Water-based drilling fluids

• US 20060019834A1
• Filed: 07/22/2004
• Published: 01/26/2006
• Est. Priority Date: 07/22/2004
• Status: Active Grant

• Current Assignee: Hercules, LLC (Ashland Global Holdings, Inc.)
• Original Assignee: Hercules Incorporated (Ashland Global Holdings, Inc.)
• Inventors: Sau, Arjun C., Melbouci, Mohand
• Granted Patent: US 7,384,892 B2
• Time in Patent Office: Days
• US Class Current: 507/100
• CPC Class Codes: C09K 8/04 Aqueous well-drilling compositions

Abstract

A water-based drilling fluid composition includes water and at least one rheology modifier and/or fluid loss control agent, and at least one other ingredient of polymeric additive, inorganic salts, dispersants, shale stabilizers, weighting agents, or finely divided clay particles, depending upon the desired attributes, wherein the rheology modifier and/or the fluid loss control agent comprises carboxymethylated raw cotton linters (CM-RCL) made from the baled raw cotton linters or comminuted raw cotton linters with increased bulk density.

Claims

1. A water-based drilling fluid composition comprising water and at least one rheology modifier and/or fluid loss control agent, and at least one other ingredient selected from the group consisting of polymeric additive, inorganic salts, dispersants, shale stabilizers or inhibitors, weighting agents, and finely divided clay particles, depending upon the desired attributes, wherein the rheology modifier and/or the fluid loss control agent comprises carboxymethylated raw cotton linters (CM-RCL) and/or salts thereof, wherein the polymeric additive and/or dispersants exclude polycarboxylic acid having a number average molecular weight not exceeding 3,000 selected from the group consisting of a homopolymer of acrylic acid, a homopolymer of methacrylic acid, a copolymer of acrylic acid and methacrylic acid, and a water-soluble salt of any of the foregoing acids.

2. The water-based drilling fluid composition of claim 1, wherein the water-based drilling fluid composition provides a 30-minute API filtrate volume of less than 17 ml based on both Chevron test procedure in KCl/seawater based mud at a concentration of 0.75 lb/bbl and PAC Superiority test procedure at a concentration of 1.0 lb/bbl.

3. The water-based drilling fluid composition of claim 1, wherein the water-based drilling fluid composition provides a 30-minute API filtrate volume of less than 15 ml based on both Chevron test procedure in KCl/seawater based mud at a concentration of 0.75 lb/bbl and PAC Superiority test procedure at a concentration of 1.0 lb/bbl.

4. The water-based drilling fluid composition of claim 1, wherein the water-based drilling fluid composition provides a 30-minute API filtrate volume of less than 13 ml based on both Chevron test procedure in KCl/seawater based mud at a concentration of 0.75 lb/bbl and PAC Superiority test procedure at a concentration of 1.0 lb/bbl.

5. The water-based drilling fluid composition of claim 1, wherein the CM-RCL has a carboxymethyl degree of substitution (CM DS) lower limit of about 0.4.

6. The water-based drilling fluid composition of claim 1, wherein the CM-RCL has a carboxymethyl degree of substitution (CM DS) lower limit of about 0.8.

7. The water-based drilling fluid composition of claim 1, wherein the CM-RCL has a carboxymethyl degree of substitution (CM DS) lower limit of about 1.0

8. The water-based drilling fluid composition of claim 1, wherein the CM-RCL has a carboxymethyl degree of substitution (CM DS) upper limit of about 2.2.

9. The water-based drilling fluid composition of claim 1, wherein the CM-RCL has a carboxymethyl degree of substitution (CM DS) upper limit of about 1.5.

10. The water-based drilling fluid composition of claim 1, wherein the CM-RCL has a carboxymethyl degree of substitution (CM DS) upper limit of about 1.2

11. The water-based drilling fluid composition of claim 1, wherein other polymeric additives are present and selected from the group consisting of starch and its derivatives, guar gum and its derivatives, xanthan gum, wellan gum, other biopolymers, cellulose ethers, polyacrylates of molecular weight greater than 3000, polyacrylamides, lignite, lignosulfonate, and mixtures thereof.

12. The water-based drilling fluid composition of claim 1, wherein inorganic salts are present and selected from the group consisting of calcium carbonate, calcium chloride, potassium chloride, sodium chloride, magnesium chloride, and mixtures thereof.

13. The water-based drilling fluid composition of claim 1, wherein dispersants are present and selected from the group consisting of causticized lignite, causticized potassium lignite, chrome lignite, chrome lignosulfonate, ferrochrome lignosulfonate, chrome-free lignosulfonate, tannin and modified chrome tannin, polyacrylates of molecular weight greater than 3000, sodium tetraphosphate, sodium pyrophosphate, sulfonated synthetic polymers, and mixtures thereof.

