Microgel composition and process for preparation thereof

• US 20050272861A1
• Filed: 05/26/2005
• Published: 12/08/2005
• Est. Priority Date: 11/27/2002
• Status: Abandoned Application

• Current Assignee: University of Melbourne
• Original Assignee: University of Melbourne
• Inventors: Qiao, Greg Guanghua, Solomon, David Henry, Mills, Martin Frederick, Gurr, Paul Andrew
• Application Number:
  US11/138,725
• Publication Number:
  US 20050272861A1
• Time in Patent Office: Days
• US Class Current: 524/591
• CPC Class Codes: C08F 2/06 Organic solvent
• CPC Class Codes: C08F 293/005 using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
• CPC Class Codes: C09D 7/20 Diluents or solvents
• CPC Class Codes: C09D 7/65 macromolecular C09D7/41-C09D7/48 take precedence

Abstract

The invention relates to a microgel composition comprising microgel particles of weight average molecular weight above 50,000 wherein a 60% w/w solution of the microgel in dioxane has a viscosity of less than 10 Pa.s measured by cone and plate viscometry.

Claims

1. A microgel composition comprising microgel particles prepared by a solution free radical polymerization process and having a weight average molecular weight above 50,000 wherein a 60% w/w solution of the microgel in dioxane has a viscosity of less than 10 Pa.s measured by cone and plate viscometry.

2. A microgel composition according to claim 1 wherein the weight average molecular weight is at least 100,000.

3. A microgel composition according to claim 1 wherein the weight average molecular weight is at least 200,000.

4. A microgel composition according to claim 1 wherein the size of the microgel particles is less than 200 nm in diameter measured by standard GPC methods.

5. A coating composition comprising a microgel composition according to claim 1 wherein the microgel forms at least part of a binder component of the coating composition and the microgel is dissolved in a liquid carrier.

6. A coating composition according to claim 5 wherein the liquid carrier is selected from the group consisting of aromatic hydrocarbons;

alcohols;

aliphatic hydrocarbons;

ketones; and

heterocycles.

7. A coating composition according to claim 5 wherein the microgel is present in an amount of from 5 to 90% by weight of the composition.

8. A coating composition according to claim 5 wherein the microgel particles comprise a crosslinked core and arms appended to the core wherein the core is formed from a multiunsaturated monomer and the arms are formed from a monounsaturated monomer.

9. A coating composition according to claim 5 further comprising a second component comprising a crosslinking agent reactive with functional groups present in the binder wherein said reactive functional groups are present in the microgel and/or an additional component of the binder.

10. A coating composition according to claim 9 wherein the crosslinking agent is selected from the group consisting of polyisocyanate, a diepoxy monomer, an amine resin, a siloxane and mixtures of two or more thereof.

11. A coating composition according to claim 9 wherein reactive groups in the binder are selected from the group consisting of hydroxyl, amine, carboxyl, alkoxysilane, epoxy and mixtures thereof.

12. A coating composition according to claim 9 further comprising a binder selected from thermoplastic polymer and thermosetting polymers.

13. A coating composition according to claim 9 comprising a thermosetting polymer binder resin selected from the group consisting of alkyds, polyesters, amino-resins such as melamine formaldehyde resins, acrylic resins, epoxy resins, urethanes and mixtures thereof.

14. A coating composition according to claim 5 further comprising a crosslinking agent adapted to react on curing with functional groups present in at least a portion of the binder component selected from the microgel particles and other optional polymeric binder components.

15. A coating composition according to claim 14 wherein the polymeric binder composition comprises a non-microgel polymeric binder component comprising reactive functional groups for crosslinking with the crosslinking agent.

16. A coating composition according to claim 14 wherein the microgel particles comprise reactive functional groups for crosslinking with said crosslinking agent.

17. A coating composition according to claim 9 wherein the microgel also comprises groups reactive with the crosslinking agent.

18. A coating composition system comprising a first component comprising a coating composition according to claim 5 and a reactive functional group containing polymer and optionally other components such as organic solvents, pigments, fillers, auxiliaries and additives and a second component comprising a crosslinking agent selected from the group consisting of di and/or polyisocyanate;

epoxide compounds having at least two epoxide groups per molecule;

amino resins; and

siloxane crosslinkers.

19. A coating composition according to claim 9 wherein the binder component comprises 50 to 90% by weight of the total composition and the crosslinker components comprises from 10 to 50% by weight of the total composition.

20. A coating composition according to claim 9 comprising an organic carrier in an amount of less than 35% by weight of the total composition.

21. A microgel composition according to claim 1 prepared by polymerising a monomer composition comprising a monounsaturated monomer and a multiunsaturated crosslinking monomer as a solution in an organic solvent by free radical solution polymerisation wherein the reactivity ratio of the monounsaturated monomer is significantly different from the multiunsaturated monomer and the concentration of the monomer component and the proportion of crosslinking monomer in said monomer composition is controlled to provide a solution of discrete microgel particles of weight average molecular weight of at least 50000.

22. A microgel composition according to claim 21 wherein the proportion of multi-unsaturated monomer is less than 15% by weight of the total monomer component.

23. A microgel composition according to claim 21 wherein the total monomer concentration is from 10 to 50% by weight of the total composition.

24. A microgel composition according to claim 21 wherein the total monomer used in preparing the microgel comprises from 25 to 45% by weight of the total composition.

25. A microgel composition according to claim 21 wherein the reactivity ratio (r) of at least one crosslinker to at least one monomer is at least 1.5.

26. A microgel composition according to claim 21 wherein the reactivity ratio of the mono-unsaturated monomer is less than 0.5