Polyvinyl alcohol film and polarizing film

• US 20050186441A1
• Filed: 05/02/2005
• Published: 08/25/2005
• Est. Priority Date: 12/17/2001
• Status: Active Grant

• Current Assignee: Kuraray Company Limited
• Original Assignee: Kuraray Company Limited
• Inventors: Hayashi, Tetsushi, Isozaki, Takanori, Fujiwara, Naoki
• Granted Patent: US 7,183,344 B2
• Time in Patent Office: Days
• US Class Current: 428/523
• CPC Class Codes: C08F 210/02 Ethene
• CPC Class Codes: C08F 216/06 Polyvinyl alcohol ; Vinyl alcohol
• CPC Class Codes: C08F 2500/26 Use as polymer for film forming
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: C08J 7/14 with acids, their salts or anhydrides
• CPC Class Codes: C09K 2323/00 Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
• CPC Class Codes: G02B 5/3033 in the form of a thin sheet or foil, e.g. Polaroid
• CPC Class Codes: G02F 1/133528 Polarisers
• CPC Class Codes: Y10T 428/31938 Polymer of monoethylenically unsaturated hydrocarbon

Abstract

The invention is a film of a vinyl alcohol polymer that contains from 0.01 to 20 mol % of cationic group-containing units and contains from 0.5 to 24 mol % of α-olefin units having at most 4 carbon atoms. The polyvinyl alcohol film gives polarizing films and polarizer which are resistant to water and have good polarizing properties and which are free from a problem of irregular coloration.

Claims

1-14. -14. (canceled)

15. A polarizing film produced by stretching a polyvinyl alcohol film of a vinyl alcohol polymer that contains from 0.01 to 20 mol % of cationic group-containing units, from 0.5 to 24 mol % of α

-olefin units having at most 4 carbon atoms and from 1 to 30 parts by weight, based on 100 parts by weight of the vinyl alcohol polymer, of a polyhydric alcohol, and wherein the thickness of the polyvinyl alcohol film ranges from 20 to 100 μ

m.

16. The polarizing film as claimed in claim 15, wherein the cationic group-containing units are derived from a monomer selected from the group consisting of trimethyl-(3-acrylamido-3-dimethylpropyl)ammonium chloride, 3-acrylamidopropyltrimethylammonium chloride, 3-methacrylamidopropyltrimethylammonium chloride, quaternary ammonium salts of N-(3-allyloxy-2-hydroxypropyl)dimethylamine, quaternary ammonium salts of N-(4-allyloxy-3-hydroxybutyl)diethylamine and quaternary ammonium salts of acrylamide, N-methylacrylamide, N-ethylacrylamide, N,N-dimethylacrylamide, diacetoneacrylamide, N-methylolacrylamide, methacrylamide, N-methylmethacrylamide, N-ethylmethacrylamide and N-methylolmethacrylamide.

17. The polarizing film as claimed in claim 15, wherein the content of cationic group-containing units in the polymer ranges from 0.05 to 10 mol % and the content of α

-olefin units having at most 4 carbon atoms ranges from 0.8 to 15 mol %.

18. The polarizing film as claimed in claim 17, wherein the content of cationic group-containing units in the polymer ranges from 0.1 to 5 mol % and the content of α

-olefin units having at most 4 carbon atoms ranges from 1 to 8 mol %.

19. The polarizing film as claimed in claim 15, wherein the unit content of the vinyl alcohol polymer is comprised of units of a copolymerizable unsaturated monomer selected from the group consisting of acrylic acid, methacrylic acid, phthalic acid (anhydride), maleic acid (anhydride), itaconic acid (anhydride), acrylonitrile, methacrylonitrile, acrylamido-2-methylpropanesulfonic acid and its sodium salt, sodium vinylsulfonate, sodium allylsulfonate, ethyl vinyl ether, butyl vinyl ether, vinyl chloride, vinyl bromide, vinyl fluoride, vinylidene chloride, vinylidene fluoride and tetrafluoroethylene in an amount of less than 10 mol %.

20. The polarizing film as claimed in claim 18, wherein the unit content of the copolymerizable unsaturated monomer is less than 5 mol %.

21. The polarizing film as claimed in claim 15, wherein the thickness of the film after stretching is 3 to 75 μ

m.

22. The polarizing film as claimed in claim 15, for which the polyvinyl alcohol film is colored with a dichroic dye.

23. A polarizer produced by laminating a protective film on each surface or on one surface of the polarizing film of claim 15.

24. A liquid crystal display containing the polarizing film according to claim 15.