Steam-generating combustion system and method for emission control using oxygen enhancement

• US 20050233274A1
• Filed: 05/31/2005
• Published: 10/20/2005
• Est. Priority Date: 02/15/2002
• Status: Active Grant

• Current Assignee: Erwin Penfornis, Fabienne Chatel-Pelage, Ovidiu Marin, Scott Macadam
• Original Assignee: Erwin Penfornis, Fabienne Chatel-Pelage, Ovidiu Marin, Scott Macadam
• Inventors: Chatel-Pelage, Fabienne, Penfornis, Erwin, Macadam, Scott, Marin, Ovidiu
• Granted Patent: US 7,320,288 B2
• Time in Patent Office: Days
• US Class Current: 431/116
• CPC Class Codes: B01D 53/32 by electrical effects other than those provided for in group B01D61/00
• CPC Class Codes: F23G 2204/201 Plasma
• CPC Class Codes: F23G 5/50 Control or safety arrangements
• CPC Class Codes: F23G 7/061 with supplementary heating
• CPC Class Codes: F23J 15/006 Layout of treatment plant
• CPC Class Codes: F23J 2215/10 Nitrogen; Compounds thereof
• CPC Class Codes: F23J 2215/20 Sulfur; Compounds thereof
• CPC Class Codes: F23J 2215/50 Carbon dioxide
• CPC Class Codes: F23J 2215/60 Heavy metals; Compounds thereof
• CPC Class Codes: F23J 2217/102 electrostatic
• CPC Class Codes: F23J 2900/15061 Deep cooling or freezing of flue gas rich of CO2 to deliver CO2-free emissions, or to deliver liquid CO2
• CPC Class Codes: F23L 2900/07001 Injecting synthetic air, i.e. a combustion supporting mixture made of pure oxygen and an inert gas, e.g. nitrogen or recycled fumes
• CPC Class Codes: F23L 2900/07007 using specific ranges of oxygen percentage
• CPC Class Codes: F23L 7/005 Evaporated water; Steam
• CPC Class Codes: F23L 7/007 Supplying oxygen or oxygen-enriched air
• CPC Class Codes: Y02E 20/12 Heat utilisation in combustion or incineration of waste
• CPC Class Codes: Y02E 20/32 Direct CO2 mitigation
• CPC Class Codes: Y02E 20/34 Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

Abstract

A steam-generating combustion system includes an oxygen enriched gas provided as at least part of an oxidant stream. A combustion chamber receives and combusts a fuel in the oxidant stream and generate steam. The combustion chamber generates flue gas having a flue gas volume which is smaller than a volume of flue gas generated by the combustion chamber when operated with air as the oxidant stream. A flue gas pollutant control system receives the flue gas from the combustion chamber and reduces at least one of particulate matter, SO_x, NO_x, and mercury. The reduction in flue gas volume allows the implementation of much smaller pollutant control equipment, since the size of the pollutant control units is mainly based on the volume or mass flow rate of flue gas to be treated. Moreover, the system including oxygen-enriched gas in the oxidant will lead to concentrated levels of the pollutants in the flue gas. The high concentrations of pollutants will enhance their absorption in the different pollutant control systems, improving removal efficiency for all species.

Claims

1. A steam-generating combustion system, comprising:

an oxidant delivery system providing an oxidant stream;

an oxygen enriched gas generation system providing an oxygen enriched gas with 21% to 100% oxygen to the oxidant delivery system;

a fuel delivery system providing a fuel stream with a fuel mass flow rate;

a combustion chamber arranged to receive and combust the fuel stream in the oxidant stream and generate steam, the combustion chamber generating flue gas having a flue gas mass flow rate which is smaller than the mass flow rate of flue gas generated by the combustion chamber when operated with the same fuel mass flow rate and with air as the oxidant stream; and

a flue gas pollutant control system receiving the flue gas from the combustion chamber and reducing the amount of at least one of particulate matter, SO_x, NO_x, and mercury in the flue gas.

