Electrode for fuel cell, fuel cell comprising the same, and method for preparing the same

• US 20060115711A1
• Filed: 11/28/2005
• Published: 06/01/2006
• Est. Priority Date: 11/26/2004
• Status: Abandoned Application

• Current Assignee: Samsung SDI Company Limited
• Original Assignee: Samsung SDI Company Limited
• Inventors: Kim, Hee-Tak, Lee, Jong-Ki, Kweon, Ho-Jin
• Application Number:
  US11/288,887
• Publication Number:
  US 20060115711A1
• Time in Patent Office: Days
• US Class Current: 429/434
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: H01M 2008/1095 Fuel cells with polymeric electrolytes
• CPC Class Codes: H01M 4/8605 Porous electrodes
• CPC Class Codes: H01M 4/8825 Methods for deposition of the catalytic active composition
• CPC Class Codes: H01M 4/921 Alloys or mixtures with metallic elements
• CPC Class Codes: H01M 4/926 on carbon or graphite
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

An electrode for a fuel cell of the present invention includes an electrode substrate, a microporous layer formed on the surface of the electrode substrate, and a nano-carbon layer formed on the surface of the microporous layer with a catalyst layer coated on the surface of the nano-carbon layer. Alternatively, an electrode for a fuel cell includes an electrode substrate in which carbon particles are dispersed, a nano-carbon layer on the electrode substrate, and a catalyst layer on the nano-carbon layer.

Claims

1. An electrode for a fuel cell comprising:

an electrode substrate;

a microporous layer on the electrode substrate;

a nano-carbon layer on the microporous layer; and

a catalyst layer on the nano-carbon layer.

2. The electrode for a fuel cell of claim 1, wherein the electrode substrate comprises a material selected from the group consisting of carbon paper, carbon cloth, and carbon felt.

3. The electrode for a fuel cell of claim 1, wherein the electrode substrate has a thickness between about 10 μ

m and 1000 μ

m.

4. The electrode for a fuel cell of claim 1, wherein the microporous layer has a thickness between about 1 μ

m and 100 μ

m.

5. The electrode for a fuel cell of claim 1, wherein the microporous layer comprises a material selected from the group consisting of carbon powder, graphite, fullerene (C60), carbon black, acetylene black, activated carbon, nano-carbon, carbon nanotube, carbon nanofiber, carbon nanowire, carbon nanohorn, and carbon nanoring.

6. The electrode for a fuel cell of claim 1, wherein the catalyst layer has a thickness between about 0.05 μ

m and 10 μ

m.

7. The electrode for a fuel cell of claim 1, wherein the nano-carbon of the nano-carbon layer is selected from the group consisting of carbon nanotubes (CNT), carbon nanofibers, carbon nanowires, carbon nanohorns, and carbon nanorings.

8. The electrode for a fuel cell of claim 1, wherein the nano-carbon layer is grown in a direction perpendicular to a surface of the microporous layer.

9. The electrode for a fuel cell of claim 1, wherein the nano-carbon is grown directly on a surface of the microporous layer.

10. The electrode for a fuel cell of claim 1, wherein the nano-carbon of the nano-carbon layer has a diameter between about 1 and 500 nm.

11. The electrode for a fuel cell of claim 1, wherein the catalyst layer is formed by depositing a metal catalyst on the nano-carbon of the nano-carbon layer.

12. The electrode for a fuel cell of claim 11, wherein the metal catalyst is deposited using a method selected from sputtering, physical vapor deposition (PVD), plasma enhanced chemical vapor deposition (PECVD), thermal chemical vapor deposition, electron beam evaporation, vacuum thermal evaporation, laser ablation, thermal evaporation, and combinations thereof.

13. The electrode for a fuel cell of claim 1, wherein the catalyst layer comprises a catalyst provided in an amount between about 0.001 and 0.5 mg/cm².

14. The electrode for a fuel cell of claim 13, wherein the catalyst is provided in an amount between about 0.01 and 0.05 mg/cm².

15. The electrode for a fuel cell of claim 1, wherein the catalyst layer comprises a catalyst with a specific surface area between about 10 and 500 m²/g.

16. The electrode for a fuel cell of claim 1, wherein the catalyst layer comprises a material selected from the group consisting of platinum, ruthenium, osmium, platinum-transition metal alloys, and combinations thereof.

