Method of fabricating an optoelectronic device having a bulk heterojunction

• US 20050227390A1
• Filed: 11/30/2004
• Published: 10/13/2005
• Est. Priority Date: 04/13/2004
• Status: Active Grant

• Current Assignee: The Trustees of Princeton University (Princeton University)
• Original Assignee: The Trustees of Princeton University (Princeton University)
• Inventors: Forrest, Stephen R., Shtein, Max, Yang, Fan
• Granted Patent: US 7,435,617 B2
• Time in Patent Office: Days
• US Class Current: 438/22
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: H10K 2102/103 comprising indium oxides, e.g. ITO
• CPC Class Codes: H10K 30/10 comprising heterojunctions between organic semiconductors and inorganic semiconductors
• CPC Class Codes: H10K 30/211 comprising multiple junctions, e.g. double heterojunctions
• CPC Class Codes: H10K 30/30 comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains
• CPC Class Codes: H10K 30/50 Photovoltaic [PV] devices
• CPC Class Codes: H10K 71/16 using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
• CPC Class Codes: H10K 85/311 Phthalocyanine
• CPC Class Codes: H10K 85/621 Aromatic anhydride or imide compounds, e.g. perylene tetra-carboxylic dianhydride or perylene tetracarboxylic di-imide
• CPC Class Codes: Y02E 10/549 Organic PV cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A method of fabricating an optoelectronic device comprises: depositing a first layer having protrusions over a first electrode, in which the first layer comprises a first organic small molecule material; depositing a second layer on the first layer such that the second layer is in physical contact with the first layer; in which the smallest lateral dimension of the protrusions are between 1 to 5 times the exciton diffusion length of the first organic small molecule material; and depositing a second electrode over the second layer to form the optoelectronic device. A method of fabricating an organic optoelectronic device having a bulk heterojunction is also provided and comprises: depositing a first layer with protrusions over an electrode by organic vapor phase deposition; depositing a second layer on the first layer where the interface of the first and second layers forms a bulk heterojunction; and depositing another electrode over the second layer.

Claims

1. A method of fabricating an optoelectronic device, comprising:

depositing a first layer having protrusions over a first electrode, wherein the first layer comprises a first organic small molecule material;

depositing a second layer on the first layer such that the second layer is in physical contact with the first layer;

wherein the smallest lateral dimension of the protrusions is between 1 to 5 times the exciton diffusion length of the first organic small molecule material; and

depositing a second electrode over the second layer to form the optoelectronic device.

2. The method of claim 1, wherein the second layer comprises polymer or semiconductor material.

3. The method of claim 2, wherein the spacing between protrusions is between 1 to 5 times the exciton diffusion length of the second layer.

4. The method of claim 1, wherein the second layer comprises a metal.

5. The method of claim 1, wherein:

the first layer having protrusions is deposited over the first electrode by organic vapor phase deposition, and the smallest lateral dimension of the protrusions is at least 5% less than the thickness of the device; and

the interface of the second layer and the first layer forms a bulk heterojunction, and the second layer has a planar surface.

6. The method of claim 5, wherein the first layer is an electron donor layer, the first electrode is an anode, the second layer is an electron acceptor layer, and the second electrode is a cathode.

7. The method of claim 5, wherein the first layer is an electron acceptor layer, the first electrode is a cathode, the second layer is an electron donor layer, and the second electrode is an anode.

8. The method of claim 6, wherein the first electrode comprises ITO, the first layer comprises CuPc, and the second layer comprises PTCBI.

9. The method of claim 8, wherein the source evaporation temperature for deposition of the first layer is at least 400°

C.

10. The method of claim 8, wherein the underlying substrate temperature for deposition of the first layer is less than 40°

C.

11. The method of claim 8, wherein the nitrogen gas carrier flow rate for deposition of the first layer is from 10-200 sccm.

12. The method of claim 8, wherein the chamber pressure for deposition of the first layer is from 0.15-0.80 Torr.

13. The method of claim 8, wherein the source evaporation temperature for deposition of the second layer is at least 400°

C.

14. The method of claim 8, wherein the substrate temperature for deposition of the second layer is less than 25°

C.

15. The method of claim 8, wherein the nitrogen gas carrier flow rate for deposition of the first layer is at least 100 sccm.

16. The method of claim 8, wherein the chamber pressure is from at least 0.50 Torr.

17. The method of claim 6, further comprising depositing a third layer over the second layer, such that the second electrode is deposited over the third layer.

18. The method of claim 17, wherein the third layer is an exciton blocking layer.

19. The method of claim 18, wherein the third layer comprises BCP.

20. The method of claim 6, wherein the first electrode comprises ITO, the first layer comprises CuPc, and the second layer comprises C₆₀.

21. The method of claim 5, further comprising depositing the first layer over a substrate.

22. The method of claim 5, wherein the device has a current density, J_SC, greater than 9 (mA/cm²) and an open circuit voltage, V_OC, between 0.4 volts and 1 volts.

23. The method of claim 5, wherein the device has a series resistance of less than 10 Ω

cm².

24. The method of claim 5, wherein the device has an external power conversion efficiency of at least 1.5% under 100 mW/cm² (AM 1.5 G) illumination.

25. The method of claim 5, further comprising:

depositing a charge recombination layer over the second layer;

depositing a third layer having protrusions over the second electrode by organic vapor phase deposition, wherein the third layer comprises a third organic small molecule material and the smallest lateral dimension of the protrusions is at least 5% less than the thickness of the device;

depositing a fourth layer on the third layer such that the fourth layer is in physical contact with the third layer, wherein the interface of the fourth layer and the third layer forms a bulk heterojunction, and the fourth layer has a planar surface; and

depositing a third electrode over the second layer to form the optoelectronic device.

26. The method of claim 17, further comprising:

depositing an electron-hole recombination zone over the third layer;

depositing a fourth layer over the electron-hole recombination zone by organic vapor phase deposition, wherein the fourth layer comprises a fourth organic small molecule material;

depositing a fifth layer on the fourth layer such that the fifth layer is in physical contact with the fourth layer, wherein the interface of the fifth layer on the fourth layer forms a bulk heterojunction, and the fifth layer has a planar surface; and

depositing an exciton blocking layer over the fifth layer; and

,

depositing the second electrode over the fifth layer to form the optoelectronic device.

27. The method of claim 1, wherein the height of the protrusions is at least equal to half of the smallest lateral dimension of the protrusions.