Separation of a substance mixture consisting of hydrogen chloride and phosgene

• US 20060123842A1
• Filed: 12/13/2003
• Published: 06/15/2006
• Est. Priority Date: 12/19/2002
• Status: Active Grant

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF Coatings GmbH (BASF SE)
• Inventors: Stroefer, Eckhard, Penzel, Ulrich, Mackenroth, Wolfgang, Deberdt, Filip, Pallasch, Hans-Jurgen, Nevejans, Filip, Jacobs, Jan D, Abeel, Peter Van Den, Sohn, Martin
• Granted Patent: US 7,584,629 B2
• Time in Patent Office: Days
• US Class Current: 62/617
• CPC Class Codes: B01D 2257/2045 Hydrochloric acid
• CPC Class Codes: B01D 2257/2064 Chlorine
• CPC Class Codes: B01D 53/002 by condensation
• CPC Class Codes: C01B 32/80 Phosgene
• CPC Class Codes: C01B 7/0712 by distillation
• CPC Class Codes: C01B 7/0731 by extraction
• CPC Class Codes: C07C 263/10 by reaction of amines with carbonyl halides, e.g. with phosgene
• CPC Class Codes: C07C 265/10 having isocyanate groups bound to carbon atoms of rings other than six-membered aromatic rings
• CPC Class Codes: C07C 265/12 having isocyanate groups bound to carbon atoms of six-membered aromatic rings
• CPC Class Codes: C07C 265/14 containing at least two isocyanate groups bound to the same carbon skeleton
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

The invention relates to a process for the partial or complete separation of a mixture comprising hydrogen chloride and phosgene, possibly solvents and possibly low boilers and inerts as are typically obtained in the preparation of isocyanates by reaction of amines with phosgene, which comprises firstly carrying out a partial or complete condensation of phosgene, then a distillation or stripping step in a column to remove the hydrogen chloride from the bottom product phosgene and subsequently a scrub of the top product hydrogen chloride by means of the process solvent to absorb the phosgene in the process solvent. An after-purification by means of adsorption on activated carbon or by another suitable method can subsequently be carried out to remove solvent residues.

Claims

1. A process for the partial or complete separation of a mixture comprising hydrogen chloride and phosgene, which comprises:

firstly carrying out a partial or complete condensation of phosgene;

then distillation or stripping step in a column to remove the hydrogen chloride from the bottom product phosgene; and

subsequently a scrub of the top product hydrogen chloride by a process solvent to absorb the phosgene in the process solvent.

2. The process as claimed in claim 1, wherein the partial or complete condensation of phosgene is carried out at from −

40°

C. to 40°

C. and pressures of from 1 to 35 bar.

3. The process as claimed in claim 1, wherein the distillation to remove hydrogen chloride from phosgene is carried out at a temperature of the bottom of from 5 to 150°

C., a pressure at the top of from 1 to 35 bar, and a temperature at the top of from −

20°

C. to 30°

C.

4. The process as claimed in claim 1, wherein the hydrogen chloride is removed from the phosgene by stripping with an inert gas.

5. The process as claimed in claim 1, wherein the absorption or scrub is carried out by the process solvent.

6. The process as claimed in claim 1, wherein the temperature at the top of the absorber is from −

40°

C. to 10°

C., the temperature at the bottom is from −

10°

C. to 30°

C., and the pressure at the top is 1-35 bar.

7. The process as claimed in claim 1, wherein an absorption medium stream for the absorption has been saturated beforehand with hydrogen chloride.

8. The process as claimed in claim 1, wherein the heat of condensation of hydrogen chloride and phosgene in an absorption medium is removed by intermediate cooling in the absorber.

9. The process as claimed in claim 1, wherein an after-purification by adsorption is carried out.

10. The process as claimed in claim 1, wherein the scrub is carried out by chlorobenzene.

11. The process as claimed in claim 1, wherein the bottom product phosgene is recirculated to the reaction section of an isocyanate synthesis.

12. A runback in distillation or reaction columns, or as a scrubbing solution for absorbers or scrubbers, comprising the bottom product phosgene as claimed in claim 1.

15. The process as claimed in claim 1, wherein the hydrogen chloride obtained is subsequently compressed.

16. The process as claimed in claim 1, wherein the hydrogen chloride obtained is subsequently added in a preparation of ethylene dichloride or a Deacon process.

17. The process as claimed in claim 1, wherein the mixture further comprises solvents, low boilers, and inert gases obtained in a preparation of isocyanates by reaction of amines with phosgene.

18. The process as claimed in claim 7, wherein a heat of condensation has been removed.

13. (canceled)

14. (canceled)