17. The electrode for a fuel cell of claim 16, wherein the transition metal is selected from the group consisting of Ru, Os, Co, Pd, Ga, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, and combinations thereof.

18. An electrode for a fuel cell comprising:

an electrode substrate having carbon particles dispersed therein;

a nano-carbon layer on the electrode substrate; and

a catalyst layer on the nano-carbon layer.

19. The electrode for a fuel cell of claim 18, wherein the electrode substrate having the carbon particles dispersed therein function both as a dispersion layer and a backing layer and comprises a material selected from the group consisting of carbon powder, graphite, fullerene (C60), carbon black, acetylene black, activated carbon, nano-carbon, carbon nanotube, carbon nanofiber, carbon nanowire, carbon nanohorn, and carbon nanoring.

20. The electrode for a fuel cell of claim 18, wherein the nano-carbon of the nano-carbon layer is selected from the group consisting of carbon nanotubes (CNT), carbon nanofibers, carbon nanowires, carbon nanohorns, and carbon nanorings.

21. A membrane-electrode assembly for a fuel cell, comprising a polymer electrolyte membrane;

and at least two electrodes respectively positioned on both sides of the polymer electrolyte membrane, wherein each electrode comprises;

an electrode substrate,

a microporous layer on the electrode substrate;

a nano-carbon layer on the microporous layer; and

a catalyst layer on the nano-carbon layer.

22. The membrane-electrode assembly for a fuel cell of claim 21, wherein the polymer electrolyte membrane is a proton-conducting polymer selected from the group consisting of perfluoro-based polymers, benzimidazole-based polymers, polyimide-based polymers, polyetherimide-based polymers, polyphenylene sulfide-based polymers, polysulfone-based polymers, polyethersulfone-based polymers, polyetherketone-based polymers, polyether-etherketone-based polymers, and polyphenylquinoxaline-based polymers.

23. The membrane-electrode assembly for a fuel cell of claim 21, wherein the polymer electrolyte membrane is a proton-conducting polymer selected from the group consisting of poly(perfluorosulfonic acid), poly(perfluorocarboxylic acid), co-polymers of tetrafluoroethylene and fluorovinylether containing sulfonic acid groups, defluorinated polyetherketone sulfides, aryl ketones, poly(2,2′

-(m-phenylene)-5,5′

-bibenzimidazole), and poly(2,5-benzimidazole).

24. A membrane-electrode assembly for a fuel cell, comprising a polymer electrolyte membrane and at least two electrode substrates, wherein the polymer electrolyte membrane has first and second side surfaces and further comprises;

nano-carbon layers on the first and second side surfaces of the polymer electrolyte membrane; and

catalyst layers on the nano-carbon layers.

25. The membrane-electrode assembly for a fuel cell of claim 24, wherein the nano-carbon of the nano-carbon layers extend in directions perpendicular to the surfaces of the polymer electrolyte membrane.

26. The membrane-electrode assembly for a fuel cell of claim 24, wherein the nano-carbon layers are grown directly on the surfaces of the polymer electrolyte membrane.

27. The membrane-electrode assembly for a fuel cell of claim 24, wherein the polymer electrolyte membrane is a proton-conducting polymer selected from the group consisting of perfluoro-based polymers, benzimidazole-based polymers, polyimide-based polymers, polyetherimide-based polymers, polyphenylene sulfide-based polymers, polysulfone-based polymers, polyethersulfone-based polymers, polyetherketone-based polymers, polyether-etherketone-based polymers, and polyphenylquinoxaline-based polymers.

28. A fuel cell system comprising an electricity generating unit, a fuel supplying unit for supplying a fuel including hydrogen to the electricity generating unit;

and an oxidant supplying unit for supplying an oxidant to the electricity generating unit, wherein the electricity generating unit comprises a plurality of membrane electrode assemblies and separators, and each membrane electrode assembly comprises a polymer electrolyte membrane between at least two electrodes, wherein at least one of the at least two electrodes comprises;

an electrode substrate;

a microporous layer on the electrode substrate;

a nano-carbon layer on the microporous layer; and

a catalyst layer on the nano-carbon layer.

29. The fuel cell system of claim 28, wherein the polymer electrolyte membrane is a proton-conducting polymer selected from the group consisting of perfluoro-based polymers, benzimidazole-based polymers, polyimide-based polymers, polyetherimide-based polymers, polyphenylene sulfide-based polymers, polysulfone-based polymers, polyethersulfone-based polymers, polyetherketone-based polymers, polyether-etherketone-based polymers, and polyphenylquinoxaline-based polymers.

