Integrated photoelectrochemical cell and system having a solid polymer electrolyte

• US 20050205128A1
• Filed: 05/23/2005
• Published: 09/22/2005
• Est. Priority Date: 11/25/2002
• Status: Abandoned Application

• Current Assignee: University of Toledo
• Original Assignee: University of Toledo
• Inventors: Deng, Xunming, Xu, Liwei
• Application Number:
  US11/134,928
• Publication Number:
  US 20050205128A1
• Time in Patent Office: Days
• US Class Current: 136/256
• CPC Class Codes: C25B 1/55 Photoelectrolysis
• CPC Class Codes: H01G 9/2009 Solid electrolytes
• CPC Class Codes: H01G 9/2045 comprising a semiconductor electrode comprising elements of the fourth group of the Periodic System (C, Si, Ge, Sn, Pb) with or without impurities, e.g. doping materials
• CPC Class Codes: H01M 14/005 Photoelectrochemical storage cells light sensitive devices H01G9/20, semiconductors sensitive to light H01L31/00
• CPC Class Codes: Y02E 10/542 Dye sensitized solar cells
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02P 20/133 Renewable energy sources, e.g. sunlight
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A photoelectrochemical (PEC) cell includes a photovoltaic electrode that generates voltage under radiation; a solid membrane electrode assembly that includes at least one solid polymer electrolyte and first and second electrodes; a mechanism that collect gases from oxidation and reduction reactions; and an electrical connection between the photovoltaic electrode and the solid membrane electrode assembly. A PEC system and a method of making such PEC cell and PEC system are also disclosed.

Claims

1. A photoelectrochemical (PEC) cell, comprising:

at least one photovoltaic electrode that generates voltage under radiation;

at least one solid membrane electrode assembly (MEA) that includes at least one solid polymer electrolyte and a first electrode on one side of the solid polymer and a second electrode on an opposing side of the solid polymer electrolyte;

at least one mechanism that collect gases from oxidation and reduction reactions; and

at least one electrical connection between the photovoltaic electrode and the solid membrane electrode assembly.

2. The PEC cell as in claim 1, wherein the photovoltaic electrode generates sufficient voltage under radiation for electrolysis.

3. The PEC cell as in claim 2, wherein the photovoltaic electrode comprises at least one of following semiconductor junctions:

amorphous silicon (a-Si), cadmium telluride (CdTe), copper indium diselenide (CuInSe₂), copper indium gallium diselenide (CIGS), III-V (GaAs, InP etc), crystalline silicon (c-Si), thin film silicon (thin-Si), or variations and combinations thereof.

4. The PEC cell as in claim 3, wherein at least one of the photovoltaic junction comprises amorphous silicon.

5. The PEC cell as in claim 3, wherein the semiconductor junction comprises multiple junctions.

6. The PEC cell as in claim 5, wherein the semiconductor junction comprises at least one metal oxide.

7. The PEC cell as in claim 6, wherein the metal oxide comprises TiO₂, WO₃ or Fe₂O₃ and combinations thereof.

8. The PEC cell as in claim 6, wherein the metal oxide is alloyed with at least one another material selected from Ca and/or Mg, to increase radiation absorption.

9. The PEC cell as in claim 5, wherein the semiconductor junction comprises at least one III-V compound semiconductor.

10. The PEC cell as in claim 9, wherein the III-V compound semiconductor includes at least one of:

InGaN, GaPN, GaAsPN, GaP and combinations thereof.

11. The PEC cell as in claim 5, wherein the semiconductor junction comprises at least one Group IV semiconductor or semiconductor alloy.

12. The PEC cell as in claim 11, wherein the Group IV semiconductor or semiconductor alloy includes at least one of:

Si, C, Ge, Sn, SiC, GeC and combinations thereof, in both amorphous and crystalline form.

13. The PEC cell as in claim 1, wherein the radiation comprises photons, electrons or other energy-carrying radiations and particles.

14. The PEC cell as in claim 13, wherein the radiation comprises solar radiation.

15. The PEC cell as in claim 1, wherein the solid membrane electrode assembly comprises at least one ion-exchange membrane.

16. The PEC cell as in claim 15, wherein the membrane comprises at least one of a cation exchange membrane or an anion-exchange membrane.

17. The PEC cell as in claims 15, wherein the ion-exchange membrane is installed behind the photovoltaic electrode and away from the radiation to allow for maximum radiation to reach the photovoltaic electrode.

18. The PEC cell as in claim 17, wherein the membrane comprises a perfluorinated polymer that contains small proportions of sulfonic or carboxylic ionic functional groups.

19. The PEC cell as in claim 1, wherein the mechanism for collecting gases comprises first and second electrically conducting end plates, the first electrically conducting end plate defining a first compartment, and the second electrically conducting end plate defining a second compartment.

20. The PEC as in claim 19, wherein the end plates comprise a corrosion-resistant conductor or a conductor coated with a thin corrosion-resistant conducting layer.

21. The PEC cell as in claim 19 wherein the first and second compartments comprise a plurality of channels in each of the opposing electrically conducting end plates.

44. The PEC cell of claim 1, wherein the photovoltaic electrode comprises:

metal substrate, metal reflector, first transparent conducting oxide (TCO), n-type a-Si layer, intrinsic a-SiGe layer or microcrystalline silicon layer, p-type a-Si based layer, n-type a-Si layer, intrinsic a-Si layer or a-SiGe layer, p-type a-Si based layer, n-type a-Si layer, intrinsic a-Si layer, p-type a-Si based layer (nipnipnip layers), second TCO layer.

