Removal of carbon dioxide from air

• US 20060051274A1
• Filed: 08/22/2005
• Published: 03/09/2006
• Est. Priority Date: 08/23/2004
• Status: Abandoned Application

• Current Assignee: Carbon Sink, Inc., Trustees Of Columbia University In The City Of New York (Columbia University), Global Research Technologies, LLC
• Original Assignee: Carbon Sink, Inc.
• Inventors: Lackner, Klaus S., Wright, Allen B.
• Application Number:
  US11/209,962
• Publication Number:
  US 20060051274A1
• Time in Patent Office: Days
• US Class Current: 423/220
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/965 including an electrochemical process step
• CPC Class Codes: B01D 61/445 with bipolar membranes; Water splitting
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

The present invention is directed to methods for removing carbon dioxide from air, which comprises exposing solvent covered surfaces to air streams where the airflow is kept laminar, or close to the laminar regime. The invention also provides for an apparatus, which is a laminar scrubber, comprising solvent covered surfaces situated such that they can be exposed to air stream. In another aspect, the invention provides a method and apparatus for separating carbon dioxide (CO₂) bound in a solvent. The invention is particularly useful in processing hydroxide solvents containing CO₂ captured from air.

Claims

1. A method for capturing carbon dioxide from air, which comprises exposing solvent covered surfaces to air streams where the air streams have a flow that is kept laminar, or close to a laminar regime.

2. The method of claim 1, comprising one or more of the following features:

(a) wherein the surfaces comprise smooth parallel plates;

(b) wherein the surfaces are not entirely flat, and follow straight parallel lines in the direction of the airflow;

(c) wherein the surfaces comprise corrugations, pipes, tubes, angular shapes akin to harmonica covers, or any combination thereof, but with the air flow skill following a straight line.;

(d) wherein the surfaces are roughened with grooves, dimples, bumps or other small structures that are smaller than the surface spacing, and wherein these surface structures remain well within the laminar boundary of the air flow;

(e) wherein the surfaces are roughened with grooves, dimples, bumps or other small structures, and the Reynolds number of the flow around these grooves, dimples, bumps or other small structures is small, in an optimum it is between 0 and 100;

(f) wherein the surface is roughened through sand blasting or other similar means;

(g) wherein the surface is roughened through etching or other similar means;

(h) wherein the surfaces are on plates made from steel or other hydroxide resistant metals;

(i) wherein the surfaces are on plates made from glass;

(j) wherein the surfaces are on plates made from plastic, preferably polypropylene; and

(k) wherein the surfaces have been coated or treated to increase hydrophilicity of the plates.

3. The method of claim 1, wherein the surfaces are foils or other thin films that are held taught by wires and supported by taught wire or wire netting.

4. The method of claim 3, comprising one or more of the following features:

(a) wherein all wires but a few supporting wires in the front and the back run parallel to the wind flow direction;

(b) wherein the foil or film is supported on a rigid structure that could be a solid plate, a honeycomb, or lattice work that can lend structural rigidity to the films;

(c) wherein the films are made from plastic foils; and

(d) wherein the films are made from plastic foils which have been surface treated to increase the hydrophilicity of the surface.

5. The method of claim 1, comprising one or more of the following features:

(a) wherein the direction of the air flow is horizontal;

(b) wherein the surfaces—

or the line of symmetry of the surfaces—

is vertical;

(c) wherein the liquid solvent flow is at about a right angle to the airflow direction;

(d) wherein the surface spacing is from about 0.3 cm to about 3 cm;

(e) wherein the surface length is at about a right angle to the airflow direction, and is from about 0.30 m to about 10 m;

(f) wherein the airflow speed is from about 0.1 m/s to about 10 m/s;

(g) wherein the distance of airflow between the surfaces is from about 0.10 m to about 2 m;

(h) wherein liquid solvent is applied by means of spraying a flow onto the upper edge of the surface;

(i) wherein the solvent is applied to both sides of the plates;

(j) wherein the solvent is applied in a pulsed manner;

(k) wherein the liquid solvent is collected at the bottom of the surfaces or plates;

(l) wherein the liquid solvent is collected at the bottom of the surfaces or plates, and the collected fluid is immediately passed on to a recovery unit;

(m) wherein the liquid solvent is collected at the bottom of the surfaces or plates, and the collected fluid is recycled to the top of the scrubbing unit for additional CO₂ collection;

(n) wherein the apparatus further comprises and is equipped with air flow straighteners to minimize losses from misalignment between the surfaces and the instantaneous wind field; and

(o) wherein the apparatus further comprises and is equipped with mechanisms that either passively or actively steer the surfaces so that they point into the wind.

