Liquid feed fuel cell with nested sealing configuration

• US 20060078785A1
• Filed: 10/07/2004
• Published: 04/13/2006
• Est. Priority Date: 10/07/2004
• Status: Active Grant

• Current Assignee: Tekion
• Original Assignee: Tekion
• Inventors: Masel, Richard I., Mozsgai, Gregory
• Granted Patent: US 7,323,267 B2
• Time in Patent Office: Days
• US Class Current: 429/465
• CPC Class Codes: H01M 12/04 composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
• CPC Class Codes: H01M 12/065 with plate-like electrodes or stacks of plate-like electrodes
• CPC Class Codes: H01M 4/661 Metal or alloys, e.g. alloy coatings H01M4/669 take precedence
• CPC Class Codes: H01M 4/667 in the form of layers, e.g. coatings
• CPC Class Codes: H01M 8/0232 Metals or alloys
• CPC Class Codes: H01M 8/0234 Carbonaceous material
• CPC Class Codes: H01M 8/0245 in the form of layered or coated products
• CPC Class Codes: H01M 8/0271 Sealing or supporting means around electrodes, matrices or membranes
• CPC Class Codes: H01M 8/0273 with sealing or supporting means in the form of a frame
• CPC Class Codes: H01M 8/0276 Sealing means characterised by their form H01M8/0273 takes precedence
• CPC Class Codes: H01M 8/0284 Organic resins; Organic polymers
• CPC Class Codes: H01M 8/1009 with one of the reactants being liquid, solid or liquid-charged H01M8/12 takes precedence
• CPC Class Codes: H01M 8/1011 Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
• CPC Class Codes: H01M 8/22 Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen
• CPC Class Codes: H01M 8/241 with solid or matrix-supported electrolytes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A direct formic acid fuel cell includes a cathode current collector having a perpendicularly extending edge that is capable of cooperating with the perpendicularly extending edge of an anode current collector to effect a press fit. The configuration seals fluids disposed within the volume formed between the current collectors.

Claims

1. A fuel cell comprising:

(a) an anode current collector having a major planar portion and at least one edge that extends substantially perpendicularly from and substantially circumscribes said anode current collector major planar portion, said anode current collector major planar portion having at least one opening formed therein for facilitating fluid diffusion through said anode current collector;

(b) a cathode current collector having a major planar portion and at least one edge that extends substantially perpendicularly from and substantially circumscribes said cathode current collector major planar portion, said cathode current collector major planar portion having at least one opening formed therein for facilitating fluid diffusion through said cathode current collector;

(c) at least one layer of electrically insulative material interposed between said anode current collector and said cathode current collector, said electrically insulative material further including a membrane electrode assembly (MEA), said MEA comprising a membrane electrolyte having two oppositely facing major planar surfaces, a first electrocatalyst layer disposed on one of said electrolyte surfaces and a second electrocatalyst layer disposed on the other of said electrolyte surface;

(d) an anode fluid diffusion layer interposed between said anode current collector and said MEA, said anode fluid diffusion layer at least partially comprising an electrically conductive material;

(e) a cathode fluid diffusion layer interposed between said cathode current collector and said MEA, said cathode fluid diffusion layer at least partially consisting of an electrically conductive material;

wherein said perpendicularly extending edge of said cathode current collector is capable of cooperating with the said perpendicularly extending edge of said anode current collector to effect a press fit, thereby at least partially sealing fluids disposed within the volume formed between said current collector major portions, and thereby at least partially promoting the diffusion of cations from said anode diffusion layer to said cathode diffusion layer.

2. The fuel cell of claim 1 wherein said membrane electrolyte comprises a perfluorosulfonic acid membrane.

3. The fuel cell of claim 1 wherein said membrane electrolyte has at least one edge that extends substantially perpendicularly from and substantially circumscribes said oppositely facing major planar portions, said membrane electrolyte perpendicularly extending edge interposed between said anode current collector perpendicularly extending edge and said cathode current collector perpendicularly extending edge, thereby forming a seal between the perpendicularly extending edges of said current collectors.

4. The fuel cell of claim 3 wherein said membrane electrolyte having at least one perpendicularly extending edge is a membrane electrolyte having only one edge.

5. The fuel cell of claim 1 wherein a liquid fuel is directed to said anode fluid diffusion layer and a fluid oxidant is directed to said cathode fluid diffusion layer.

6. The fuel cell of claim 5 wherein said liquid fuel stream is selected from the group consisting essentially of formic acid, methanol, methyl formate, ethanol, propanol, sodium borohydride, alcohols, and esters.

7. The fuel cell of claim 6 wherein said liquid fuel stream comprises formic acid.

8. The fuel cell of claim 5 wherein said fluid oxidant is oxygen-containing air.

9. The fuel cell of claim 1 wherein the material comprising said anode fluid diffusion layer and said cathode diffusion layer is selected from the group of materials consisting essentially of electrically conductive mesh, electrically conductive expanded foil, or electrically conductive cloth.

10. The fuel cell of claim 1 wherein said anode and cathode comprise gold-plated titanium.

11. The fuel cell of claim 1 wherein said at least one layer of electrically insulative material further comprises a sealant.

