Methods and apparatus for scanning a band of frequencies using an array of high temperature superconductor sensors

• US 20050264289A1
• Filed: 04/29/2005
• Published: 12/01/2005
• Est. Priority Date: 04/30/2004
• Status: Active Grant

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Alvarez, Robby L., McCambridge, James D.
• Granted Patent: US 7,279,896 B2
• Time in Patent Office: Days
• US Class Current: 324/310
• CPC Class Codes: G01R 33/441 Nuclear Quadrupole Resonance [NQR] Spectroscopy and Imaging
• CPC Class Codes: G01V 3/14 operating with electron or nuclear magnetic resonance

Abstract

The methods of the invention for scanning a band of frequencies using a nuclear quadrupole resonance detection system with an array of high temperature superconductor sensors to detect nuclear quadrupole resonance signals improve the nuclear quadrupole resonance detection system performance.

Claims

1. A method for scanning a band of frequencies Δ

F with a nuclear quadrupole resonance detection system comprising an array of n high temperature superconductor sensors to detect nuclear quadrupole resonance signals, wherein n≧

2 and the bandwidth of each sensor is Δ

f, comprising;

a) determining r different frequencies that span the band of frequencies Δ

F when using sensors with bandwidths Δ

f, wherein r is of the order of Δ

F/Δ

f;

b) tuning the resonance frequencies of the n sensors to n different resonance frequencies, wherein the n different resonance frequencies are selected from the group of the r different frequencies, and maintaining these resonance frequencies for a selected period of time;

c) retuning simultaneously the resonance frequencies of the n sensors to n different frequencies selected from the group of the r different frequencies, and maintaining these retuned resonance frequencies for a selected period of time, wherein each of the n sensors has a retuned resonance frequency that is different from the resonance frequency to which it was tuned or retuned in any previous step; and

d) repeating step (c) r−

2 times wherein the resonance frequency of each sensor is tuned for one period of time to each of the r different frequencies, and no two sensors are tuned to the same resonance frequency at the same time.

2. The method of claim 1, further comprising repeating steps (b), (c) and (d) one or more times.

3. The method of claim 1, further comprising combining the signals detected by all sensors that are tuned to a selected frequency.

4. The method of claim 1, wherein the periods of time for which the resonance frequencies are maintained in steps (b), (c) and (d) are the same.

5. The method of claim 1, wherein the n high temperature superconductor sensors solely detect nuclear quadrupole resonance signals, and wherein each high temperature superconductor sensor is comprised of a high temperature superconductor self-resonant planar coil.

6. A method for scanning a band of frequencies Δ

F with a nuclear quadrupole resonance detection system comprising an array of n high temperature superconductor sensors to detect nuclear quadrupole resonance signals, wherein n≧

4 and the bandwidth of each sensor is Δ

f, comprising;

a) dividing the sensors into m groups with p sensors in each group, determining r different frequencies that span the band of frequencies Δ

F when using sensors with bandwidths Δ

f, wherein r is of the order of Δ

F/Δ

f, dividing the r different frequencies into s sets with p of the r different frequencies in each set, and assigning each set of frequencies to one of the groups of sensors;

b) tuning the resonance frequencies of the p sensors in each group to the p different frequencies in the set of frequencies assigned to that group, and maintaining these tuned resonance frequencies for a selected period of time;

c) retuning simultaneously the resonance frequencies of the p sensors in each group to p different frequencies within the same set assigned to that group for step (b), and maintaining these retuned resonance frequencies for a selected period of time, wherein each of the p sensors has a retuned resonance frequency that is different from the resonance frequency to which it was tuned or retuned in any previous step;

d) repeating step (c) p−

2 times;

e) retuning the resonance frequencies of the p sensors in each group to the p different frequencies in a second set of frequencies assigned to that group, and maintaining these retuned resonance frequencies for a selected period of time;

f) retuning simultaneously the resonance frequencies of the p sensors in each group to p different frequencies within the same set assigned to that group for step (e), and maintaining these retuned resonance frequencies for a selected period of time, wherein each of the p sensors has a retuned resonance frequency that is different from the resonance frequency to which it was tuned or retuned in any previous step;

g) repeating step (f) p−

2 times; and

h) repeating steps (e), (f) and (g) for each additional set of p different frequencies until all s sets of frequencies have been used as resonance frequencies for one of the m groups of sensors.

7. The method of claim 6, further comprising repeating steps (b) through (h) one or more times.

8. The method of claim 6, further comprising combining the signals detected by all sensors that are tuned to a selected frequency.