8. The method of claim 1, wherein the surfaces are rotating disks where wetting is helped by the rotary motion of the disks and the air is moving at right angle to the axis.

9. The method of claim 8, comprising one or more of the following features:

(a) wherein the axis is approximately horizontal and the disks dip into the solvent at their rim and the circular motion promotes distribution of the fluid on the disks;

(b) wherein the liquid is sprayed onto the disk as it moves by a radially aligned injector; and

(c) wherein the liquid is extruded onto the disk near the axis.

10. The method of claim 1, wherein the surfaces are concentric tubes of circular or other cross-section shape with the air flowing in the direction of the tube axis.

11. The method of claim 10, comprising one or more of the following features:

(a) wherein the tubes rotate around the center axis;

(b) wherein the tubes have axis oriented approximately vertically and solvent is applied in a manner that it flows downward on the surfaces of the tube; and

(c) wherein the tubes have axis oriented at an angle to the vertical and the solvent is inserted at a single point at the upper opening and flows downward in a spiral motion covering the entire surface.

12. The method of claim 1, wherein the solvent is a hydroxide solution.

13. The method of claim 12, comprising one or more of the following features:

(a) wherein the hydroxide concentration is between 0.1 and 20 molar;

(b) wherein the hydroxide concentration is between 1 and 3 molar;

(c) wherein the concentration of the solution exceeds 3 molar;

(d) wherein the concentration of the solution has been adjusted to minimize water losses or water gains;

(e) wherein where the concentration of the solution is allowed to adjust itself until its vapor pressure matches that of the ambient air;

(f) wherein the hydroxide is sodium hydroxide;

(g) wherein where the hydroxide is potassium hydroxide;

(h) wherein the solvent is a hydroxide solution where additives or surfactants have been added;

(i) wherein the solvent is a hydroxide solution containing additives or surfactants which increase the reaction kinetics of CO₂ with the solution;

(j) wherein the solvent is a hydroxide solution containing additives to reduce the water vapor pressure over the solution;

(k) wherein the solvent is a hydroxide solvent containing additives or surfactants which change the viscosity or other rheological properties of the solvent; and

(l) wherein the solvent is a hydroxide solvent containing additives or surfactants which improve the absorption properties of the solvent to scrub gases other than CO₂ from the air.

15. The method of claim 14, wherein the carbon dioxide is captured from ambient air by the process of claim 1.

6. A laminar wind scrubber that utilizes pressure drops created by natural air flows comprising:

(a) wind stagnation in front of the scrubber;

(b) a pressure drop created by flows substantially orthogonal to the entrance and/or exit into the scrubbers;

or

(c) a pressure drop created by thermal convection.

7. A scrubber of claim 6, comprising one or more of the following features:

(a) wherein the pressure drop is created in a cooling tower or by thermal convection along a hill side;

(b) comprising a plurality of lamella wetted at least in part by a liquid sorbent; and

(c) wherein spacing between lamella is chosen such that the system does not transition a laminar flow regime, and preferably is about 2 to 4 mm.

14. A method of creating tradable carbon credits which comprises extracting carbon dioxide from ambient air at a location remote from where the carbon dioxide was generated, using an absorbent, and selling, trading or transferring the resulting carbon credits to a third party.

16. The method of claim 14, wherein the carbon dioxide is captured from ambient air using the apparatus of claim 6.

17. The method of claim 14, wherein a carbon credit is sold, traded or transferred with the sale or lease of an automobile or truck or with fuel for the automobile or truck.

18. The method of claim 14, wherein a carbon credit is sold by a producer of a hydrocarbon fuel.

19. A method for separating a hydroxide/carbonate brine into hydroxide and CO₂, wherein the brine is first concentrated to approach the carbonate saturation point;

the concentrated hydroxide carbonate brine is subsequently separated through thermal swing precipitation of the carbonate from the brine;

the carbonate is electrochemically separated into sodium hydroxide solution and sodium bicarbonate solution in a first electrochemical process step;

the bicarbonate is mixed with an acid to release carbon dioxide and the acid is recovered from its salt in a second electrochemical process step.

