Method for the deacidification of a fluid stream by means of an inert scrubbing column and corresponding device

• US 20060156923A1
• Filed: 05/29/2004
• Published: 07/20/2006
• Est. Priority Date: 06/05/2003
• Status: Abandoned Application

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Meckl, Stefan, Asprion, Norbert
• Application Number:
  US10/559,143
• Publication Number:
  US 20060156923A1
• Time in Patent Office: Days
• US Class Current: 95/236
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/1456 Removing acid components
• CPC Class Codes: B01D 53/18 Absorbing units; Liquid distributors therefor B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32
• CPC Class Codes: B01D 53/77 Liquid phase processes

Abstract

A process for deacidifying a fluid stream containing acid gases as impurities, which comprises, in at least one absorption step at a pressure of from 0.5 to 20 bar, bringing the fluid stream into intimate contact with an absorbent with the proviso that the absorption step, and in the case of a plurality of absorption steps at least one of the absorption steps, is carried out in an inert scrubbing column, the internal surface of which essentially consists of plastic or rubber.

Claims

1. A process for deacidifying a fluid stream containing acid gases as impurities, which comprises, in at least one absorption step at a pressure of from 0.5 to 20 bar, bringing the fluid stream into intimate contact with an absorbent with the proviso that the absorption step, and in the case of a plurality of absorption steps at least one of the absorption steps, is carried out in an inert scrubbing column, the internal surface of which essentially consists of plastic or rubber.

2. A process as claimed in claim 1, wherein the fluid stream is formed in

a) the oxidation of organic substances,

b) the composting or storage of waste materials containing organic substances, or

c) the bacterial decomposition of organic substances.

3. A process as claimed in claim 2, wherein the organic substances which are subjected to oxidation are fossil fuels or waste materials containing organic substances.

4. A process as claimed in claim 2, wherein the waste materials which contain organic substances and are subjected to composting or storage are domestic refuse, plastic wastes or packaging waste.

5. A process according to claim 2, wherein the organic substances which are subjected to bacterial decomposition are stable manure, straw, liquid manure, sewage sludge or fermentation residues.

6. A process as claimed in claim 1, wherein inert scrubbing columns are used which essentially consist of glass fiber reinforced plastics selected from the group consisting of polyvinyl chloride, polyethylene, polypropylene, polyvinylidene fluoride, ethylene-chlorotrifluoroethylene copolymers, Halar, polyfluoroethylenepropylene, perfluoroalkoxy polymers, copolymers of tetrafluoroethylene and perfluorovinyl ethers, polytetrafluoroethylene.

7. A process as claimed in claim 1, wherein an inert steel scrubbing column is used the interior of which is coated with rubber.

8. A process as claimed in claim 1, wherein the absorbent is a chemical solvent selected from the group consisting of

solutions consisting primarily of aliphatic or cycloaliphatic amines having from 4 to 12 carbons, alkanolamines having from 4 to 12 carbons, cyclic amines where 1 or 2 nitrogens together with 1 or 2 alkanediyl groups form 5-, 6- or 7-membered rings, mixtures of the above solutions, aqueous solutions of the above mixtures and solutions,

aqueous solutions containing salts of amino acids

aqueous potash solutions optionally containing piperazine or methylethanolamine

aqueous NaOH solutions or milk of lime.

9. A process as claimed in claim 8, wherein, as chemical solvent, use is made of solutions consisting primarily of monoethanolamine (MEA), methylaminopropylamine (MAPA), piperazine, diethanolamine (DEA), triethanolamine (TEA), diethylethanolamine (DEEA), diisopropylamine (DIPA), aminoethoxyethanol (AEE), dimethylaminopropanol (DIMAP) and methyldiethanolamine (MDEA), mixtures of the above solutions and aqueous solutions of the above mixtures and solutions.

10. A process as claimed in claim 1, wherein the absorbent is a physical solvent selected from the group consisting of cyclotetramethylene sulfone (sulfolane) and derivatives thereof, aliphatic acid amides (acetylmorpholine, N-formylmorpholine), NMP (N-methylpyrrolidone), propylene carbonate, N-alkylated pyrrolidones and corresponding piperidones, methanol and mixtures of dialkyl ethers of polyethylene glycols.

11. A process as claimed in claim 1, wherein the scrubbing solution is a mixture of a physical solvent and a chemical solvent.

12. A process as claimed in claim 1, wherein the scrubbing solution is an aqueous solution comprising methyldiethanolamine and piperazine.

13. A process as claimed in claim 1, wherein the scrubbing liquid, after passing through the absorption step, is regenerated and then recirculated to an absorption step.

14. A process as claimed in claim 12, wherein the scrubbing liquid is regenerated by a single-stage or multistage expansion.

15. A process as claimed in claim 12, wherein the scrubbing liquid, after the expansion, is regenerated by stripping with an inert fluid, in particular nitrogen or steam.

16. A process as claimed in claim 1, wherein the absorption step is carried out in a plurality of sequential substeps and the acid-gas-containing fluid stream, in each of the substeps, is brought into contact in each case with one substream of the scrubbing solution.

17. A process as claimed in claim 1, wherein a fluid stream is used which, under standard conditions, contains less than 50 mg/m³ of sulfur dioxide.

18. An apparatus for carrying out the process as claimed in claim 1 consisting of one or more serially connected scrubbing columns which are charged with a scrubbing solution, at least one scrubbing column being an inert scrubbing column the internal surface of which consists of plastic or rubber.