Process for producing olefins
First Claim
1. A process for producing olefins comprising:
- (a) providing a vapor product stream from an oxygenate to olefin reaction, said vapor product stream comprising C2 to C4 olefins, C2 to C6 carbonyl compounds and water;
(b) cooling said vapor product stream to provide a first vapor effluent stream comprising no more than 10 wt. % water, and a liquid water-rich stream;
(c) compressing the first vapor effluent stream and a first wash flash vapor stream from a first suction pressure to a second pressure greater than said first pressure to form a second vapor effluent stream;
(d) cooling the second vapor effluent stream to form a cooled second effluent stream that is at least partially in the vapor state;
(e) washing at least part of the cooled second effluent stream with a liquid alcohol-containing stream, at a third pressure greater than the first suction pressure but not greater than the second pressure, to produce a wash liquid stream comprising C3 and C4 olefins, and a wash vapor stream, said wash vapor stream having a lower content of C2 to C6 carbonyl compounds than the first vapor effluent stream; and
(f) exposing the wash liquid stream to a pressure of at least the first suction pressure but less than the third pressure to form a first wash flash liquid stream and said first wash flash vapor stream, said first wash flash vapor stream being provided for compression (c).
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Accused Products
Abstract
A process for producing olefins comprises providing a vapor product stream from an oxygenate to olefin reaction, the vapor product stream comprising C2 to C4 olefins, C2 to C6 carbonyl compounds and water. The vapor product stream is cooled to provide a first vapor effluent stream comprising no more than 10 wt. % water, and a liquid water-rich stream. The first vapor effluent stream, and a first wash flash vapor stream, are compressed from a first pressure to a second pressure greater than said first pressure to form a second vapor effluent stream, which is then cooled to form a cooled second effluent stream that is at least partially in the vapor state. At least part of the cooled second effluent stream is washed with a liquid alcohol-containing stream, at a third pressure greater than the first pressure but not greater than the second pressure, to produce a wash liquid stream, which comprises C3 and C4 olefins, and a wash vapor stream, which contains less C2 to C6 carbonyl compounds than the first vapor effluent stream. The wash liquid stream is exposed to a pressure of at least the first pressure but less than the third pressure to form a first wash flash liquid stream and the first wash flash vapor stream, the first wash flash vapor stream being provided for compression with the first vapor effluent stream.
11 Citations
97 Claims
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1. A process for producing olefins comprising:
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(a) providing a vapor product stream from an oxygenate to olefin reaction, said vapor product stream comprising C2 to C4 olefins, C2 to C6 carbonyl compounds and water;
(b) cooling said vapor product stream to provide a first vapor effluent stream comprising no more than 10 wt. % water, and a liquid water-rich stream;
(c) compressing the first vapor effluent stream and a first wash flash vapor stream from a first suction pressure to a second pressure greater than said first pressure to form a second vapor effluent stream;
(d) cooling the second vapor effluent stream to form a cooled second effluent stream that is at least partially in the vapor state;
(e) washing at least part of the cooled second effluent stream with a liquid alcohol-containing stream, at a third pressure greater than the first suction pressure but not greater than the second pressure, to produce a wash liquid stream comprising C3 and C4 olefins, and a wash vapor stream, said wash vapor stream having a lower content of C2 to C6 carbonyl compounds than the first vapor effluent stream; and
(f) exposing the wash liquid stream to a pressure of at least the first suction pressure but less than the third pressure to form a first wash flash liquid stream and said first wash flash vapor stream, said first wash flash vapor stream being provided for compression (c). - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42)
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43. A process for producing olefins comprising:
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(a) providing a vapor product stream from an oxygenate to olefin reaction, said product comprising C2 to C4 olefins, C2 to C6 carbonyl compounds and water;
(b) cooling said vapor product stream to provide a first vapor effluent stream at a first pressure and comprising no more than 10 wt. % water, and a liquid water-rich stream;
(c) compressing the first vapor effluent stream from a first suction pressure that is no greater than said first pressure to an intermediate pressure greater than said first pressure to form an intermediate effluent stream;
(d) cooling the intermediate effluent stream to form an intermediate effluent vapor stream and an intermediate effluent liquid stream;
(e) compressing the intermediate effluent vapor stream from an intermediate suction pressure that is no greater than said intermediate pressure to a second pressure greater than said intermediate pressure to form a second effluent stream;
(f) cooling the second effluent stream to form a cooled second effluent stream that is at least partially vapor;
(g) washing at least part of the cooled second effluent stream with a liquid alcohol-containing stream in a vapor-liquid contacting device, at a third pressure greater than the intermediate suction pressure but not greater than the second pressure, to produce a wash liquid stream comprising C3 and C4 olefins, and a wash vapor stream, said wash vapor stream having a lower content of C2 to C6 carbonyl compounds than the first vapor effluent stream; and
(h) exposing at least part of the wash liquid stream to a pressure of at least the first suction pressure and less than the third pressure to form a first wash flash liquid stream and a first wash flash vapor stream, said first wash flash vapor stream being provided for compression (c) along with the first vapor effluent stream, or for compression (e) along with the intermediate effluent vapor stream, or both. - View Dependent Claims (44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79)
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80. A process for producing olefins comprising:
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(a) providing a vapor product stream from an oxygenate to olefin reaction, said product comprising C2 to C4 olefins, C2 to C6 carbonyl compounds and water;
(b) cooling said vapor product stream to provide a first vapor effluent stream at a first pressure and comprising no more than 10 wt. % water, and a liquid water-rich stream;
(c) introducing the first vapor effluent stream and an intermediate effluent liquid stream into a first vessel to form a flash vapor added first effluent stream and a first vessel liquid stream;
(d) compressing the flash vapor added first effluent stream to an intermediate pressure to form an intermediate effluent stream;
(e) cooling the intermediate effluent stream and introducing said cooled intermediate effluent stream into a second vessel together with a second liquid effluent stream and a wash liquid stream to form an intermediate effluent vapor stream and said intermediate effluent liquid stream;
(f) compressing the intermediate effluent vapor stream to a second pressure greater than said intermediate pressure to form a second effluent stream;
(g) cooling the second effluent stream and introducing said cooled second effluent stream into a third vessel to form a cooled second vapor effluent stream and said second liquid effluent stream; and
(h) washing the cooled second vapor effluent stream with an liquid alcohol-containing stream in a vapor-liquid contacting device, at a third pressure of greater than the intermediate pressure but no greater than the second pressure, to produce said wash liquid stream comprising C3 and C4 olefins, and a wash vapor stream, said wash vapor stream having a lower content of C2 to C6 carbonyl compounds than the first effluent stream. - View Dependent Claims (81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97)
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Specification