20. The method of claim 19, comprising one or more of the following features:

(a) wherein the sodium hydroxide solution and the sodium bicarbonate solution are separated from the brine by electrodialysis with bipolar membranes;

(b) wherein the second electrochemical process comprises electrodialysis with bipolar membranes;

(c) wherein the brine is processed without initial concentration;

(d) wherein at least some of the carbonate is separated from the hydroxide in the second electrochemical process step;

(e) wherein acid is used to neutralize the brine before it releases CO₂;

(f) wherein acid injection is used to neutralize the brine before it releases CO₂, said acid injection is accomplished in a first low pressure unit that adjusts the mixture to a pH level that supports the formation of bicarbonate, and a second high pressure system that generates CO₂;

(g) wherein CO₂ is released by an electrochemical process in a pressure vessel so as to provide high pressure CO₂;

(h) wherein the CO₂ is released in an electrochemical process which comprises electrodialysis with bipolar membranes;

(i) wherein the CO₂ is released in an electrochemical process which generates hydrogen on the cathodes and uses it again in a hydrogen anode.

(j) wherein the carbonate is separated from the hydroxide at a last step; and

(k) wherein all or part of the hydroxide and the carbonate are separated in a CO₂ releasing step.

25. The method of claim 19, wherein the sodium bicarbonate is subjected to thermal decomposition into sodium carbonate and CO₂ followed by recycling of the sodium carbonate to an earlier stage of the process.

26. The method of claim 25, comprising one or more of the following features:

(a) wherein the bicarbonate solution is reduced in water content through membrane separation by concentration gradients or electrochemical gradients (reverse electrodialysis), bicarbonate is extracted from the concentrated brine in a thermal swing precipitation followed by a thermal calcination of the bicarbonate to CO₂ and carbonate, and a resulting dilute bicarbonate output stream is recycled to another dewatering of the bicarbonate solution;

(b) wherein the bicarbonate solution is heated until CO₂ is released resulting in a carbonate/bicarbonate brine which is electrochemically reprocessed to bicarbonate;

(c) wherein the bicarbonate solution evolves CO₂ inside a pressure vessel;

(d) including a heat exchange between inputs and outputs of the thermal steps to minimize energy consumption;

(e) wherein dilute water streams generated are kept out of the brines and treated as off-water;

(f) wherein dilute water streams are used as make-up water in the input in an air contactor unit;

(g) wherein the base ion is sodium;

(h) wherein the base ion is potassium.

(i) wherein the base ion is a mixture including sodium and potassium; and

(j) wherein the base comprises an organic base.

35. A method for the separation of carbon dioxide from a hydroxide brine as claimed in claim 25 wherein the thermal decomposition step is replaced with an electrochemical process as claimed in claim 34.

36. The method of claim 35, wherein the CO₂ producing unit is pressurized to deliver a concentrated stream of CO₂.

21. A method for partially separating a hydroxide/carbonate brine into a hydroxide solution and a carbonate solution in a device that separates a volume into cells by means of membranes which alternate between bipolar membranes and cationic membranes, and fluid flowing in every other chamber is a concentrated hydroxide/carbonate brine whereas in the alternating chamber flows a dilute NaOH solution with sodium ions transferring across the cationic membranes and the bipolar membranes providing the necessary hydroxide ions and protons to maintain charge neutrality.

22. The method of claim 21, comprising one or both of the following features:

(a) wherein the cells are arranged in a stack having a liquid connection between the first and the last cell which contain brines of the same type;

(b) wherein the cells are arranged in a toroidal shape; and

(c) wherein the cells are arranged in a stack which comprises two separate cells.

24. The method of claim 21, comprising one or more of the following features:

(a) wherein the sodium hydroxide solution and the sodium bicarbonate solution are separated from the brine by electrodialysis with bipolar membranes;

(b) wherein the electrochemical process for recovering the acid from its salt comprises electrodialysis with bipolar membranes;

(c) wherein the brine is processed without initial concentration;

(d) wherein at least some of the carbonate is separated from the hydroxide in the second electrochemical process step;

(e) wherein acid is used to neutralize the brine before it releases CO₂;

(f) wherein acid injection is used to neutralize the brine before it releases CO₂, said acid injection is accomplished in a first low pressure unit that adjusts the mixture to a pH level that supports the formation of bicarbonate, and a second high pressure system that generates CO₂;

(g) wherein CO₂ release is accomplished by an electrochemical process.