2. The system of claim 1, wherein the oxidant delivery system includes a dilution gas delivery system delivering dilution gas to the oxygen enriched gas to form the oxidant stream.

3. The system of claim 2, wherein the dilution gas delivery system delivers a dilution gas in the form of recirculated wet or dry flue gas.

4. The system of claim 2, wherein the dilution gas delivery system delivers a dilution gas comprising at least one of air, CO₂, N₂ or steam.

5. The system of claim 1, wherein the oxygen enriched gas generation system provides oxygen enriched gas with about 90% oxygen or greater.

6. The system of claim 1, wherein the oxidant delivery system provides an oxidant stream with about 90% oxygen or greater.

7. The system of claim 1, wherein the oxygen-enriched gas generation system comprises an air separation unit configured to separate air into at least a first stream of gaseous oxygen having a purity of about 90% or greater and a second stream.

8. The system of claim 7, wherein the second stream is nitrogen having a purity of about 90% or greater.

9. The system of claim 1, wherein the oxygen-enriched gas generation system comprises an air separation unit configured to separate air into at least a first stream of gaseous oxygen having a purity of about 95% or greater and a second stream.

10. The system of claim 9, wherein the second stream is nitrogen having a purity of between about 98% or greater.

11. The system of claim 1, wherein the oxidant delivery system provides the oxidant stream to the combustion chamber in a plurality of streams having different compositions.

12. The system of claim 1, further comprising an electric generator connected to a steam outlet of the combustion chamber.

13. The system of claim 1, wherein the fuel delivery system provides a fuel stream of natural gas, waste gases from industrial processes, or other gaseous fuels.

14. The system of claim 1, wherein the fuel delivery system provides a fuel stream of coal, coke, stoker, solid heavy residues, or other solid fuels.

15. The system of claim 1, wherein the fuel delivery system provides a fuel stream of oil, liquid heavy residues, or other liquid fuels.

16. The system of claim 1, wherein the flue gas pollutant control system includes separate devices for reduction of particulate matter, SO_x, NO_x, and mercury.

17. The system of claim 1, wherein the flue gas pollutant control system includes a combined device for reduction of the amount of at least two of particulate matter, SO_x, NO_x, and mercury.

18. The system of claim 1, wherein the flue gas pollutant control system includes a plasma-based flue gas treatment device for oxidizing at least one of NO, SO₂, and Hg, into water soluble oxides.

19. The system of claim 18, wherein the plasma-based flue gas treatment device is enhanced with oxygen injection.

20. The system of claim 18, comprising an absorption vessel and a wet electrostatic precipitator receiving the water soluble oxides from the plasma-based flue gas treatment device and reducing the amount of the water soluble oxides.

21. The system of claim 1, wherein the flue gas mass flow rate exiting the combustion chamber is at least a factor of two times smaller than the mass flow rate of flue gas exiting the combustion chamber when the combustion chamber is operated in the same conditions except with air as the oxidant stream.

22. The system of claim 1, wherein the flue gas pollutant control system includes devices having flue gas flow capacities smaller than the flue gas capacity needed to treat a flue gas generated by the combustion chamber when operated with air as the oxidant stream.

23. A method of steam-generating combustion, comprising:

providing an oxidant enriched gas stream with an oxygen content of 21% to 100%;

creating an oxidant stream containing the oxygen enriched gas stream;

combusting a fuel in the oxidant stream in a steam-generating combustion chamber and generating flue gas having a flue gas mass flow rate which is smaller than a mass flow rate of flue gas generated by the combustion chamber when operated with the same mass flow rate of fuel and with air as the oxidant stream; and

reducing the amount of at least one of particulate matter, SO_x, NO_x, and mercury in the flue gas with a flue gas pollutant control system.

24. The method of claim 23, wherein the step of creating an oxidant stream comprises delivering a dilution gas to the oxygen enriched gas to form the oxidant stream.

