Scanning a band of frequencies using an array of high temperature superconductor sensors tuned to different frequencies

• US 20050258831A1
• Filed: 04/29/2005
• Published: 11/24/2005
• Est. Priority Date: 04/30/2004
• Status: Active Grant

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Alvarez, Robby L., McCambridge, James D.
• Granted Patent: US 7,279,897 B2
• Time in Patent Office: Days
• US Class Current: 324/310
• CPC Class Codes: G01N 24/084 Detection of potentially hazardous samples, e.g. toxic samples, explosives, drugs, firearms, weapons
• CPC Class Codes: G01R 33/34023 Superconducting RF coils
• CPC Class Codes: G01R 33/441 Nuclear Quadrupole Resonance [NQR] Spectroscopy and Imaging

Abstract

The methods of the invention for scanning a band of frequencies using a nuclear quadrupole resonance detection system with an array of high temperature superconductor sensors to detect nuclear quadrupole resonance signals improve the nuclear quadrupole resonance detection system performance.

Claims

1. A method for scanning a band of frequencies Δ

F with a nuclear quadrupole resonance detection system comprising an array of n high temperature superconductor sensors to detect nuclear quadrupole resonance signals, wherein n≧

2 and the bandwidth of each sensor is Δ

f, comprising;

a) determining r different frequencies that span the band of frequencies Δ

F when using sensors with bandwidths Δ

f, wherein r is of the order of Δ

F/Δ

f;

b) tuning the resonance frequencies of the n sensors to n different frequencies, wherein the n different frequencies are selected from the group of the r different frequencies, and maintaining the resonance frequencies of the n sensors for a selected period of time;

c) retuning the resonance frequencies of some or all of the n sensors to any of the r different frequencies that were not used in any previous step, wherein the n sensors have n different resonance frequencies, and maintaining the resonance frequencies of the n sensors for a selected period of time; and

d) repeating step (c) until all the r different frequencies have been used as resonance frequencies.

2. The method of claim 1, further comprising repeating steps (b), (c) and (d) one or more times.

3. The method of claim 1, further comprising combining the signals detected by all sensors that are tuned to a selected frequency.

4. The method of claim 1, wherein the periods of time for which the resonance frequencies are maintained in steps (b), (c) and (d) are the same.

5. The method of claim 1, wherein in step (c) the resonance frequencies of all of the n sensors are retuned to any of the r different frequencies that were not used in any previous step.

6. The method of claim 1, wherein the n high temperature superconductor sensors solely detect nuclear quadrupole resonance signals.

7. The method of claim 6, wherein each high temperature superconductor sensor is comprised of a high temperature superconductor self-resonant planar coil.

8. A nuclear quadrupole resonance detection system for scanning a sample, comprising:

a) n high temperature superconductor sensors, each with bandwidth Δ

f, to scan a band of frequencies Δ

F and detect any nuclear quadrupole resonance signal within the band of frequencies Δ

F, wherein n≧

2;

b) means to tune the resonance frequencies of the n sensors to n different frequencies, wherein the n different frequencies are selected from the group of r different frequencies that span the band of frequencies Δ

F using sensors with bandwidths Δ

f, and wherein r is of the order of Δ

F/Δ

f; and

c) means to simultaneously retune the resonance frequencies of the n sensors to n different frequencies that are not any of the r different frequencies used previously as resonance frequencies, and to continue to retune the n sensors in the same manner until all the r different frequencies have been used as resonance frequencies.

9. The nuclear quadrupole resonance detection system of claim 8, further comprising:

d) means to combine the signals detected by all sensors that are tuned to a selected frequency.

10. The nuclear quadrupole resonance detection system of claim 8, wherein the n high temperature superconductor sensors solely detect nuclear quadrupole resonance signals, and wherein each high temperature superconductor sensor is comprised of a high temperature superconductor self-resonant planar coil.

11. The nuclear quadrupole resonance detection system of claim 10, further comprising one or more shielded-loop resonator coils to apply to the sample to be scanned for nuclear quadrupole resonance an RF signal capable of exciting quadrupolar nuclei in the sample.

12. The nuclear quadrupole resonance detection system of claim 10, wherein the means to tune and simultaneously retune the resonance frequency of each of the n sensors is comprised of (a) n circuits, one for each of the n sensors, wherein each circuit is comprised of a single loop or coil to inductively couple the circuit to the high temperature superconductor self-resonant sensor, (b) a variable reactance in series with the single loop or coil, and (c) means to connect the variable reactance to, and disconnect the variable reactance from, the single loop or coil.

13. The nuclear quadrupole resonance detection system of claim 10, wherein the means to tune and simultaneously retune the resonance frequency of each of the n sensors is comprised of one or more circuits that is comprised of a variable reactance.

14. The nuclear quadrupole resonance detection system of claim 8, wherein the sample comprises explosives, drugs or other contraband.

15. A nuclear quadrupole resonance detection system for scanning a sample, comprising:

a) n high temperature superconductor sensors, each with bandwidth Δ

f, to scan a band of frequencies Δ

F and detect any nuclear quadrupole resonance signal within the band of frequencies Δ

F, wherein n≧

2; and

b) means to tune the resonance frequencies of each of the n sensors to r different frequencies, wherein the r different frequencies span the band of frequencies Δ

F using sensors with bandwidths Δ

f and wherein r is of the order of Δ

F/Δ

f.

16. The nuclear quadrupole resonance detection system of claim 15, wherein the n high temperature superconductor sensors solely detect nuclear quadrupole resonance signals, and wherein each high temperature superconductor sensor is comprised of a high temperature superconductor self-resonant planar coil.

17. The nuclear quadrupole resonance detection system of claim 16, further comprising one or more shielded-loop resonator coils to apply to the sample to be scanned for nuclear quadrupole resonance an RF signal capable of exciting quadrupolar nuclei in the sample.

18. The nuclear quadrupole resonance detection system of claim 16, wherein the means to tune and simultaneously retune the resonance frequency of each of the n sensors is comprised of n circuits, one for each of the n sensors, wherein each circuit is comprised of (a) a single loop or coil to inductively couple the circuit to the high temperature superconductor self-resonant sensor, (b) a variable reactance in series with the single loop or coil, and (c) means to connect the variable reactance to, and disconnect the variable reactance from, the single loop or coil.

19. The nuclear quadrupole resonance detection system of claim 16, wherein the means to tune and simultaneously retune the resonance frequency of each of the n sensors is comprised of one or more circuits that is comprised of a variable reactance.

20. The nuclear quadrupole resonance detection system of claim 15, wherein the sample comprises explosives, drugs or other contraband.

21. A safety system, a security system, or a law enforcement screening system comprising the nuclear quadrupole resonance detection system of claim 15.