Laminated membranes for diffusion limited gas sensors resistant to pressure variations
First Claim
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1. A micro-fuel cell sensor for measuring in fluid streams, the sensor comprising:
- a housing;
a sensing element comprising first and second gas diffusing electrodes spaced from one another, said sensing element disposed in said housing;
a fuel-cell spacer having an acidic electrolyte disposed between said first and second electrodes;
a gas permeable membrane separating said first electrode from the oil with dissolved gas and enabling gas dissolved in oil to diffuse therethrough, said first membrane being spaced from said first electrode enabling gas diffused through said first membrane to contact said first electrode;
a second gas permeable membrane separating said second electrode from atmospheric air and defining a second cavity therewith isolated from said first cavity.
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Abstract
A micro fuel cell sensor having laminated gas permeable membrane. The sensor comprises a housing, first and second gas diffusing electrodes spaced from one another, a fuel-cell spacer having an acidic electrolyte disposed between said first and second electrodes, and two gas permeable membranes. The first gas permeable membrane comprises a polymer laminated on a metal substrate, wherein the substrate comprises pores that have dimensions at least less than one-half the thickness of the polymer film.
31 Citations
19 Claims
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1. A micro-fuel cell sensor for measuring in fluid streams, the sensor comprising:
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a housing;
a sensing element comprising first and second gas diffusing electrodes spaced from one another, said sensing element disposed in said housing;
a fuel-cell spacer having an acidic electrolyte disposed between said first and second electrodes;
a gas permeable membrane separating said first electrode from the oil with dissolved gas and enabling gas dissolved in oil to diffuse therethrough, said first membrane being spaced from said first electrode enabling gas diffused through said first membrane to contact said first electrode;
a second gas permeable membrane separating said second electrode from atmospheric air and defining a second cavity therewith isolated from said first cavity. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16)
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17. An apparatus for measuring dissolved gasses in oil, the apparatus comprising:
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a housing;
a micro-fuel cell sensor disposed in said housing;
a cover member;
said sensor comprising;
a sensing element comprising first and second gas diffusing electrodes spaced from one another, said sensing element disposed in said housing;
a fuel-cell spacer having an acidic electrolyte disposed between said first and second electrodes;
a first gas permeable membrane separating said first electrode from the oil with dissolved gas and enabling gas dissolved in oil to diffuse therethrough, said first membrane being spaced from said first electrode enabling gas diffused through said first membrane to contact said first electrode;
a second gas permeable membrane separating said second electrode from atmospheric air and defining a second cavity therewith isolated from said first cavity. - View Dependent Claims (18)
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19. In a sensor having a housing, a sensing element comprising first and second gas diffusing electrodes spaced from one another, said sensing element disposed in said housing and comprising;
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a fuel-cell spacer having an acidic electrolyte disposed between said first and second electrodes;
wherein said electrodes comprise platinum on carbon;
a first gas permeable membrane separating said first electrode from the oil with dissolved gas and enabling gas dissolved in oil to diffuse therethrough, said first membrane being spaced from said first electrode enabling gas diffused through said first membrane to contact said first electrode;
wherein said gas permeable membrane is impervious to oil; and
further wherein the gas permeation rate through the laminated membrane is less than the rate of the electrochemical gas sensing reaction occurring in the sensor;
said gas permeable membrane comprising;
a polymer laminated on a metal disc;
vacuum resistant;
wherein the polymer comprises at least one of Polytetrafluoroethylene, Perfluorinated Ethylene-Propylene Copolymer, Perfluoroalkoxy Polytetrafluoroethylene, Polyvinylidene fluoride, Polyvinyl Chloride, Polyimide, Polyethylene, Polyether Ester Ketone, Polycarbonate and Polyurethane;
and further the polymer has a thickness in a range from about 25 micron (1 mil) to about 250 micron (10 mil);
a porous metal disc;
the metal disc supports the polymer film under positive and negative pressure;
the metal disc comprises pores;
the diameter of the pores of the metal disc are less than or equal to about one-half of the polymer thickness; and
further wherein the dimension of the pores of the metal disc are much larger than the gas molecules to be analyzed by the sensor.
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Specification