(h) wherein the CO₂ is released by an electrochemical process in a pressure vessel so as to provide high pressure CO₂;

(i) wherein the CO₂ is released in an electrochemical process which comprises electrodialysis with bipolar membranes;

(j) wherein the CO₂ is released in an electrochemical process which generates hydrogen on the cathodes and uses it again in a hydrogen anode.

(k) wherein the carbonate is separated from the hydroxide at a last step; and

(l) wherein all or part of the hydroxide and the carbonate are separated in a CO₂ releasing step.

27. The method of claim 21, wherein the sodium bicarbonate is subjected to thermal decomposition into sodium carbonate and CO₂ followed by recycling of the sodium carbonate to an earlier stage of the process.

28. The method of claim 27, comprising one or more of the following features:

(a) wherein the bicarbonate solution is reduced in water content through membrane separation by concentration gradients or electrochemical gradients (reverse electrodialysis), bicarbonate is extracted from the concentrated brine in a thermal swing precipitation followed by a thermal calcination of the bicarbonate to CO₂ and carbonate, and a resulting dilute bicarbonate output stream is recycled to another dewatering of the bicarbonate solution;

(b) wherein the bicarbonate solution is heated until CO₂ is released resulting in a carbonate/bicarbonate brine which is electrochemically reprocessed to bicarbonate;

(c) wherein the bicarbonate solution evolves CO₂ inside a pressure vessel;

(d) including a heat exchange between inputs and outputs of the thermal steps to minimize energy consumption;

(e) wherein dilute water streams generated are kept out of the brines and treated as off-water;

(f) wherein dilute water streams are used as make-up water in the input in an air contractor unit.

(g) wherein the base ion is sodium;

(h) wherein the base ion is potassium;

(i) wherein the base ion is a mixture including sodium and potassium; and

(j) wherein the base comprises an organic base.

37. A method for the separation of carbon dioxide from a hydroxide brine as claimed in claim 27 wherein the thermal decomposition step is replaced with an electrochemical process as claimed in claim 36.

38. The method of claim 37, wherein the CO₂ producing unit is pressurized to deliver a concentrated stream of CO₂.

23. A method for separating a hydroxide/carbonate brine into a hydroxide solution and CO₂ which uses an electrochemical process to separate the hydroxide solution from the carbonate solution;

and the carbonate is electrochemically separated into sodium hydroxide solution and sodium bicarbonate solution in a first electrochemical process step;

the bicarbonate is mixed with an acid to release carbon dioxide; and

the acid is recovered from its salt through a second electrochemical process step.

29. A device for generating CO₂ by mixing acid and bicarbonate comprising in combination:

a reservoir for holding an acid, a reservoir for holding a base, and a reservoir for holding a product salt;

a line in fluid communication with the acid and base reservoirs, said line having a structure for enhancing mixing;

a gas separation unit for feeding CO₂ under pressure to an exit pressure valve, said gas separation unit being connected to the salt reservoir; and

an exit line from the salt brine reservoir mechanically coupled to pumps feeding acid and base into the acid and base holding reservoirs, respectively.

30. The device of claim 29, comprising one or more of the following features:

(a) wherein the CO₂ provides the bulk of the pumping power requirements to the device;

(b) further including a device for converting excess pressure on the CO₂ exit valve into usable power; and

(c) wherein excess pressure is converted into useable power which is channeled to the two input pumps or could be used elsewhere.

31. A device for generating CO₂ by mixing an acid and a bicarbonate, which comprises:

three reservoirs, one for holding an acid, one for holding a base, and one for holding a product salt, said reservoirs being separated from one another by membranes, said device being operated in a batch mode where fresh fluid is loaded at ambient pressure and the fluid is pressurized during the production of CO₂.

32. A device for separating an alkaline carbonate brine into a cation and bicarbonate, said device including an anode and a cathode to which power is delivered whereupon the cation is moved across the cationic membrane whereby to convert the initial brine to bicarbonate while the brine gradually accumulates as a pure hydroxide solution.

33. The device of claim 32, wherein the cation is sodium or potassium, or an ion that will not precipitate from the solution.

34. A device for separating CO₂ from a bicarbonate brine containing CO₂, which device comprises:

a reservoir having acidic cells and basic cells separated by anionic membranes alternating with bipolar membranes for producing in a stream bicarbonate ions which is mixed with acid in the acidic cells which produces CO₂, and leaving behind in the basic cells a residual brine enriched in carbonate ions.