45. The PEC cell of claim 1, wherein the photovoltaic electrode comprises:

metal substrate, metal reflector, first transparent conducting oxide (TCO) layer, p-type a-Si based layer, intrinsic a-SiGe layer or microcrystalline silicon layer, n-type a-Si layer, p-type a-Si based layer, intrinsic a-Si or a-SiGe layer, n-type a-Si layer, p-type a-Si based layer, intrinsic a-Si layer, n-type a-Si layer (pinpinpin layers), second TCO layer.

46. A light illuminating device comprising the PEC cell of claim 1.

47. A particle or radiation detector device comprising the PEC cell of claim 1.

48. A device for generating gases comprising the PEC cell of claim 1.

49. The device of claim 48 for generating hydrogen and oxygen.

22. A PEC system comprising:

i) a photoelectrochemical (PEC) cell, comprising;

a substrate that is substantially transparent to radiation;

at least one photovoltaic electrode that generates voltage under radiation;

at least one solid membrane electrode assembly that includes at least one solid polymer electrolyte and a first electrode on one side of the solid polymer and a second electrode on an opposing side of the solid polymer electrolyte;

at least one mechanism that collect gases from oxidation and reduction reactions; and

at least one electrical connection between the photovoltaic electrode and the solid membrane electrode assembly; and

,

ii) at least one collecting mechanism to collect gases generated by the PEC cell.

23. The PEC system as in claim 22 comprising at least one end adaptor that delivers water to the PEC cell.

24. The PEC system as in claim 22 comprising collecting water mixed with oxygen or hydrogen bubbles from the PEC cell.

25. The PEC system as in claim 22, wherein the collecting mechanism comprises

a first collection container for receiving a first gas generated in the first compartment;

a second collection container for receiving a second gas generated in the second compartment; and

a supply of water for circulating through the first and second compartments.

26. The PEC system as in claim 25, wherein hydrogen gas is generated in the a compartment in the PEC cell and exits from a first outlet tube operatively connected to the first collection container, and wherein oxygen is generated in a second compartment in the PEC cell and exits from a second outlet tube operatively connected to the second collection container.

27. The PEC system as in claim 26, further comprising first and second pumps for circulating water wherein gases and water are circulated by the pumps through the first and second gas collection containers, respectively, so that hydrogen is collected at a first collection port in the first gas collection container and oxygen is collected at a second collection port in the second gas collection container;

and wherein water flows from first and second recycling ports in the first and second collection containers, respectively, back into the first and second top compartments respectively, through third and fourth inlet tubes operatively connected to a second end adaptor on and opposing end of the PEC cell.

28. The PEC system as in claim 27, further comprising first and second water inlet valves and switches operatively connected via first and second ports, respectively, to the first and second gas collection containers to allow additional water to flow into the system.

29. A method of making a PEC cell comprising:

a) forming a photovoltaic (PV) structure,

b) placing a reflective metal layer adjacent the PV structure,

c) forming a membrane electrode assembly,

d) forming electrically conducting end plates on each side of the membrane electrode assembly, and

e) forming at least one electrical connection between a radiation side of the PV structure and the membrane electrode assembly.

30. The method as in claim 29 wherein the photovoltaic (PV) structure is formed by

i) depositing a first transparent conductor layer on a substrate,

ii) depositing at least one semiconductor junction comprising a photovoltaic electrode on the first transparent conductor layer, and

iii) depositing a second transparent conductor layer on an opposing side of the semiconductor junction.

31. The method as in claim 29 wherein the membrane electrode assembly is formed by:

i) forming a solid polymer electrolyte, and

ii) forming opposing electrodes on each side of the solid polymer electrolyte.

32. The method of making the PEC cell described in claim 30, wherein the substrate comprises a metal foil or plate.

33. The method of making the PEC cell described in claim 29, wherein the reflective metal layer comprises an aluminum layer.

34. The method of making the PEC cell described in claim 30, wherein the first transparent conductor layer comprises at least one of tin oxide, zinc oxide indium oxide, indium tin oxide, or combinations and mixtures thereof.

35. The method of making the PEC cell described in claim 30, wherein the PV structure is isolated using a scribing process that includes laser scribing.

36. The method of making the PEC cell described in claim 30, wherein the semiconductor junction comprises a-Si based semiconductor layers.

37. The method of making the PEC cell described in claim 30, wherein a thin layer of catalyst is deposited on the second transparent conductor layer.

38. The method of making the PEC cell described in claim 30, further includes depositing a catalyst comprising a thin layer of carbon powder with micrometer sized spheres that support nanometer sized Pt particles on the substrate.

39. The method of making the PEC cell described in claim 38, wherein the carbon powder is pressed or bonded to the transparent conductor layer.

40. The method of making the PEC cell described in claim 39, wherein the catalyst is applied to selected regions so that the catalyst does not substantially block incoming radiation.

41. The PEC system as in claim 40, wherein hydrogen gas is generated in a first compartment and exits from a first outlet tube operatively connected to the first collection container, and wherein oxygen is generated in a second compartment and exits from a second outlet tube operatively connected to the second collection container.

42. The PEC system as in claim 41, further comprising first and second pumps for circulating water wherein gases and water are circulated by the pumps through first and second gas collection containers, respectively, so that hydrogen is collected at a first collection port in the first gas collection container and oxygen is collected at a second collection port in the second gas collection container;

and wherein water flows from first and second recycling ports in the first and second collection containers, respectively, back into the first and second top compartments respectively, through third and fourth inlet tubes operatively connected to a second end adaptor on and opposing end of the PEC cell.

43. The PEC system as in claim 42, further comprising first and second water inlet valves and switches operatively connected via first and second ports, respectively, to the first and second gas collection containers to allow additional water to flow into the system.