Double loop technology

• US 20050272891A1
• Filed: 02/14/2005
• Published: 12/08/2005
• Est. Priority Date: 02/13/2004
• Status: Abandoned Application

• Current Assignee: Total Research & Technology Feluy SA (Totalenergies Se)
• Original Assignee: FINA Research SA
• Inventors: Brande, Frans Van den, Auwera, Marc Van der, Conti, Giacomo, Miserque, Olivier, Fouarge, Louis, Lewalle, Andre, Damme, Eric, Siraux, Daniel, Marechal, Philippe, Oreins, Renaud, Sillis, Marjan, Moers, Marc, Bodart, Philippe, Verleysen, Mark, Vandaele, Hugo, Laurent, Etienne, Camp, Carl Van, Folie, Pascal, D'Hooghe, Leopold, Hortman, Kai
• Application Number:
  US11/057,715
• Publication Number:
  US 20050272891A1
• Time in Patent Office: Days
• US Class Current: 526/64
• CPC Class Codes: B01J 19/1837 Loop-type reactors
• CPC Class Codes: B01J 2208/00548 Flow
• CPC Class Codes: B01J 2208/00752 Feeding
• CPC Class Codes: B01J 8/0035 Periodical feeding or evacuation
• CPC Class Codes: B01J 8/20 with liquid as a fluidising medium
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 2/001 Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer C08F295/00, C08F297/00 take precedence
• CPC Class Codes: C08F 2/01 characterised by special features of the polymerisation apparatus used
• CPC Class Codes: C08F 2/06 Organic solvent
• CPC Class Codes: C08F 2/14 Organic medium
• CPC Class Codes: C08F 210/14 Monomers containing five or more carbon atoms
• CPC Class Codes: C08F 210/16 Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
• CPC Class Codes: C08F 2500/04 Broad molecular weight distribution, i.e. Mw/Mn > 6
• CPC Class Codes: C08F 2500/12 Melt flow index or melt flow ratio
• CPC Class Codes: C08F 2500/18 Bulk density
• CPC Class Codes: C08F 2500/23 Waxy properties
• CPC Class Codes: G05D 11/132 by controlling the flow of the individual components G05D11/133 takes precedence

Abstract

The present invention relates to an apparatus and process for polymerizing olefins. One embodiment comprises polymerizing at least one monomer in a first loop reactor in the presence of a catalyst to produce a first polyolefin fraction. A portion of the first polyolefin fraction is transferred to a second loop reactor, connected in series with the first loop reactor. The process further comprises polymerizing in the second loop reactor at least one monomer in the presence of a catalyst to produce a second polyolefin fraction in addition to the first polyolefin fraction. The combination of the first and second polyolefin fractions can produce a polymer resin fluff having bimodal molecular weight distribution.

Claims

1. An apparatus for controlling the injection of catalyst slurry in a polymerization reactor wherein polyethylene is prepared, comprising

one or more storage vessels for storing catalyst slurry consisting of solid catalyst in a hydrocarbon diluent, whereby each vessel is provided with means for transferring said catalyst slurry from said storage vessels to a mixing vessel,

a mixing vessel, being connected with said storage vessels by means of said transferring means, for diluting said catalyst slurry to a suitable concentration,

one or more conduits, connecting said mixing vessel to a polymerization reactor for transferring said diluted catalyst slurry from said mixing vessel to said reactor, whereby each conduit is provided with a pumping means for pumping said slurry to said reactor, and

the dilution being adapted to the pumping means.

2. The apparatus according to claim 1, wherein the pumping means is a membrane pump.

3. The apparatus according to claim 1 wherein the dilution being adapted to the pumping means comprises a solid catalyst diluted with a hydrocarbon diluent to a concentration comprised between 0.1 and 1.5% by weight.

4. The apparatus according to claim 1 wherein said catalyst is a metallocene catalyst.

5. The apparatus according to claim 4 wherein the metallocene catalyst is a supported metallocene catalyst.

6. The apparatus according to claim 1, wherein said pumping means provided on said conduit is controlled as a function of the concentration of a reactant in said reactor.

