Addition reaction curable silicone rubber composition

• US 20060009577A1
• Filed: 07/08/2005
• Published: 01/12/2006
• Est. Priority Date: 07/09/2004
• Status: Abandoned Application

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Hara, Hiroyasu
• Application Number:
  US11/176,319
• Publication Number:
  US 20060009577A1
• Time in Patent Office: Days
• US Class Current: 524/862
• CPC Class Codes: B32B 25/20 comprising silicone rubber
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08K 5/05 Alcohols; Metal alcoholates
• CPC Class Codes: C08K 5/34922 Melamine; Derivatives thereof
• CPC Class Codes: C08L 2666/28 Non-macromolecular organic substances
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: C09J 183/04 Polysiloxanes
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

Provided is a self-adhesive addition reaction curable silicone rubber composition including (A) 100 parts by mass of an organopolysiloxane containing at least two alkenyl groups bonded to silicon atoms, (B) an organohydrogenpolysiloxane, in sufficient quantity to provide from 0.4 to 10.0 mols of hydrogen atoms bonded to silicon atoms within this component (B) for every 1 mol of alkenyl groups within the entire composition, (C) an effective quantity of a platinum-based catalyst, (D) a curing retarder, and (E) an adhesion imparting agent, in which the blend quantity of the curing retarder of the component (D) is sufficient to ensure that, if a torque value of the composition after standing for 180 minutes at 80° C. following preparation is deemed 100%, the time required for the torque value to reach 90% is no more than 120 minutes. Also provided is a method of bonding a plastic substrate and a silicone rubber, in which the above-stated addition reaction curable silicone rubber composition is cured on the plastic substrate at a temperature of no more than 120° C. The addition reaction curable silicone rubber composition is able to be cured even in the presence of curing inhibiting substances, and is very useful as a silicone adhesive.

Claims

1. An addition reaction curable silicone rubber composition comprising:

(A) 100 parts by mass of an organopolysiloxane containing at least two alkenyl groups bonded to silicon atoms, represented by an average composition formula (1) shown below;

R¹_aR²_bSiO_(4-a-b)/2  

 

(1)

(wherein, each R¹ group represents an identical or different unsubstituted or substituted monovalent hydrocarbon group that contains no aliphatic unsaturated bonds, R² represents an alkenyl group, a represents a number from 0.96 to 2.00, b represents a number from 0.0001 to 0.5, and a+b represents a number within a range from 1.90 to 2.04),

(B) an organohydrogenpolysiloxane represented by an average composition formula (2) shown below;

R³_cH_dSiO_(4-c-d)/2  

 

(2)

(wherein, each R³ group represents an identical or different unsubstituted or substituted monovalent hydrocarbon group that contains no aliphatic unsaturated bonds, c represents a number from 0.70 to 2.00, d represents a number from 0.01 to 1.2, and c+d represents a number within a range from 1 to

     3), in sufficient quantity to provide from 0.4 to 10.0 mols of hydrogen atoms bonded to silicon atoms within said component (B) for every 1 mol of alkenyl groups within said composition,

(C) an effective quantity of a platinum-based catalyst,

(D) a curing retarder, and

(E) an adhesion imparting agent, wherein

a blend quantity of said curing retarder of said component (D) is sufficient to ensure that, if a torque value of said composition after standing for 180 minutes at 80°

C. following preparation is deemed 100%, a time required for said torque value to reach 90% is no more than 120 minutes.

2. The addition reaction curable silicone rubber composition according to claim 1, wherein said composition is a one-part type composition.

3. The addition reaction curable silicone rubber composition according to claim 1, wherein an introducing time period for curing at 40°

C. is at least 168 hours.

4. The addition reaction curable silicone rubber composition according to claim 1, wherein said component (D) is an acetylene alcohol-based compound or a triallyl isocyanurate-based compound.

5. The addition reaction curable silicone rubber composition according to claim 4, wherein said component (D) is an acetylene alcohol-based compound, and the acetylene alcohol-based compound is an acetylene alcohol, a silane-modified product thereof, or a siloxane-modified product thereof.

6. The addition reaction curable silicone rubber composition according to claim 4, wherein said component (D) is a triallyl isocyanurate-based compound, and the triallyl isocyanurate-based compound is triallyl isocyanurate, an alkoxysilyl-substituted triallyl isocyanurate, in which from 1 to 3 alkoxysilyl groups have been added to the allyl groups, and a siloxane-modified product thereof in which the alkoxysilyl groups have undergone a hydrolysis-condensation with one another.

7. The addition reaction curable silicone rubber composition according to claim 1, wherein said adhesion imparting agent of said component (E) combines an organosilicon compound and a non-silicon-based organic compound.

8. An adhesive comprising the addition reaction curable silicone rubber composition according to claim 1.

9. The adhesive according to claim 6, wherein said adhesive is used for bonding plastic.

10. The adhesive according to claim 7, wherein said plastic is polybutylene terephthalate, polyphenylene sulfide, nylon 6, nylon 66, or polyphthalamide.

11. A method of producing a laminate comprising a layer of a substrate and a layer, adhered to said layer of said substrate, of a cured product of the addition reaction curable silicone rubber composition according to claim 1, said method comprising the steps of:

applying said composition to said substrate and

curing said composition on said substrate at a temperature of no more than 120°

C.

12. A method of bonding two substrates, comprising the steps of:

sandwiching the addition reaction curable silicone rubber composition according to claim 1 between said two substrates and

curing said composition at a temperature of no more than 120°

C.