Apparatus and method for osmotic membrane distillation

• US 20050269266A1
• Filed: 06/01/2005
• Published: 12/08/2005
• Est. Priority Date: 06/04/2004
• Status: Active Grant

• Current Assignee: Chemetics Inc. (Jacobs Solutions, Inc.)
• Original Assignee: Aker Kvaerner Canada Inc. (Jacobs Solutions, Inc.)
• Inventors: Bessarabov, Dmitri, Fetissoff, Peter E., Drackett, Thomas S., Twardowski, Zbigniew
• Granted Patent: US 7,361,276 B2
• Time in Patent Office: Days
• US Class Current: 210/640
• CPC Class Codes: B01D 61/364 Membrane distillation
• CPC Class Codes: C01B 17/88 Concentration of sulfuric acid
• CPC Class Codes: C25B 15/08 Supplying or removing reactants or electrolytes; Regeneration of electrolytes

Abstract

A method of enhancing the concentration of a first inorganic compound in a first aqueous solution of a first process of a heavy chemical plant, the method comprising (a) feeding the first solution having the first compound at a first concentration and a first water vapor pressure to an osmotic membrane distillation means comprising a hydrophobic, gas and water vapor permeable membrane separating (i) a first chamber for receiving the first solution, from (ii) a second chamber for receiving a receiver feed aqueous solution having a second water vapor pressure lower than the first water vapor pressure; (b) feeding the receiver aqueous feed solution to the second chamber as to effect transfer of water vapor through the membrane from the first chamber to the second chamber, and to produce (i) a resultant first solution having a second concentration of the first compound greater than the first concentration and (ii) a diluted receiver feed aqueous solution; and (c) collecting the resultant first solution. The apparatus and method are of particular value in electrolytic haloalkali production plants in offering reduced capital and operating re-concentration and dilution costs.

Claims

1. A method of enhancing the concentration of a first inorganic compound in a first aqueous solution of a first process of a heavy chemical plant, said method comprising

(a) feeding said first solution having said first compound at a first concentration and a first water vapor pressure to an osmotic membrane distillation means comprising a hydrophobic, gas and water vapor permeable membrane separating (i) a first chamber for receiving said first solution, from (ii) a second chamber for receiving a receiver feed aqueous solution having a second water vapor pressure lower than said first water vapor pressure;

(b) feeding said receiver aqueous feed solution to said second chamber as to effect transfer of water vapor through said membrane from said first chamber to said second chamber, and to produce (i) a resultant first solution having a second concentration of said first compound greater than said first concentration and (ii) a diluted receiver feed aqueous solution; and

(c) collecting said resultant first solution.

2. A method as defined in claim 1 wherein said receiver feed aqueous solution is provided by a second process of said heavy chemical plant;

and further collecting said diluted receiver feed aqueous solution.

3. A method as defined in claim 1 wherein said resultant first solution and said diluted receiver feed solution are re-cycled back within said heavy chemical plant.

4. A method as defined in claim 1 wherein said first solution is at a temperature selected from at least 50°

C. and less than its boiling point.

5. A method as defined in claim 4 wherein said receiver feed aqueous solution is at a temperature selected from at least 50°

C. and 80°

C.

6. A method as defined in claim 1 wherein said membrane is microporous.

7. A method as defined in claim 6 wherein said membrane has a pore size of <

0.5 μ

m.

8. A method as defined in claim 1 wherein said hydrophobic membrane is characterized by high free volume and is non-porous.

9. A method as defined in claim 1 wherein said first compound is an alkali metal halide, and said alkali metal halide solution is spent solution from an electrolytic cell for the electrolytic production of halogen and alkali metal hydroxide from said alkali metal halide.

10. A method as defined in claim 9 wherein said alkali metal halide is sodium chloride.

11. A method as defined in claim 1 wherein said receiver feed aqueous solution comprises a solution selected from the group consisting of (i) concentrated brine;

(ii) concentrated sodium hydroxide; and

(iii) spent sulphuric acid from a chlorine drying process.

12. A method as defined in claim 9 wherein said receiver feed aqueous solution is a product solution from an electrolytic cell for the electrolytic production of said alkali metal hydroxide.

13. A method as defined in claim 12 wherein said receiver feed aqueous solution is selected from sodium hydroxide of a catholyte re-circulation loop, and product sodium hydroxide suitable in the preparation of sodium hydroxide bleach.

14. A method as defined in claim 9 wherein said resultant alkali metal halide solution is brine having a second concentration of at least 22% w/w.

15. A method as defined in claim 9 wherein said alkali metal halide solution comprises sodium chloride and chlorine, and further comprising dechlorinating said solution occurring concurrently in said osmotic membrane distillation means.

16. A method as defined in claim 1 wherein said osmotic membrane distillation means comprises a plurality of said osmotic membrane distillation means units linked in parallel and/or series.

17. A method as defined in claim 1 further comprising subjecting said solution in said first chamber and/or second chamber to agitation selected from the group consisting of air-sparging, turbulence-promoters and pulsated flow.

18. A method as defined in claim 1 wherein said osmotic membrane distillation means comprises a unit selected from the group consisting of a plate-and-frame means, shell-and-tube means, and pleated or transverse-flow design membrane contactor means.

19. An improved electrolytic process for the production of alkali metal hydroxide and halogen gas from an alkali metal halide solution, said process comprising electrolyzing said aqueous solution of said alkali metal halide in an electrolytic cell to produce said alkali metal hydroxide, gaseous halogen, and spent alkali metal halide solution, the improvement comprising subjecting at least a portion of said spent alkali metal halide solution having a spent water vapor pressure to an osmotic membrane distillation means comprising a hydrophobic, gas and water vapor permeable membrane separating (i) a spent solution chamber for receiving said spent solution from (ii) a receiver chamber for receiving an aqueous receiver feed solution having a receiver solution water vapor pressure lower than said spent water vapor pressure;

and feeding said at least portion of said spent alkali metal halide solution to said spent solution chamber;

feeding said receiver feed solution to said receiver chamber as to effect transfer of water vapor through said membrane from said spent solution chamber to said receiver chamber, to produce a resultant, more concentrated spent alkali metal halide solution, and a resultant less concentrated receiver feed solution.

