Plasma torch for microwave induced plasmas

• US 20050242070A1
• Filed: 05/21/2003
• Published: 11/03/2005
• Est. Priority Date: 05/21/2002
• Status: Abandoned Application

• Current Assignee: Varian Australia Pty., Ltd. (Agilent Technologies, Inc.)
• Original Assignee: Varian Australia Pty., Ltd. (Agilent Technologies, Inc.)
• Inventors: Hammer, Michael R.
• Application Number:
  US10/515,797
• Publication Number:
  US 20050242070A1
• Time in Patent Office: Days
• US Class Current: 219/121.480
• CPC Class Codes: G01N 21/73 using plasma burners or torches
• CPC Class Codes: G01N 22/00 Investigating or analysing materials by the use of microwaves or radio waves, i.e. electromagnetic waves with a wavelength of one millimetre or more G01N3/00 - G01N17/00, G01N24/00 take precedence
• CPC Class Codes: G01N 33/18 Water
• CPC Class Codes: H05H 1/0031 by interferrometry
• CPC Class Codes: H05H 1/30 using applied electromagnetic fields, e.g. high frequency or microwave energy H05H1/28 takes precedence
• CPC Class Codes: H05H 1/3405 Arrangements for stabilising or constricting the arc, e.g. by an additional gas flow
• CPC Class Codes: H05H 1/42 with provisions for introducing materials into the plasma, e.g. powder, liquid arc stabilising or constricting arrangements H05H1/3405; coaxial protecting fluids H05H1/341; electrostatic spraying, spraying apparatus with means for charging the spray electrically B05B5/00 ; cf. B23K9/324, B05B7/22

Abstract

A Plasma torch (10) for microwave induced plasma spectrochemical analysis of a sample includes a nozzle (30) in an inlet (18) for the main plasma gas flow between outer tube (12) and intermediate tube (14) of the torch (10). The nozzle (30) increases the gas flow velocity in the sheathing gas layer for the plasma which is provided by the gas flow from the annular gap (22) between the tubes (12 and 14). The increased velocity of the gas in the sheathing gas layer “stiffens” that layer and thus better confines the microwave induced plasma (such better confinement not being necessary for an ICP torch). Thus the torch is of improved durability for a microwave induced plasma compared to an ICP torch. The sample injection (inner) tube (16) may have a reduced diameter outlet at its end (34) which is substantially level with the end (35) of intermediate tube (14) to improve injection of a sample into the microwave induced plasma. The inlet end (26) of the sample injection tube (16) may include a heater (36) to assist in preventing blockages in tube (16) near its outlet end.

Claims

1. A torch for plasma spectrochemical analysis including an outer tube, an intermediate tube and an inner tube, the inner tube being substantially coaxially located within the intermediate tube for injecting a first gas flow for carrying a sample for analysis into a plasma produced in the torch,

an intermediate-gas inlet leading into the intermediate tube for admitting a second gas flow into the space between the inner tube and the intermediate tube for controlling the axial position of the plasma produced in the torch,

an outer-gas inlet leading into the outer tube for supplying a third gas flow between the outer tube and the intermediate tube for providing a sheathing gas layer for the plasma produced in the torch,

wherein the outer-gas inlet is offset from a central axis of the torch to impart a spiral flow to the supplied third gas as it moves along the torch to provide the sheathing gas layer,

and means associated with the outer-gas inlet for increasing the gas velocity in the sheathing gas compared to the gas velocity upstream of said means to thereby increase the confining force of the sheathing gas layer on the plasma.

2. A torch as claimed in claim 1, wherein the means associated with the outer-gas inlet is a restriction within the inlet.

5. A torch as claimed in claim 1, wherein the means associated with the outer-gas inlet is such as to, in use, cause a relatively high increase in the gas velocity.

6. A torch as claimed in claim 1, wherein the intermediate and inner tubes terminate at respective ends within the outer tube, and wherein the ends of the intermediate and inner tubes are substantially level, for example within about 2 mm.

7. A torch as claimed in claim 6, wherein the inner tube has an outlet that is of reduced diameter compared to an inlet end of the inner tube.

8. A torch as claimed in claim 1, wherein the inner tube includes an inlet section, and a heating means is associated with said inlet section for heating an aerosol passing through that section to substantially completely evaporate liquid from the aerosol, the section of the inner tube being spaced from the outlet for the liquid to be substantially completely evaporated before the aerosol reaches the proximity of the outlet.

9. A torch as claimed in claim 8, wherein the heating means is an electrical resistance heater.

10. A torch as claimed in claim 9, wherein the electrical resistance heater is provided by an electrical coil around the inlet section.

14. A microwave induced plasma spectrochemical analysis system including a torch as claimed in claim 1,

a gas supply for supplying a plasma support gas to the outer-gas inlet of the torch,

wherein the gas supply supplies the plasma support gas at a substantially constant pressure,

whereby the flow rate of the plasma support gas into the torch is regulated by the means associated with the outer-gas inlet for increasing the gas velocity in the sheathing gas layer.

3.

4. A torch as claimed in claim 3, wherein the nozzle is formed in situ from a cured potting material within the outer-gas inlet.

11. A torch for plasma spectrochemical analysis including

an outer tube, an intermediate tube and an inner tube, the inner tube being substantially coaxially located within the intermediate tube for carrying a first gas flow for conveying an aerosol of a nebulised sample liquid for injection through an outlet thereof into a plasma formed in the torch,

an intermediate-gas inlet leading into the intermediate tube for admitting a second gas flow into the space between the inner tube and the intermediate tube for controlling the axial position of a plasma produced in the torch,

an outer-gas inlet leading,into the outer tube for supplying a third gas flow between the outer tube and the intermediate tube for providing a sheathing gas layer for a plasma produced in the torch,

wherein the outer-gas inlet is offset from a central axis of the torch to impart a spiral flow to the supplied third gas as it moves along the torch to provide the sheathing gas layer,

and a heating means associated with a section of the inner tube for heating an aerosol passing through that section to substantially completely evaporate liquid from the aerosol, the section of the inner tube being spaced from the outlet of the. inner tube for the liquid to be substantially completely evaporated before the aerosol reaches the proximity of the outlet.

12. A torch as claimed in claim 11, wherein the heating means is an electrical resistance heater.

13. A torch as claimed in claim 12, wherein the electrical resistance heater is provided by an electrical coil round the inlet section.