25. The method of claim 24, wherein the dilution gas comprises recirculated wet or dry flue gas.

26. The method of claim 24, wherein the dilution gas comprises at least one of air, CO₂, N₂ or steam.

27. The method of claim 24, wherein the oxygen enriched gas stream has an oxygen content of about 90% or greater.

28. The method of claim 23, wherein the oxidant stream has an oxygen content of about 90% or greater.

29. The method of claim 23, wherein the oxidant enriched gas stream is generated by an air separation unit configured to separate air into at least a first stream of gaseous oxygen having a purity of about 90% or greater and a second stream.

30. The method of claim 29, wherein the second stream is nitrogen having a purity of about 90% or greater.

31. The method of claim 23, wherein the oxidant enriched gas stream is generated by an air separation unit configured to separate air into at least a first stream of gaseous oxygen having a purity of about 95% or greater and a second stream.

32. The method of claim 31, wherein the second stream is nitrogen having a purity of between about 98% or greater.

33. The method of claim 23, wherein the oxidant stream is delivered to the combustion chamber in a plurality of streams having different compositions.

34. The method of claim 23, further comprises generating electricity with steam from the combustion chamber.

35. The method of claim 23, wherein the fuel comprises natural gas, waste gases from industrial processes, or other gaseous fuels.

36. The method of claim 23, wherein the fuel comprises coal, coke, stoker, solid heavy residues, or other solid fuels.

37. The method of claim 23, wherein the fuel comprises oil, liquid heavy residues, or other liquid fuels.

38. The method of claim 23, wherein the flue gas pollutant control system includes separate devices for reduction of particulate matter, SO_x, NO_x, and mercury.

39. The method of claim 23, wherein the flue gas pollutant control system includes a combined device for reduction of at least two of particulate matter, SO_x, NO_x, and mercury.

40. The method of claim 23, wherein the flue gas pollutant control system includes a plasma-based flue gas treatment device for oxidizing at least one of NO, SO₂, and Hg, into water soluble oxides.

41. The method of claim 40, wherein the plasma-based flue gas treatment device is enhanced with oxygen injection.

42. The method of claim 40, comprising an absorption vessel and a wet electrostatic precipitator receiving the water soluble oxides from the plasma-based flue gas treatment device and reducing the amount of the water soluble oxides.

43. The method of claim 23, wherein the flue gas mass flow rate exiting in the combustion chamber is at least a factor of two times smaller than the mass flow rate of flue gas exiting by the combustion chamber when the combustion chamber is operated in the same conditions except with air as the oxidant stream.

44. The method of claim 23, wherein the flue gas pollutant control system includes devices having flue gas flow capacities smaller than the flue gas capacity needed to treat a flue gas generated by the combustion chamber when operated with air as the oxidant stream.

45. A method of retrofitting or repowering a commercial air-fired, steam-generating combustion system to reduce overall cost of emission control, the method comprising:

adding an oxygen-enriched gas generation system to the air-fired, steam-generating combustion system to deliver an oxygen enriched stream with 21% to 100% oxygen;

delivering the oxygen-enriched stream to an oxidant delivery system to produce an oxidant stream for the combustion chamber of the combustion system;

achieving a reduced mass flow rate of flue gas exiting the combustion chamber due to enhancement of the oxidant with the oxygen-enriched gas stream; and

modifying a flue gas pollution control system of the combustion system to take advantage of the flue gas mass flow rate reduction.

46. The method of claim 45, wherein the step of modifying the flue gas pollution control system involves replacing at least one device in the flue gas pollution control system of the combustion system with a pollution device of a smaller size which achieves similar or better pollution control.

47. The method of claim 45, wherein the step of modifying the flue gas pollution control system involves adding at least one device in the flue gas pollution control system with a smaller size than the size of the corresponding device needed to treat the flue gas generated by the combustion system when operated with air.

48. The method of claim 45, wherein the step of modifying the flue gas pollution control system involves removing a device dedicated to NO_x abatement when the oxygen-enhanced combustion system achieves very low NO_x levels.