Metal matrix composites, and methods for making the same

• US 20060024490A1
• Filed: 07/29/2004
• Published: 02/02/2006
• Est. Priority Date: 07/29/2004
• Status: Abandoned Application

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Grether, Michael F., Werner, Paul S.
• Application Number:
  US10/902,382
• Publication Number:
  US 20060024490A1
• Time in Patent Office: Days
• US Class Current: 428/323
• CPC Class Codes: B22D 19/14 the objects being filamentary or particulate in form making alloys containing fibres or filaments by contacting the fibres or filaments with molten metal C22C47/08
• CPC Class Codes: C22C 47/06 by forming the fibres or filaments into a preformed structure, e.g. using a temporary binder to form a mat-like element
• CPC Class Codes: C22C 47/08 by contacting the fibres or filaments with molten metal, e.g. by infiltrating the fibres or filaments placed in a mould C22C47/16 takes precedence
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles

Abstract

Metal matrix composite inserts and articles, and methods for making the same.

Claims

1. A method for making a metal matrix composite insert, the method comprising:

consolidating a three dimensional array of elongated metal matrix composite articles together to provide a metal matrix composite insert,

wherein at least three of the elongated metal matrix composite articles each comprise a plurality of substantially continuous fibers selected from the group consisting of boron fibers, boron nitride fibers, carbon fibers, ceramic oxide fibers, graphite fibers, silicon carbide fibers, and combinations thereof in a metal selected from the group consisting of aluminum, magnesium, and alloys thereof, wherein the metal secures the substantially continuous fibers in place, and wherein the metal extends along at least a portion of the length of the substantially continuous fibers, and

wherein the metal matrix composite insert comprises the substantially continuous fibers and metal of the elongated metal matrix composite articles, wherein such metal secures the substantially continuous fibers in place, wherein at least 50 percent by volume of the metal matrix composite insert are the substantially continuous fibers, wherein such metal extends along at least a portion of the length of the substantially continuous fibers.

2. The method according to claim 1, wherein the metal matrix composite insert has an outer surface, and wherein the method further comprises providing a metal layer onto the outer surface.

3. The method according to claim 1, wherein the metal matrix composite insert has an outer surface, and wherein the method further comprises providing at least one of a zinc or tin layer onto the outer surface.

4. The method according to claim 1, wherein the metal matrix composite insert has an outer surface, and wherein the method further comprises providing a metal layer having a positive Gibbs oxidation free energy at a temperature above at least 200°

C. onto the outer surface.

5. The method according to claim 4, wherein the metal layer having a positive Gibbs oxidation free energy at a temperature above at least 200°

C. has a thickness of at least 8 micrometers.

6. The method according to claim 1, wherein the metal matrix composite insert has an outer surface, and wherein the metal matrix composite insert further comprises, in order (i) at least one of a zinc or tin layer, (ii) a nickel layer, and (iii) a metal layer having a positive Gibbs oxidation free energy at a temperature above at least 200°

C. onto the outer surface.

7. A method of making a metal matrix composite article, the method comprising:

positioning a metal matrix composite insert according to claim 6 in a mold;

providing molten metal selected from the group consisting of aluminum and alloys thereof into the mold; and

cooling the molten metal to provide a metal matrix composite article.

8. The method according to claim 7, wherein the plurality of substantially continuous fibers includes substantially continuous ceramic oxide fibers, and wherein the metal securing the substantially continuous ceramic oxide fibers is selected from the group consisting of aluminum and alloys thereof.

9. The method according to claim 8, wherein at least 60 percent by volume of the metal matrix composite insert are the substantially continuous ceramic oxide fibers.

10. The method according to claim 8, wherein in a range from 50 to 70 percent by volume of the metal matrix composite insert are the substantially continuous ceramic oxide fibers.

11. The method according to claim 8, wherein the metal matrix article is a vehicle component selected from the group consisting of suspension component, engine component, and structural component.

12. The method according to claim 8, wherein the metal matrix article is a brake caliper.

13. The method according to claim 7, wherein the metal matrix article is a vehicle component selected from the group consisting of suspension component, engine component, and structural component.