9. The method of claim 6, wherein the periods of time for which the resonance frequencies are maintained in steps (b) through (h) are the same.

10. The method of claim 6, wherein the n high temperature superconductor sensors solely detect nuclear quadrupole resonance signals, and wherein each high temperature superconductor sensor is comprised of a high temperature superconductor self-resonant planar coil.

11. A method for scanning a band of frequencies Δ

F with a nuclear quadrupole resonance detection system comprising an array of n high temperature superconductor sensors to detect nuclear quadrupole resonance signals, wherein n≧

4 and the bandwidth of each sensor is Δ

f, comprising;

a) dividing the n sensors into m groups with p sensors in each group, determining r different frequencies that span the band of frequencies Δ

F when using sensors with bandwidths Δ

f, wherein r is of the order of Δ

F/Δ

f, dividing the r different frequencies into m sets with at least p of the r different frequencies in each set, and assigning one set of frequencies to each group of sensors;

b) tuning the resonance frequencies of the p sensors in each group to p different frequencies selected from any of the frequencies assigned to that group, and maintaining these tuned resonance frequencies for a selected period of time;

c) retuning simultaneously the resonance frequencies of the p sensors in each group to p different frequencies selected from any of frequencies assigned to that group, and maintaining these retuned resonance frequencies for a selected period of time, wherein each of the p sensors has a retuned resonance frequency that is different from the resonance frequency to which it was tuned or retuned in any previous step; and

d) repeating step (c) until all of the frequencies in the sets of frequencies assigned to each group have been used as a resonance frequency by each sensor in the group.

12. The method of claim 11, further comprising repeating steps (b), (c) and (d) one or more times.

13. The method of claim 11, further comprising combining the signals detected by all sensors that are tuned to a selected frequency.

14. The method of claim 11, wherein the periods of time for which the resonance frequencies are maintained in steps (b), (c) and (d) are the same.

15. The method of claim 11, wherein the n high temperature superconductor sensors solely detect nuclear quadrupole resonance signals, and wherein each high temperature superconductor sensor is comprised of a high temperature superconductor self-resonant planar coil.

16. A nuclear quadrupole resonance detection system for scanning a sample, comprising a) n high temperature superconductor sensors, each with bandwidth Δ

f, to scan a band of frequencies Δ

F and detect any nuclear quadrupole resonance signal within the band of frequencies Δ

F, wherein n≧

2;

b) means to tune the resonance frequencies of the n sensors to n different frequencies, wherein the n different frequencies are selected from the group of r different frequencies that span the band of frequencies Δ

F using sensors with bandwidths Δ

f, and wherein r is of the order of Δ

F/Δ

f; and

c) means to simultaneously retune r−

1 times the resonance frequencies of the n sensors to n different frequencies each time, wherein after each retuning, each of the n sensors has a retuned resonance frequency that is different from any of the resonance frequencies to which it was previously tuned or retuned.

17. The nuclear quadrupole resonance detection system of claim 16, further comprising:

d) means to combine the signals detected by all sensors that are tuned to a selected frequency.

18. The nuclear quadrupole resonance detection system of claim 16, wherein the n high temperature superconductor sensors solely detect nuclear quadrupole resonance signals, and wherein each high temperature superconductor sensor is comprised of a high temperature superconductor self-resonant planar coil.

19. The nuclear quadrupole resonance detection system of claim 18, further comprising one or more shielded-loop resonator coils to apply to the sample to be scanned for nuclear quadrupole resonance an RF signal capable of exciting quadrupolar nuclei in the sample.

20. The nuclear quadrupole resonance detection system of claim 18, wherein the means to tune and simultaneously retune the resonance frequency of each of the n sensors is comprised of n circuits, one for each of the n sensors, wherein each circuit is comprised of (a) a single loop or coil to inductively couple the circuit to the high temperature superconductor self-resonant sensor, (b) a variable reactance in series with the single loop or coil, and (c) means to connect the variable reactance to, and disconnect the variable reactance from, the single loop or coil.

21. The nuclear quadrupole resonance detection system of claim 18, wherein the means to tune and simultaneously retune the resonance frequency of each of the n sensors is comprised of one or more circuits that is comprised of a variable reactance.

22. The nuclear quadrupole resonance detection system of claim 16, wherein the sample comprises explosives, drugs or other contraband.

23. A safety system, a security system, or a law enforcement screening system comprising the nuclear quadrupole resonance detection system of claim 16.