 further comprising a common dc buss electrically connected to said at least one hydrogen generator and each of said fuel cell module unregulated dc buss.

27. The regenerative fuel cell system of claim 26 further comprising a water storage unit fluidly coupled to said at least one hydrogen generator.

28. The regenerative fuel cell system of claim 27 further comprising at least one second hydrogen generator coupled to said storage container and said water storage unit.

29. The regenerative fuel cell system of claim 28 further comprising a user interface electrically connected to said power generator, said storage container and said first and second hydrogen generators.

30. The regenerative fuel cell system of claim 29 wherein said user interface includes means for providing electrical power to said first and second hydrogen generator and said at least one power generator.

31. The regenerative fuel cell system of claim 25 wherein said unregulated dc bus is electrically connected to said at least one first hydrogen generator.

32. The regenerative fuel cell system of claim 28 wherein said unregulated dc bus is electrically connected to said at least one first hydrogen generator and said at least one second hydrogen generator.

33. The regenerative fuel cell system of claim 32 where in said unregulated dc bus is electrically connected to said storage container and said user interface.

34. A health monitoring system for a regenerative fuel cell system comprising:

at least one hydrogen storage container having a first sensor associated therewith;

at least one hydrogen generator fluidly coupled with said storage container and having a second sensor associated therewith;

at least one power generator having a third sensor associated therewith; and

,

a disconnect device electrically connected to said first, second and third sensors wherein said disconnect device disables said hydrogen generator, said power generator and said storage container in response to a signal from said first second or third sensor.

35. The health monitoring system of claim 34 wherein said first, second or third sensor is chosen from a group comprising:

thermal fuse, pyrometer, combustible gas detector, tachmeter, a smoke detector, a pressure switch, a pressure transducer, a flow switch or a level sensor.

36. The health monitoring system of claim 34 wherein said disconnect device is a contactor.

37. A manifold for limited hydrogen flow to a power generator having a fuel cell, said manifold comprising:

an input port;

at least one output port fluidly coupled to said input port; and

,

at least one orifice associated with said at least one output port, said orifice sized to limit hydrogen flow to the fuel cell to a predetermined maximum flow rate.

38. The manifold of claim 37 wherein said orifice has a diameter of 0.187 inches and limits the flow of gas to 99 liters per minute at 150 psi.