20. A process as defined in claim 19 wherein said receiver feed aqueous solution comprises a solution selected from the group consisting of (i) concentrated brine;

(ii) concentrated alkali metal hydroxide; and

(iii) spent sulphuric acid from a chlorine drying process.

21. A process as defined in claim 19 wherein said receiver feed solution contains an alkali metal hydroxide.

22. A process as defined in claim 21 wherein said alkali metal hydroxide is sodium hydroxide.

23. A process as defined in claim 19 wherein said receiver feed solution comprises at least a portion of said alkali metal hydroxide from said electrolytic cell.

24. A process as defined in claim 19 wherein said resultant, more concentrated spent alkali metal halide solution is recycled to said electrolytic cell.

25. Apparatus for enhancing the concentration of a first inorganic compound in a first aqueous solution having a first water vapor pressure provided by a first process of a heavy chemical plant by osmotic membrane distillation, said apparatus comprising

osmotic membrane distillation means comprising

(i) a hydrophobic, gas and water vapor permeable membrane;

(ii) a first chamber for receiving said first solution; and

(iii) a second chamber for receiving a receiver feed aqueous solution having a second water vapor pressure lower than said first water vapor pressure and separated from said first chamber by said membrane means;

means for feeding said first solution to said first chamber and means for feeding said receiver feed aqueous solution to said second chamber as to operably effect transfer of water vapor through said membrane from said first chamber to said second chamber, and to produce

(i) a resultant first solution having a second concentration of said first compound greater than said first concentration, and

(ii) a diluted receiver feed aqueous solution;

means for collecting said resultant first solution; and

means for collecting said diluted receiver feed solution.

26. Apparatus as defined in claim 25 wherein said receiver feed aqueous solution is provided by a second process of said heavy chemical plant.

27. Apparatus as defined in claim 25 further comprising means for recycling said resultant first solution back to said chemical plant.

28. Apparatus as defined in claim 27 further comprising means for recycling said diluted receiver feed solution back to said chemical plant.

29. Apparatus as defined in any one of claims 25 to 28 wherein said membrane is microporous.

30. Apparatus as defined in claim 25 further comprising means for providing isothermal operation at a temperature of at least 50°

C.

31. Apparatus as defined in claim 25 comprising means for feeding to said first chamber spent alkali metal halide solution constituting said first solution obtained from an electrolytic cell for the production of halogen and alkali metal hydroxide from alkali metal halide.

32. Apparatus as defined in claim 25 comprising means for feeding to said second chamber, said receiver feed solution selected from the group consisting of

(i) concentrated brine,

(ii) concentrated sodium hydroxide;

and

(iii) spent sulfuric acid from a chlorine drying process.

33. An improved haloalkali production plant comprising

an electrolytic cell for the electrolytic production of alkali metal hydroxide and halogen from an alkali metal halide solution;

means for feeding feed alkali metal halide solution to said cell;

means for collecting spent alkali metal halide solution having a spent water vapor pressure from said cell;

means for collecting said alkali metal hydroxide from said cell;

the improvement comprising

osmotic membrane distillation means comprising

(i) a hydrophobic, gas and water vapor permeable membrane;

(ii) a first chamber for receiving said spent alkali metal halide solution and wherein the production of re-concentrated alkali metal halide solution is effected; and

(iii) a second chamber for receiving a receiver feed aqueous solution having a receiver water vapor pressure lower than said spent water vapor pressure, separated from said first chamber by said membrane and wherein the production of a diluted receiver feed aqueous solution is effected;

means for feeding said spent alkali metal halide solution to said first chamber;

means for feeding said receiver feed aqueous solution to said second chamber;

means for recycling said re-concentrated alkali metal halide solution in whole or in part, directly or indirectly from said first chamber to said electrolytic cell; and

means for collecting said diluted receiver feed aqueous solution from said second chamber.

34. A plant as defined in claim 33 further comprising means for feeding said alkali metal hydroxide to said second chamber.

35. A plant as defined in claim 33 wherein said alkali metal halide is sodium chloride.

36. A plant as defined in claim 33 wherein said hydrophobic, gas and water vapor permeable membrane is microporous.

37. An improved haloalkali electrolytic production process using an electrolytic cell for producing alkali metal hydroxide and halogen from an alkali metal halide solution, said process comprising electrolysing feed alkali metal halide solution in said cell to produce halogen, alkali metal hydroxide, hydrogen and spent alkali halide solution;

the improvement comprising

(a) feeding in whole or a portion of said spent alkali halide solution having a spent water vapor pressure and a spent alkali halide concentration to an osmotic membrane distillation means comprising a hydrophobic, gas and water vapor permeable membrane separating a first chamber for receiving said spent alkali halide solution from a second chamber for receiving a receiver feed aqueous solution having a receiver water vapor pressure lower than said spent water vapor pressure;

(b) feeding said receiver feed aqueous solution to said second chamber as to effect transfer of water vapor through said membrane from said first chamber to said second chamber, and produce a re-concentrated spent alkali halide solution and a diluted receiver solution; and

(c) recycling said re-concentrated spent alkali halide solution, in whole or in part, directly or indirectly, back to said electrolytic cell.

38. A process as defined in claim 37 comprising feeding in whole or in part said alkali metal hydroxide as constituting said receiver feed aqueous solution to said receiver.