12. The fuel cell of claim 11 wherein said sealant is silicone.

13. A fuel cell array comprising at least two fuel cells, each of said fuel cells comprising:

(a) an anode current collector having a major planar portion and at least one edge that extends substantially perpendicularly from and substantially circumscribes said anode current collector major planar portion, said anode current collector major planar portion having at least one opening formed therein for facilitating fluid diffusion through said anode current collector;

(b) a cathode current collector having a major planar portion and at least one edge that extends substantially perpendicularly from and substantially circumscribes said cathode current collector major planar portion, said cathode current collector major planar portion having at least one opening formed therein for facilitating fluid diffusion through said cathode current collector;

(c) at least one layer of electrically insulative material disposed between said anode current collector and said cathode current collector, said electrically insulative material further including a membrane electrode assembly (MEA) interposed between said anode current collector and cathode current collector, said MEA comprising a membrane electrolyte having two oppositely facing major planar surfaces, a first electrocatalyst layer disposed on one of said membrane surfaces and a second electrocatalyst layer disposed on the other of said membrane surfaces;

(d) an anode fluid diffusion layer interposed between said anode current collector and said MEA, said anode fluid diffusion layer at least partially comprising an electrically conductive material;

(e) a cathode fluid diffusion layer interposed between said cathode current collector and said MEA, said cathode fluid diffusion layer at least partially comprising an electrically conductive material;

said fuel cell array further comprising a frame having at least two edge portions, each of said edge portions having a channel formed therein for accommodating said perpendicularly extending edges of said anode and cathode current collectors, thereby substantially containing fluids disposed within the volume formed within said fuel cell array.

14. The fuel cell array of claim 13 wherein said membrane electrolyte comprises a perfluorosulfonic acid membrane.

15. The fuel cell array of claim 13 wherein said membrane electrolyte has at least one edge that extends substantially perpendicularly from and substantially circumscribes said oppositely facing major planar portions, said perpendicularly extending edge interposed between said anode current collector perpendicularly extending edge and said cathode current collector perpendicularly extending edge, thereby forming a seal between the perpendicularly extending edges of said current collectors.

16. The fuel cell array of claim 13 wherein said membrane electrolyte having at least one perpendicularly extending edge is a membrane electrolyte having only one edge.

17. The fuel cell array of claim 13 wherein a liquid fuel is directed to said anode fluid diffusion layer and a fluid oxidant is directed to said cathode fluid diffusion layer.

18. The fuel cell array of claim 17 wherein said liquid fuel comprises a constituent selected from the group consisting essentially of formic acid, methanol, methyl formate, ethanol, propanol, sodium borohydride, alcohols, and esters.

19. The fuel cell array of claim 18 wherein said liquid fuel comprises formic acid.

20. The fuel cell array of claim 17 wherein said fluid oxidant is gaseous oxygen.

21. The fuel cell array of claim 13 wherein said frame is formed from an electrically insulative, substantially rigid material.

22. The fuel cell array of claim 21 wherein said electrically insulative, substantially rigid material is polymeric.

23. The fuel cell array of claim 22 wherein said polymeric material is polycarbonate.

24. The fuel cell array of claim 13 wherein said frame has at least one passage transversing from said frame'"'"'s interior volume to said frame'"'"'s exterior volume.

25. The fuel cell array of claim 24 wherein said at least one passage facilitates fluid diffusion to said fuel cell'"'"'s anode current collector.

26. The fuel cell array of claim 13 wherein said frame channel and said perpendicularly extending edge portions of said anode and cathode current collectors are at least partially joined with an adhesive.

27. A fuel cell comprising:

(a) an anode current collector having a major planar portion and at least one edge that extends substantially perpendicularly from and substantially circumscribes said anode current collector major planar portion;

(b) a cathode current collector having a major planar portion and at least one edge that extends substantially perpendicularly from and substantially circumscribes said cathode current collector major planar portion, said cathode current collector major planar portion having at least one opening formed therein for facilitating fluid diffusion through said cathode current collector;

(c) at least one layer of electrically insulative material disposed between said anode current collector and said cathode current collector, said electrically insulative material further including a sealant and a membrane electrode assembly (MEA) interposed between said anode current collector and cathode current collector, said MEA comprising a membrane electrolyte having two oppositely facing major planar surfaces, a first electrocatalyst layer disposed on one of said membrane surfaces and a second electrocatalyst layer disposed on the other of said membrane surfaces;

(d) an anode fluid diffusion layer interposed between said anode current collector and said MEA, said anode fluid diffusion layer at least partially consisting of an electrically conductive material;

(e) a cathode fluid diffusion layer interposed between said cathode current collector and said MEA, said cathode fluid diffusion layer at least partially consisting of an electrically conductive material;

wherein said perpendicularly extending edge of said cathode current collector is capable of cooperating with the said perpendicularly extending edge of said anode current collector to effect a press fit, and wherein said sealant seals said perpendicularly extending edges of said anode current collector and said cathode current collector, thereby at least partially sealing fluids disposed within the volume formed between said current collector major portions.

28. The fuel cell of claim 27 wherein said membrane electrolyte has at least one edge that extends substantially perpendicularly from and substantially circumscribes said oppositely facing major planar portions, said perpendicularly extending edge interposed between said anode current collector perpendicularly extending edge and said cathode current collector perpendicularly extending edge, thereby forming a seal between the perpendicularly extending edges of said current collectors.

29. The fuel cell of claim 28 wherein the at least one layer of electrically insulating material further comprises two bands of said sealant, a first band interposed between said anode current collector perpendicularly extending edge and said membrane electrolyte perpendicularly extending edge, a second band interposed between said cathode current collector perpendicularly extending edge and said membrane electrolyte perpendicularly extending edge.

30. The fuel cell of claim 27 wherein said sealant is silicone.