14. The water-based drilling fluid composition of claim 1, wherein shale stabilizers or inhibitors are present and selected from the group consisting of partially hydrolyzed polyacrylamides (PHPA), potassium chloride, potassium acetate, potassium carbonate, potassium hydroxide, sulfonated asphalt, blown asphalt, gilsonite, polyglycols, poly amino acids, surfactants, cationic polymers, mixed metal hydroxides (MMH), and mixtures thereof.

15. The water-based drilling fluid composition of claim 1, wherein weighting agents are present and selected from the group consisting of barite, hematite, manganese oxide, sized calcium carbonate made from ground limestone or marble, and mixtures thereof.

16. The water-based drilling fluid composition of claim 1, wherein finely divided clay particles are present and selected from the group consisting of bentonite, attapulgite, sepiolite, saponite, and mixtures thereof.

17. The water-based drilling fluid composition of claim 1, wherein a lubricant is present and selected from the group consisting of glycol, asphalt, and mixtures thereof.

18. The water-based drilling fluid composition of claim 1, wherein a corrosion inhibitor is present and selected from the group consisting of amine, inorganic thiocyanate, and mixtures thereof.

19. The water-based drilling fluid composition of claim 18, wherein the inorganic thiocyanate is selected from the group consisting of potassium thiocyanate, sodium thiocyanate, and ammonium thiocyanate.

20. The water-based drilling fluid composition of claim 1, wherein a secondary fluid loss control agent is also present.

21. The water-based drilling fluid composition of claim 20, wherein the secondary fluid loss control agent is selected from the group consisting of liquid resins, resinated lignite, starch and its derivatives, cellulose ethers, guar and its derivatives, polyacrylates, polyacrylamides, 2-acrylamido-2-methylpropanesulfonic acid (AMPS) based copolymers, and polyglycols.

22. The water-based drilling fluid composition of claim 1, wherein the drilling fluid further comprises biopolymers as a primary rheology modifier.

23. The water-based drilling fluid composition of claim 22, wherein the biopolymers are selected from the group consisting of xanthan gum, wellan gum, and guar gum.

24. The water-based drilling fluid composition of claim 1, wherein the drilling fluid further comprises an oxygen scavenger.

25. The water-based drilling fluid composition of claim 1, wherein the drilling fluid further comprises a pH control agent selected from the group consisting of sodium hydroxide (NaOH), magnesium oxide (MgO), sodium bicarbonate (NaHCO₃), calcium oxide (CaO), potassium hydroxide (KOH), and mixtures thereof.

26. The water-based drilling fluid composition of claim 1, wherein the CM-RCL contains a member selected from the group consisting of potassium, lithium, sodium, calcium, aluminum, barium, magnesium, ammonium ions, and mixtures thereof as counter-cations.

27. The water-based drilling fluid composition of claim 26, wherein the CM-RCL containing potassium ions as countercations is produced by alkalizing raw cotton linters with potassium hydroxide and reacting the alkalized raw cotton linters with potassium chloroacetate.

28. The water-based drilling fluid composition of claim 1, wherein the CM-RCL contains salts of barium (II), calcium (II), strontium (II), magnesium (II), chromium (II), titanium (IV), aluminum (III), iron (II), iron (III), zinc (II), nickel (II), tin (II), or tin (IV) and nitrilo-triacetic acid, 1,2-cylohexane-diamine-N,N,N′

,N′

-tetra-acetic acid, diethylenetriamine-pentaacetic acid, ethylenedioxy-bis(ethylene-nitrilo)-tetraacetic acid, N-(2-hydroxyethyl)-ethylenediamino-N, N′

,N′

-triacetic acid, triethylene-tetraamine-hexaacetic acid or N-(hydroxyethyl) ethylenediamine-triacetic acid or a mixture thereof as a ligand.

29. The water-based drilling fluid composition of claim 28, wherein the amount of salts based on dry weight of CM-RCL is 0.1-25 wt %.

30. The water-based drilling fluid composition of claim 1, wherein the CM-RCL contains hydroxyalkyl groups.

31. The water-based drilling fluid composition of claim 30, wherein the hydroxyalkyl groups are selected from the members consisting of hydroxyethyl groups, hydroxypropyl groups, and hydroxybutyl groups.