14. The method according to claim 7, wherein the metal matrix article is a brake caliper.

15. The method according to claim 1, wherein the plurality of substantially continuous ceramic fibers includes substantially continuous ceramic oxide fibers, and wherein the metal securing the substantially continuous ceramic oxide fibers is selected from the group consisting of aluminum and alloys thereof.

16. The method according to claim 15, wherein the metal matrix composite insert has an outer surface, and wherein the metal matrix composite insert further comprises, in order (i) at least one of a zinc or tin layer, (ii) a nickel layer, and (iii) a metal layer having a positive Gibbs oxidation free energy at a temperature above at least 200°

C. onto the outer surface.

17. The method according to claim 16, wherein in a range from 50 to 70 percent by volume of the metal matrix composite insert is the substantially continuous ceramic oxide fibers.

18. The method according to claim 17, wherein the metal matrix composite insert has a transverse strength of at least 275 MPa.

19. The method according to claim 16, wherein the consolidating is conducted at a pressure less than 40 MPa.

20. The method according to claim 16, wherein the substantially continuous ceramic oxide fibers are longitudinally aligned.

21. A metal matrix composite reinforcement insert comprising:

substantially continuous fibers and a metal, wherein the metal secures the substantially continuous fibers in place, wherein at least 50 percent by volume of the metal matrix composite insert are the substantially continuous fibers, wherein the metal extends along at least a portion of the length of the substantially continuous fibers, wherein the substantially continuous fibers are selected from the group consisting of boron fibers, boron nitride fibers, carbon fibers, ceramic oxide fibers, graphite fibers, silicon carbide fibers, and combinations thereof, wherein the metal is selected from the group consisting of aluminum, magnesium, and alloys thereof, wherein the metal matrix composite reinforcement insert includes a microstructure comprising a plurality of generally polygonal shapes, and wherein for at least some of the generally polygonal shapes, each generally polygonal shape generally shares a common vertex with at least two adjacent generally polygonal shapes.

22. The metal matrix composite reinforcement insert according to claim 21, wherein the plurality of generally polygonal shapes comprises generally hexagonal shapes.

23. The metal matrix composite insert according to claim 22, wherein the metal matrix composite insert has an outer surface, and wherein the metal matrix composite insert further comprises a metal layer on the outer surface.

24. The metal matrix composite insert according to claim 22, wherein the metal matrix composite insert has an outer surface, and wherein the metal matrix composite insert further comprises at least one of a zinc or tin layer on the outer surface.

25. The metal matrix composite insert according to claim 22, wherein the metal matrix composite insert has an outer surface and further comprises a metal layer on the outer surface, and wherein the metal layer has a positive Gibbs oxidation free energy at a temperature above at least 200°

C.

26. The metal matrix composite insert according to claim 25, wherein the metal layer has a thickness of at least 8 micrometers.

27. The metal matrix composite insert according to claim 22, wherein the metal matrix composite insert has an outer surface, and wherein the metal matrix composite insert further comprises, in order (i) at least one of a zinc or tin layer, (ii) a nickel layer, and (iii) a metal later having a positive Gibbs oxidation free energy at a temperature above at least 200°

C. onto the outer surface.

28. The metal matrix composite insert according to claim 27, wherein the plurality of substantially continuous fibers includes substantially continuous ceramic oxide fibers, and wherein the metal securing the substantially continuous ceramic oxide fibers is selected from the group consisting of aluminum and alloys thereof.

29. The metal matrix composite insert according to claim 28, wherein at least 60 percent by volume of the metal matrix composite insert is the substantially continuous ceramic oxide fibers.

30. The metal matrix composite insert according to claim 28, wherein in a range from 50 to 70 percent by volume of the metal matrix composite insert is the substantially continuous ceramic oxide fibers.

31. The metal matrix composite insert according to claim 28, wherein the metal matrix composite insert has a transverse strength of at least 275 MPa.

32. The metal matrix composite insert according to claim 22, wherein the plurality of substantially continuous fibers includes substantially continuous ceramic oxide fibers, and wherein the metal securing the substantially continuous ceramic oxide fibers is selected from the group consisting of aluminum and alloys thereof.

33. The metal matrix composite insert according to claim 32, wherein the substantially continuous ceramic oxide fibers are longitudinally aligned.