Polyester blends with improved stress whitening for film and sheet applications

• US 20060111519A1
• Filed: 11/10/2005
• Published: 05/25/2006
• Est. Priority Date: 11/12/2004
• Status: Active Grant

• Current Assignee: Eastman Chemical Company
• Original Assignee: Eastman Chemical Company
• Inventors: Salyer, David Gayle, Strand, Marc Alan, Piner, Rodney Layne
• Granted Patent: US 8,071,695 B2
• Time in Patent Office: Days
• US Class Current: 525/444
• CPC Class Codes: C08K 5/0008 Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
• CPC Class Codes: C08K 5/09 Carboxylic acids; Metal salts thereof; Anhydrides thereof
• CPC Class Codes: C08K 5/098 Metal salts of carboxylic acids
• CPC Class Codes: C08K 5/101 of monocarboxylic acids
• CPC Class Codes: C08K 5/103 with polyalcohols
• CPC Class Codes: C08K 5/20 Carboxylic acid amides
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/18 Polyesters or polycarbonates according to C08L67/00 - C08L69/00; Derivatives thereof
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence
• CPC Class Codes: C08L 67/025 containing polyether sequences
• CPC Class Codes: C08L 91/06 Waxes

Abstract

Disclosed are polyester blends that provide improved stress whitening behavior. The blends may be prepared from a polyester having crystallization half-time of at least 5 minutes and a polyester elastomer. The polyesters blends may be extruded or, in the presence of a release additive, calendered to produce film or sheet. Also disclosed are processes for making a film or sheet by extrusion or calendering the above blends and the film or sheet produced therefrom. The polyester blend and the film or sheet produced therefrom also may include plasticizers and/or flame retardants to increase their flexibility and enable their use in commercial applications requiring flame resistance. The film and sheet have excellent appearance and can be used in a wide range of decorative and packaging applications.

Claims

1. A polyester blend comprising:

(a) a polyester, wherein said polyester is a random copolymer having a crystallization half-time from a molten state of at least 5 minutes; and

(b) one or more polyester elastomers comprising;

(i) diacid residues comprising the residues of one or more substituted or unsubstituted cycloaliphatic dicarboxylic acids containing 5 to 20 carbon atoms; and

(ii) diol residues comprising the residues of one or more substituted or unsubstituted, linear or branched, diols selected from the group consisting of aliphatic diols containing 2 to 20 carbon atoms, poly(oxyalkylene)-glycols and copoly(oxyalkylene)glycols of molecular weight of about 400 to about 12000, cycloaliphatic diols containing 5 to 20 carbon atoms, and aromatic diols containing 6 to 20 carbon atoms.

2. The polyester blend according to claim 1, which further comprises a release additive in an amount effective to prevent sticking of said polyester blend to calendering rolls.

3. The polyester blend according to claim 2, wherein the release additive is selected from the group consisting of erucylamide, stearamide, calcium stearate, zinc stearate, stearic acid, montanic acid, montanic acid esters, montanic acid salts, oleic acid, palmitic acid, paraffin wax, polyethylene waxes, polypropylene waxes, carnauba wax, glycerol monostearate, and glycerol distearate.

4. The polyester blend according to claim 2, wherein the release additive comprises (i) a fatty acid or salt thereof containing more than 18 carbon atoms and (ii) an ester wax comprising a fatty acid residue containing more than 18 carbon atoms and an alcohol residue containing from 2 to about 28 carbon atoms.

5. The polyester blend according to claim 1, which further comprises one or more additives selected from the group consisting of plasticizers, flame retardants, antioxidants, antiblocking agents, fillers, colorants, and pigments.

6. The polyester blend according to claim 1, wherein the polyester further comprises one or more modifying acids selected from the group consisting of succinic acid, glutaric acid, adipic acid, suberic acid, sebacic acid, azelaic acid, dimer acid, and sulfoisophthalic acid.

7. The polyester blend according to claim 1, wherein the polyester further comprises about 0.05 to about 1 weight percent, based on the total weight of the polyester, of one or more residues of a branching monomer selected from the group consisting of trimellitic acid, trimellitic anhydride, pyromellitic dianhydride, trimethylolpropane, glycerol, pentaerythritol, citric acid, tartaric acid, 3-hydroxyglutaric acid.

8. The polyester blend according to claim 1, wherein the polyester elastomer comprises residues of at least one diacid selected from the group consisting of 1,4-cyclohexanedicarboxylic acid and 1,3-cyclohexanedicarboxylic acid.

9. The polyester blend according to claim 1, wherein the polyester elastomer comprises residues of at least one diol selected from the group consisting of ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 2-methylpropanediol, 2,2-dimethylpropanediol, 1,6-hexanediol, decanediol, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, 1,3-cyclohexanedimethanol, 1,4-cyclohexanedimethanol, poly(ethylene ether)glycol, poly(propylene ether)glycol, and poly(tetramethylene ether) glycol.

10. The polyester blend according to claim 9, wherein the polyester elastomer further comprises about 0.05 to about 1 weight percent, based on the total weight of the polyester elastomer, of one or more residues of a branching monomer selected from the group consisting of trimellitic acid, trimellitic anhydride, pyromellitic dianhydride, trimethylolpropane, glycerol, pentaerythritol, citric acid, tartaric acid, 3-hydroxyglutaric acid.

11. The polyester blend according to claim 1, wherein the polyester elastomer comprises:

(a) diacid residues comprising

(i) at least 90 mole %, based on the total moles of diacid residues, of the residues of 1,4-cyclohexanedicarboxylic acid; and

(ii) about 0.1 to about 2 mole %, based on the total diacid residues, of the residues of at least one branching agent selected from the group consisting of trimellitic acid, trimellitic anhydride, and pyromellitic dianhydride; and

(b) diol residues comprising

(i) about 2 to about 20 mole %, based on the total diol residues, of a poly(tetramethylene ether) glycol having a molecular weight of about 500-2000, and

(ii) about 98 to about 80 mole %, based on the total diol residues, of the residues of at least one diol selected from the group consisting of 1,4-cyclohexanedimethanol and 1,4-butanediol.

12. The polyester blend according to claim 1, which comprises from about 15 to about 25 weight percent of the polyester elastomer.

13. A process for making a film or sheet, comprising calendering or extruding the polyester blend according to claim 1.

14. A process for making a film or sheet, comprising calendering or extruding the polyester blend according to claim 2.

15. A film or sheet, prepared by an extrusion or calendering process, comprising the polyester blend according to claim 1.

16. A film or sheet, prepared by an extrusion or calendering process, comprising the polyester blend according to claim 2.