Water-based release coating containing fluorochemical
First Claim
1. A water-based release coating composition comprising water and solids, wherein the solids comprise a mixture of (A) from 0.I to about 5 wt % of a fluoto(meth)abrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —
- (CF2)nCF3, wherein n is an integer from 1 to 3;
(B) from about 5 to about 99.9 wt % of a copolymer compeg consisting of the reaction product of (a) from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, (b) from about 3 to about 20 wt % of (meth)acrylic acid, (c) from about 20 to about 40 wt % acrylcinitrile, and (d) from 0 to about 15 wt % of vinyl monomer, other than those monomers of a. through c. above; and
C. from 0 to about 94.9 wt % of an extender polymer.
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Abstract
In one aspect, the invention provides a water-based release coating composition comprising a mixture of: A. from 0.1 to about 5 wt % of a fluoro(meth)acrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —(CF2)nCF3, wherein n is an integer from 1 to 3; B. from about 5 to about 99.9 wt % of a copolymer comprising the reaction product of a. from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, b. from about 3 to about 20 wt % of (meth)acrylic acid, c. from about 20 to about 40 wt % acrylonitrile, and d. from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of a. through d. equals 100%; and C. from 0 to about 94.9 wt % of an extender polymer, wherein the sum of A., B., and C. is 100% and wt % is based on the total amount of solids in the composition.
59 Citations
28 Claims
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1. A water-based release coating composition comprising water and solids, wherein the solids comprise a mixture of
(A) from 0.I to about 5 wt % of a fluoto(meth)abrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula — - (CF2)nCF3, wherein n is an integer from 1 to 3;
(B) from about 5 to about 99.9 wt % of a copolymer compeg consisting of the reaction product of (a) from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, (b) from about 3 to about 20 wt % of (meth)acrylic acid, (c) from about 20 to about 40 wt % acrylcinitrile, and (d) from 0 to about 15 wt % of vinyl monomer, other than those monomers of a. through c. above; and
C. from 0 to about 94.9 wt % of an extender polymer. - View Dependent Claims (2, 3, 5, 6, 7, 8, 21, 22, 23, 24)
- (CF2)nCF3, wherein n is an integer from 1 to 3;
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4. The composition according to cliaim 1 wherein (A) is a fluoro(meth)acrylate (co)polymer comprising a monomer having the formula:
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9-11. -11. (canceled)
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19. (canceled)
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25. An adhesive article comprising
a backing having first and second surfaces; -
an adhesive on at least a portion of the first surface of the backing; and
a release composition on at least a portion of the second surface of the backing, wherein the release composition comprises a mixture of (A) from 0.1 to about 5 wt % of a fluoro(meth)acrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —
(CF2)CF3, wherein n is an integer from 1 to 3;
(B) from about 5 to about 99.9 wt % of a copolymer consisting of the reaction product of (a) from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, (b) from about 3 to about 20 wt % of (meth)acrylic acid, (c) from about 20 to about 40 wt % acrylonitrile, and (d) from 0 to about 15 wt % of vinyl monomer, other than those monomers of (a) through (c) above; and
(C) from 0 to about 94.9 wt % of an extender polymer. - View Dependent Claims (12, 13, 14, 15, 16, 17, 18, 20, 26, 27, 28)
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Specification