7. The apparatus according to claim 1 wherein a first means for transferring said catalyst slurry from a first storage vessel to a mixing vessel is interchangeable with a second means for transferring said catalyst slurry from a second storage vessel to a mixing vessel through lines connecting said first means with said second means.

8. The apparatus according to claim 1 wherein said means for transferring said catalyst slurry from a storage vessel to a mixing vessel, each are provided with a metering valve, provided downstream the connecting lines.

9. The apparatus according to claim 1 further comprising measuring means on said conduit for measuring catalyst flow rate.

10. The apparatus according to claim 1 further comprising a co-catalyst feeding system for bringing a suitable amount of co-catalyst into contact with the catalyst slurry for a suitable period of time before injecting said catalyst slurry to said reactor, said co-catalyst feeding system comprising a co-catalyst storage vessel and a conduit connected thereto for transferring said co-catalyst.

11. The apparatus according to claim 10, wherein said conduit is provided with a contact vessel for enhancing the contact time of said co-catalyst with said catalyst slurry in said conduit.

13. The method according to claim 11 wherein said catalyst is a metallocene catalyst.

14. The method of claim 13 wherein the metallocene catalyst is a supported metallocene catalyst.

12. A method for controlling the injection of catalyst slurry in a polymerization reactor, wherein polyethylene is prepared, said catalyst consisting of solid catalyst in a hydrocarbon diluent, comprising the subsequent steps of:

providing solid catalyst and a hydrocarbon diluent in one or more storage vessels such that a catalyst slurry is obtained in said vessel,

transferring said catalyst slurry from said storage vessel to a mixing vessel wherein said catalyst slurry is diluted for obtaining a suitable concentration for use in a polymerization reaction,

pumping said diluted catalyst slurry at a controlled flow rate from said mixing vessel to said polymerization reactor through one or more conduits, by means of a pumping means, provided in each of said conduits, and

the dilution being adapted to the pumping means.

15. The method according to claim 12 wherein said catalyst slurry is diluted with said hydrocarbon diluent in said mixing vessel to a concentration comprised between 0.1 and 10% by weight.

16. The method according to claim 12 comprising controlling the flow rate of said catalyst slurry from the mixing vessel to the polymerization reactor by determining the concentration of a reactant in said reactor.

17. The method of claim 16 wherein the reactant in said reactor is ethylene

18. The method according to claim 12 comprising transferring said catalyst slurry from said storage vessel to said mixing vessel at a controlled flow by controlling the ratio between diluent and catalyst in the mixing vessel.

19. The method according to claim 12 further comprising bringing a suitable amount of co-catalyst into contact with the catalyst slurry for a suitable period of time before injecting said catalyst slurry to said reactor.

20. The method according to claim 19 comprising bringing a co-catalyst into contact with said catalyst slurry present in the conduit.

21. The method according to claim 20 comprising enhancing the contact time of said co-catalyst with said catalyst slurry in the conduit, by locally enhancing the volume of said conduit.

22. The method according to claims 12 comprising continuously supplying said catalyst slurry from said mixing vessel to said reactor through conduits at a suitable flow rate.

23. A process for the co-polymerization of ethylene monomer and an olefin co-monomer in a polymerization loop reactor comprising the steps of

feeding monomer, an olefin co-monomer, diluents and optionally hydrogen into the loop reactor,

feeding at least one polymerization catalyst into the reactor,

co-polymerizing said monomer and said co-monomer to produce a polymer slurry comprising essentially liquid diluent and solid olefin co-polymer particles,

allowing said polymer slurry to settle into one or more settling legs connected to the reactor, and

sequentially discharging the settled polymer slurry from said one or more settling legs out of the reactor,

characterized in that said process further comprises the step of controlling the co-monomer/monomer ratio along the path of the reactor.