Growth of planar, non-polar a-plane gallium nitride by hydride vapor phase epitaxy

• US 20060008941A1
• Filed: 07/15/2003
• Published: 01/12/2006
• Est. Priority Date: 12/16/2002
• Status: Active Grant

• Current Assignee: Japan Science And Technology Agency
• Original Assignee: BASF AG (BASF SE)
• Inventors: Speck, James S., DenBaars, Steven P., Haskell, Benjamin A., Nakamura, Shuji, Craven, Michael D., Fini, Paul T., Matsuda, Shigemasa
• Granted Patent: US 7,427,555 B2
• Time in Patent Office: Days
• US Class Current: 438/93
• CPC Class Codes: C30B 25/02 Epitaxial-layer growth
• CPC Class Codes: C30B 29/40 AIIIBV compounds wherein A is B, Al, Ga, In or Tl and B is N, P, As, Sb or Bi
• CPC Class Codes: C30B 29/406 Gallium nitride
• CPC Class Codes: H01L 21/02389 Nitrides
• CPC Class Codes: H01L 21/0242 Crystalline insulating materials
• CPC Class Codes: H01L 21/02433 Crystal orientation
• CPC Class Codes: H01L 21/0254 Nitrides
• CPC Class Codes: H01L 21/02587 Structure
• CPC Class Codes: H01L 21/02609 Crystal orientation
• CPC Class Codes: H01L 21/0262 Reduction or decomposition of gaseous compounds, e.g. CVD

Abstract

Highly planar non-polar a-plane GaN films are grown by hydride vapor phase epitaxy (HVPE). The resulting films are suitable for subsequent device regrowth by a variety of growth techniques

Claims

1. A method for forming a planar, non-polar, a-plane gallium nitride (GaN) film on a substrate, comprising:

(a) loading a substrate into a reactor,

(b) heating the reactor to a growth temperature;

(c) reducing the reactor'"'"'s pressure to a desired deposition pressure, wherein the desired deposition pressure is below atmospheric pressure;

(d) initiating a gaseous hydrogen chloride (HCl) flow to a gallium (Ga) source to begin growth of the a-plane GaN film directly on the substrate, wherein the gaseous HCl reacts with the Ga to form gallium monochloride (GaCl);

(e) transporting the GaCl to the substrate using a carrier gas that includes at least a fraction of hydrogen (H₂), wherein the GaCl reacts with ammonia (NH₃) at the substrate to form the GaN film; and

(f) after a desired growth time has elapsed, interrupting the gaseous HCl flow, returning the reactor'"'"'s pressure to atmospheric pressure, and reducing the reactor'"'"'s temperature to room temperature.

3. The method of claim 1, wherein the substrate is coated with a thin film of GaN, aluminum nitride (AlN), or aluminum gallium nitride (AlGaN).

5. The method of claim 1, wherein the substrate is a free-standing GaN, aluminum nitride (AlN), or aluminum gallium nitride (AlGaN) film.

6. The method of claim 1, further comprising evacuating the reactor and backfilling the reactor with purified nitrogen (N₂) gas to reduce oxygen and water vapor levels therein before heating the reactor.

7. The method of claim 1, further comprising nitridating the substrate, at a temperature in excess of 900°

C.;

8. The method of claim 7, wherein the nitridating step comprises adding anhydrous ammonia (NH₃) to a gas stream in the reactor to nitridate the substrate.

9. The method of claim 1, wherein the heating step (b) comprises heating the reactor to the growth temperature of approximately 1040°

C., with a mixture of hydrogen (H₂) and nitrogen (N₂) flowing through all channels in the reactor.

10. The method of claim 1, wherein the gaseous KCl reacts with the Ga at a temperature in excess of 600°

C. to form the GaCl.

11. The method of claim 1, wherein the desired deposition pressure ranges from 5 to 100 Torr.

12. The method of claim 1, wherein the desired deposition pressure is approximately 76 Torr.

13. The method of claim 1, wherein typical growth rates for the GaN film range from 1 to 50, per hour.

14. The method of claim 1, wherein the interrupting step (f) further comprises including anhydrous ammonia (NH₃) in a gas stream to prevent decomposition of the GaN film during the reduction of the reactor'"'"'s temperature.

15. The method of claim 1, wherein the interrupting step (f) further comprises cooling the substrate at a reduced pressure between 5 and 760 Torr.

16. A device manufactured using the method of claim 1.

17. The device of claim 16, wherein the device is a laser diode, light-emitting diode or transistor.

19. The method of claim 1, wherein the substrate is comprised of a patterned surface encouraging growth of the a-plane GaN film on selected areas of the surface.

2. The method of clam 1, wherein the substrate is a sapphire substrate,

4. The method of claim 2, wherein the substrate is coated with a nucleation layer deposited either at low temperatures or at the growth temperature.

18. (canceled)