30. A fuel cell system comprising an electricity generating unit, a fuel supplying unit for supplying a fuel including hydrogen to the electricity generating unit;

and an oxidant supplying unit for supplying an oxidant to the electricity generating unit, wherein the electricity generating unit comprises a plurality of membrane electrode assemblies and separators, and each membrane electrode assembly comprises a polymer electrolyte membrane between at least two electrodes, wherein the polymer electrolyte membrane includes first and second surfaces and further comprises;

a microporous layer on at least one of the first and second surfaces;

a nano-carbon layer on the microporous layer; and

a catalyst layer on the nano-carbon layer.

31. A method of preparing an electrode for a fuel cell, the method comprising:

providing an electrode substrate;

forming a microporous layer on the electrode substrate;

providing a first catalyst for synthesizing nano-carbon on the microporous layer;

heating the first catalyst locally while exposing the first catalyst to a reactive gas including carbon to grow a nano-carbon layer on the microporous layer; and

coating a second catalyst on the nano-carbon layer.

32. The method of claim 31, wherein the electrode substrate is selected from the group consisting of carbon paper, carbon cloth, and carbon felt.

33. The method of claim 31, wherein the electrode substrate has a thickness between about 10 μ

m and 1000 μ

m.

34. The method of claim 31, wherein the microporous layer has a thickness between about 1 μ

m and 100 μ

m.

35. The method of claim 31, wherein the microporous layer comprises a material selected from the group consisting of carbon powder, graphite, fullerene (C60), carbon black, acetylene black, activated carbon, nano-carbon, carbon nanotube, carbon nanofiber, carbon nanowire, carbon nanohorn, and carbon nanoring.

36. The method of claim 31, wherein the first catalyst is selected from the group consisting of Fe, Ni, Co, Y, Pd, Pt, Au, Pd, Ga, Ti, V, Cr, Mn, Cu, Ta, W, Mo, Al, alloys thereof, and metal-containing carbides, borides, oxides, nitrides, sulfides, sulfates, and nitrates.

37. The method of claim 31, wherein the first catalyst is introduced by a method selected from electrophoresis, thermal spray method, and sputtering.

38. The method of claim 31, wherein the reactive gas is selected from the group consisting of hydrocarbon gases, carbon monoxide, and carbon dioxide.

39. The method of claim 31, wherein the local heating of the catalyst is performed by a method selected from microwave irradiation, electromagnetic induced heating, laser heating, and high frequency (RF) heating.

40. The method of claim 31, wherein the catalyst layer is formed to a thickness between 0.05 μ

m and 10 μ

m.

41. The method of claim 31, wherein the nano-carbon of the nano-carbon layer is selected from the group consisting of carbon nanotubes (CNT), carbon nanofibers, carbon nanowires, carbon nanohorns, and carbon nanorings.

42. The method of claim 31, wherein the nano-carbon of the nano-carbon layer is grown in a direction perpendicular to the microporous layer.

43. The method of claim 31, wherein the nano-carbon of the nano-carbon layer has a diameter between about 1 and 500 nm.

44. The method of claim 31, wherein the catalyst layer comprises a catalyst provided in an amount between about 0.001 and 0.5 mg/cm².

45. The method of claim 31, wherein the catalyst layer has a specific surface area between about 10 and 500 m²/g.

46. The method of claim 31, wherein the catalyst layer is formed by depositing a metal catalyst on the nano-carbon layer.

47. The method of claim 46, wherein the metal catalyst is deposited using a method selected from sputtering, physical vapor deposition (PVD), plasma enhanced chemical vapor deposition (PECVD), thermal chemical vapor deposition, electron beam evaporation, vacuum thermal evaporation, laser ablation, and thermal evaporation.

48. The method of claim 46, further comprising removing the first catalyst from the catalyst layer.

49. The method of claim 48, wherein the first catalyst is removed by acid treatment.

50. A method of preparing a polymer electrode membrane for a fuel cell comprising:

providing a polymer electrode membrane substrate;

providing a first catalyst for synthesizing nano-carbon on the polymer electrode membrane substrate;

heating the first catalyst locally while exposing the first catalyst to a reactive gas including carbon to grow a nano-carbon layer on the microporous layer; and

coating a second catalyst on the nano-carbon layer.