Optical element, process for production thereof, substrate for liquid crystal alignment, liquid crystal display device, and birefringent material

• US 20050206818A1
• Filed: 01/31/2005
• Published: 09/22/2005
• Est. Priority Date: 02/02/2004
• Status: Abandoned Application

• Current Assignee: Dai Nippon Printing Company Limited
• Original Assignee: Dai Nippon Printing Company Limited
• Inventors: Hayashi, Shinji
• Application Number:
  US11/047,356
• Publication Number:
  US 20050206818A1
• Time in Patent Office: Days
• US Class Current: 349/123
• CPC Class Codes: C09K 19/2007 the chain containing -COO- or -OCO- groups
• CPC Class Codes: C09K 19/3857 containing at least one asymmetric carbon atom
• CPC Class Codes: C09K 19/588 Heterocyclic compounds
• CPC Class Codes: C09K 2019/0448 the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate
• CPC Class Codes: G02F 1/133565 inside the LC elements, i.e. between the cell substrates
• CPC Class Codes: G02F 1/13363 Birefringent elements, e.g. for optical compensation
• CPC Class Codes: G02F 1/133633 using mesogenic materials
• CPC Class Codes: G02F 1/133634 the refractive index Nz perpendicular to the element surface being different from in-plane refractive indices Nx and Ny, e.g. biaxial or with normal optical axis
• CPC Class Codes: G02F 2413/02 Number of plates being 2

Abstract

There is provided an optical element which has desired birefringence characteristics and, at the same time, has a low haze value. The optical element comprises: a birefringence layer comprising a chiral agent and a polymerizable liquid crystal comprised of rodlike molecules; and a light transparent base material for supporting the birefringence layer. The polymerizable liquid crystal has a molecular arrangement which has been fixed by crosslinking while holding a planar cholesteric phase structure. A substrate layer underlying the birefringence layer is formed of glass or silicon oxide.

Claims

1. An optical element comprising:

a birefringence layer comprising a chiral agent and a polymerizable liquid crystal comprised of rodlike molecules; and

a light transparent base material for supporting the birefringence layer,

said polymerizable liquid crystal having a molecular arrangement which has been fixed by crosslinking while holding a planar cholesteric phase structure,

a substrate layer underlying said birefringence layer being formed of glass or silicon oxide.

2. The optical element according to claim 1, wherein said light transparent base material is a glass substrate and said birefringence layer is provided directly on one side of said glass substrate.

3. The optical element according to claim 1, wherein said light transparent base material comprises a resin substrate and a glass thin film or a silicon oxide film provided on one side of the resin substrate and said birefringence layer is provided directly on said glass thin film or silicon oxide film.

4. The optical element according to claim 1, wherein said light transparent base material comprises a light transparent substrate, a light absorption-type color filter provided on said light transparent substrate, a glass thin film or a silicon oxide film provided to cover the light absorption-type color filter and said birefringence layer is provided directly on the glass thin film or silicon oxide film.

5. The optical element according to claim 1, wherein said birefringence layer further comprises a silane coupling agent.

6. A process for producing an optical element according to claim 1, said process comprising:

providing a light transparent base material provided with a film formed of glass or silicon oxide;

coating a coating composition comprising a chiral agent and a polymerizable liquid crystal of rodlike molecules onto a said film formed of glass or silicon oxide,

aligning said polymerizable liquid crystal in the coating to a planar cholesteric phase; and

crosslinking said polymerizable liquid crystal in such a state that the alignment in the planar cholesteric phase is held, thereby fixing the molecular arrangement of said polymerizable liquid crystal.

7. The process according to claim 6, wherein said coating composition further comprises a silane coupling agent.

8. A substrate for liquid crystal alignment, comprising at least a light transparent base material and an aligning film provided on one side of said light transparent base material, wherein

a birefringence layer is provided between said light transparent base material and said aligning film or on the base material in its surface remote from said aligning film,

said birefringence layer comprises a chiral agent and a polymerizable liquid crystal comprised of rodlike molecules, and the molecular arrangement of the polymerizable liquid crystal has been fixed by crosslinking while holding a planar cholesteric phase structure, and

a substrate layer underlying said birefringence layer is formed of glass or silicon oxide.

9. The substrate for liquid crystal alignment according to claim 8, wherein

said light transparent base material comprises a glass substrate,

said birefringence layer is provided directly on one side of said glass substrate,

a light absorption-type color filter is provided on said birefringence layer, and

said aligning film is provided to cover said light absorption-type color filter.

10. The substrate for liquid crystal alignment according to claim 8, wherein

said light transparent base material comprises a resin substrate and a glass thin film or a silicon oxide film provided on one side of the resin substrate and said birefringence layer is provided directly on said glass thin film or silicon oxide film,

a light absorption-type color filter is provided on said birefringence layer, and

said aligning film is provided to cover said light absorption-type color filter.

11. The substrate for liquid crystal alignment according to claim 8, wherein said light transparent base material comprises a light transparent substrate, a light absorption-type color filter provided on said light transparent substrate, a glass thin film or a silicon oxide film provided to cover the light absorption-type color filter,

said birefringence layer is provided directly on the glass thin film or silicon oxide film, and

said aligning film is provided to cover said birefringence layer.

12. A liquid crystal display device comprising a liquid crystal panel for display, said liquid crystal panel comprising:

a first substrate for liquid crystal alignment located on its display surface side; and

a second substrate for liquid crystal alignment located on its backside, wherein

said first substrate for liquid crystal alignment and/or said second substrate for liquid crystal alignment are the substrate for liquid crystal alignment according to claim 8.

13. A birefringent material comprising a chiral agent, a polymerizable liquid crystal comprised of rodlike molecules, and a silane coupling agent, wherein the molecular arrangement of said polymerizable liquid crystal has been fixed by crosslinking while holding a planar cholesteric phase structure.