Toner processes and compositions thereof

• US 20060078814A1
• Filed: 10/12/2004
• Published: 04/13/2006
• Est. Priority Date: 10/12/2004
• Status: Active Grant

• Current Assignee: Nu-Kote Incorporated
• Original Assignee: Nu-Kote Incorporated
• Inventors: Thompson, Richard J., Hsieh, Bing B.
• Granted Patent: US 7,247,416 B2
• Time in Patent Office: Days
• US Class Current: 430/108.700
• CPC Class Codes: G03G 9/0804 whereby the components are brought together in a liquid dispersing medium
• CPC Class Codes: G03G 9/0812 Pretreatment of components
• CPC Class Codes: G03G 9/0819 characterised by the dimensions of the particles
• CPC Class Codes: G03G 9/08782 Waxes
• CPC Class Codes: G03G 9/09 Colouring agents for toner particles
• CPC Class Codes: G03G 9/0926 characterised by physical or chemical properties
• CPC Class Codes: G03G 9/09716 treated with organic compounds
• CPC Class Codes: G03G 9/09725 Silicon-oxides; Silicates
• CPC Class Codes: G03G 9/09741 cationic
• CPC Class Codes: G03G 9/0975 anionic
• CPC Class Codes: G03G 9/09783 Organo-metallic compounds

Abstract

The invention relates to color toner compositions prepared from a process for the preparation of a dry toner powder from an aqueous pigment concentrate dispersion comprising: blending at least an aqueous-based pigment concentrate dispersion and a resin to produce a paste; charging the paste to an extruder to generate an extruded pigment/resin mixture; dispersing the extruded pigment/resin mixture in a low boiling organic medium to create an organic phase; dispersing the organic phase in an aqueous phase containing a particulate stabilizer and mixing the organic phase and the aqueous phase at elevated temperature and under shear force to form toner particles of a controlled size and shape; removing the organic solvent and particulate stabilizer from the formed particles; and washing, drying, and collecting the particles for use as a dry toner powder.

Claims

1. A process for the preparation of a dry toner powder from an aqueous pigment concentrate dispersion, the process comprising:

a. blending at least an aqueous-based pigment concentrate dispersion and a resin to produce a paste;

b. charging the paste to an extruder and compounding the paste at a temperature of up to about 150°

C. to generate an extruded pigment/resin mixture with a greater degree of dispersion than was present in the paste;

c. dispersing the extruded pigment/resin mixture in a low boiling organic medium to create an organic phase;

d. dispersing the organic phase in an aqueous phase containing a particulate stabilizer and optionally an interface promoter and mixing the organic phase and the aqueous phase at elevated temperature and under shear force to form toner particles of a controlled size and shape;

e. removing the organic solvent, particulate stabilizer, and interface promoter, if used, from the formed particles; and

f. washing, drying, and collecting the particles for use as a dry toner powder.

2. The process of claim 1 wherein the aqueous pigment concentrate dispersion comprises water, pigment, a pigment stabilizer, and optionally a surfactant, and exhibits from about 30% to about 50% by weight pigment solids.

3. The process of claim 1 wherein the paste further comprises one or more toner components selected from the group consisting of a wax, a charge control agent, an additional colorant, and a plasticizer.

4. The process of claim 3 wherein the wax is a low molecular weight wax selected from the group consisting of polyolefin waxes, carnauba wax, candelilla wax, hydrogenated jojoba oil, rice wax, hydrogenated lanolin, meadowfoam oil, and derivatives thereof, and is used as up to 15 wt % of the paste.

5. The process of claim 3 wherein the charge control agent is selected from the group consisting of quaternary salts, metal and non-metal dyes, chromium, cobalt and zinc complexes, nigrosines, positive and negative colorless polymers, metal chelates, and quaternary amines, and is included as up to about 10 wt % of the paste.

6. The process of claim 3 wherein the additional colorant, present as up to 8 wt % of the paste, is a dry pigment.

7. The process of claim 1 wherein the extrusion process of step (b) drives off substantially all of the water from the aqueous pigment concentrate dispersion.

8. The process of claim 1 wherein the extruded pigment/resin mixture is mixed with the low boiling organic medium at a temperature of from about 20°

C. to about 50°

C. and at a weight ratio of extruded mixture to organic medium of from 10;

90 to 60;

40.

9. The process of claim 1 wherein the organic phase, present as from about 10% to about 60% of the total volume being mixed, is dispersed in the aqueous phase in a microfluidizer to generate content-uniform droplets of toner/organic medium, the size of which is reduced under high shear agitation.

10. The process of claim 1 wherein the particulate stabilizer of step (d) is particulate silica.

11. The process of claim 1 wherein the dry toner powder produced by the process exhibits a particle size of from about 5 μ

m to about 8 μ

m and is substantially spherical.

12. The process of claim 1 wherein the dry toner powder produced by the process is further combined with at least one external post-additive agent.

13. A dry toner powder comprising homogeneous toner powder particles containing at least a binder and a colorant, wherein the colorant is derived from an aqueous pigment concentrate dispersion, the aqueous solvent from which is removed during processing of the toner powder to generate dry toner powder particles exhibiting substantially uniform content and a particle size of from about 5 microns to about 8 microns.

14. The dry toner powder of claim 13 wherein the aqueous pigment concentrate dispersion comprises at least water, pigment, and a pigment stabilizer, and exhibits a pigment content of about 40% solids.

15. The dry toner powder of claim 13 wherein the dry toner powder is prepared from a mixture comprising about 9.5% aqueous pigment concentrate dispersion, about 79% binder, about 4% wax component, about 2% charge control agent, about 4.5% dry pigment colorant, and about 1% fine silica powder, based on the total weight of the mixture.

16. The dry toner powder of claim 13 wherein the toner powder particles are substantially spherical.

17. The dry toner powder of claim 13 wherein the toner powder particles exhibit a narrow size distribution.