32. The water-based drilling fluid composition of claim 1, wherein the CM-RCL contains C₁-C₃₀ alkyl groups.

33. The water-based drilling fluid composition of claim 1, wherein the CM-RCL contains sulfoethyl groups.

34. The water-based drilling fluid composition of claim 1, wherein the CM-RCL is modified with a cationic group comprising quaternary ammonium group.

35. The water-based drilling fluid composition of claim 34, wherein the quaternary ammonium group that is incorporated into the CM-RCL using cationic reagents is selected from the group consisting of 3-chloro-2-hydroxypropylmethyl ammonium chloride, 3-chloro-2-hydroxypropyl trimethyl ammonium chloride, 3-chloro-2-hydroxypropyl dimethyl benzyl ammonium chloride, 2,3-epoxypropyl dimethyl benzyl ammonium chloride, 3-chloro-2-hydroxypropyl dimethyldodecyl ammonium chloride, 3-chloro-2-hydroxypropyl dimethyloctadecyl ammonium chloride, 3-chloro-2-hydroxypropyl dimethyltetradecyl ammonium chloride, 3-chloro-2-hydroxypropyl dimethyloctadecyl ammonium chloride, 3-chloro-2-hydroxypropyl dimethylhexadecyl ammonium chloride, 3-chloro-2-hydroxypropyl dimethyloctyl ammonium chloride, 3-chloro-2-hydroxypropyl trimethyldodecyl ammonium chloride, 2-chloroethyl trimethyl ammonium chloride and 2,3-epoxypropyl trimethyl ammonium chloride.

36. The water-based drilling fluid composition of claim 34 wherein the cationic degree of substitution of the cationically modified CM-RCL is from about 0.0005 to about 0.9.

37. The water-based drilling fluid composition of claim 1, further comprises at least one amphoteric polymer, selected from the class consisting of partially hydrolyzed polyacrylamide containing quaternary ammonium groups, partially hydrolyzed poly(acrylamide-co-acrylates) containing quaternary ammonium groups, carboxymethylated cellulose derivatives containing quaternary ammonium groups, carboxymethylated starch derivatives containing quaternary ammonium groups, carboxymethylated guar derivatives containing quaternary ammonium groups and mixtures thereof.

38. The water-based drilling fluid composition of claim 1, wherein the CM-RCL contains dimethylaminoethyl methacrylate groups.

39. The water-based drilling fluid composition of claim 1, wherein the CM-RCL contains both sulfoethyl and cationic groups.

40. The water-based drilling fluid composition of claim 1, wherein the molecular weight of the CM-RCL is reduced.

41. The water-based drilling fluid composition of claim 40, wherein the molecular weight of the CM-RCL is reduced by treating the CM-RCL with a member of molecular weight reducing agents selected from the group consisting of an acid, hypochlorites, chlorites, a mixture of caustic and oxygen, peroxides, cellulolytic enzymes, and radiation.

42. The water-based drilling fluid composition of claim 40, wherein the molecular weight reduction of the CM-RCL is carried out in a solution or slurry process.

43. The water-based drilling fluid composition of claim 1, wherein high molecular weight CM-RCL is used in combination with molecular weight reduced CM-RCL to further improve the fluid control properties.

44. The water-based drilling fluid composition of claim 1, wherein the CM-RCL is not purified.

45. The water-based drilling fluid composition of claim 1, wherein the CM-RCL has an assay of 40 wt %.

46. The water-based drilling fluid composition of claim 1, wherein the CM-RCL has an assay of 65 wt %.

47. The water-based drilling fluid composition of claim 1, wherein the CM-RCL has an assay of 98 wt %.

48. The water-based drilling fluid composition of claim 1, wherein the raw cotton linters used to make the CM-RCL is uncut.

49. The water-based drilling fluid composition of claim 1, wherein the raw cotton linters used to make the CM-RCL is cut.

50. The water-based drilling fluid composition of claim 49, wherein the cut raw cotton linters is a loose mass of comminuted raw cotton linter fibers that a) has a bulk density of at least 8 g/100 ml and b) at least 50 wt % of the fibers in the loose mass passes through a US standard sieve size # 10 (2 mm openings).

51. The water-based drilling fluid composition of claim 1, wherein the CM-RCL is used in combination with cellulose ethers made from purified cotton linters or wood pulps.

52. The water-based drilling fluid composition of claim 51, wherein the cellulose ethers are selected from the group consisting of carboxymethyl-cellulose (CMC), hydroxyethylcellulose (HEC), carboxymethyl-hydroxyethylcellulose (CMHEC) and polyanionic cellulose (PAC).

53. The water-based drilling fluid composition of claim 41, wherein the molecular weight reducing agent is hydrogen peroxide or sodium peroxide.