Non-aqueous slurries used as thickeners and defoamers and method of using slurries in aqueous systems

• US 20060160921A1
• Filed: 04/01/2005
• Published: 07/20/2006
• Est. Priority Date: 01/20/2005
• Status: Abandoned Application

• Current Assignee: Sherwin-Williams Company
• Original Assignee: Sherwin-Williams Company
• Inventors: Sweitzer, Gerald M., Walker, Joseph K., Ragone, Pietro J., Martuch, Robert A.
• Application Number:
  US11/096,652
• Publication Number:
  US 20060160921A1
• Time in Patent Office: Days
• US Class Current: 523/122
• CPC Class Codes: C08J 2300/00 Characterised by the use of unspecified polymers
• CPC Class Codes: C08J 3/11 from solid polymers
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: C08K 5/01 Hydrocarbons C08K5/0091 takes precedence
• CPC Class Codes: C08L 1/28 Alkyl ethers
• CPC Class Codes: C08L 1/284 with hydroxylated hydrocarbon radicals
• CPC Class Codes: C09D 5/04 Thixotropic paints
• CPC Class Codes: C09D 7/43 Thickening agents

Abstract

A low VOC, HAPs free, substantially non-aqueous slurry for use as a rheology modifier in aqueous systems including but not limited to latex paints. The slurry comprises a particulate water-swelling polymer such as hydroxyethyl cellulose, mineral oil carrier liquid, a non-ionic surfactant, a particulate thickening agent, a defoamer, and optionally an amine component.

Claims

1. A slurry, adapted to modify the rheology of a latex paint composition, comprising:

(a) from about 40% to about 45%, based on the total weight of the slurry, of a particulate water-swelling polymer having a molecular weight of about 100,000 to about 20 million;

(b) from about 20% to about 30%, based on the total weight of the slurry, of a water-insoluble organic carrier vehicle which is a non-solvent for the water-swelling polymer;

(c) from about 20% to about 30% of a mineral oil based defoamer, wherein the defoamer is adapted to actively reduce foam in the latex paint composition;

(d) from about 2% to about 4%, based on the total weight of the slurry, of a non-ionic surfactant having an HLB value of about 8-12; and

(e) from about 0.15% to 0.25% based on the total weight of the slurry of a particulate thickening agent.

2. The slurry of claim 1 further comprising about 0.1% to about 2% based on the total weight of the slurry of an amine.

3. The slurry of claim 2 wherein the amine is selected from the group consisting of 2-amino-2-methyl-1-propanol, ammonium hydroxide, monoethanolamine, diethanolamine, N, N dimethylethanolamine, triethanolamine.

4. The slurry of claim 1 wherein the defoamer is selected from silicone, a fatty acid wax, or a hydrophobic particulate or mixtures thereof.

5. The slurry of claim 1 wherein the defoamer comprises mineral oil treated with hydrophobic silica.

6. The slurry of claim 1 wherein the particulate water-swelling polymer comprises hydroxyethyl cellulose.

7. The slurry of claim 1 wherein the particulate water-swelling polymer is selected from the group consisting of hydroxyethyl cellulose, carboxy methyl cellulose, hydroxylpropyl methyl cellulose, hydroxylpropyl cellulose, methylcellulose, hydroxylethyl ethylcellulose, methylethyl hydroxyethyl cellulose, ethoxylated cellulose, cellulose ether, cellulose acetate, cellulose acetate propronate, cellulose tricetate, cellulose nitrate, microcrystalline cellulose, hydroxypropyl guar, guar gum, polyacrylic polymer, carboxyvinyl polymer, hydrophobically modified polyacrylic polymer, alkali-swellable polyacrylate, polyquaternium-10, xantham gum, colodial magnesium aluminum silicate, and acrylic copolymer.

8. The slurry of claim 1 wherein the water-insoluble carrier vehicle comprises mineral oil.

9. A slurry composition comprising:

(a) from about 40% to about 45% based on the total weight of the slurry of hydroxyethyl cellulose;

(b) from about 20% to about 30% based on the total weight of the slurry of mineral oil;

(c) from about 20% to about 30% based on the total weight of the slurry of a mineral oil based defoamer;

(d) from about 0.15% to about 0.25% based on the total weight of the slurry of fumed silica; and

(e) from about 2% to about 4% based on the total weight of the slurry of a non-ionic surfactant having an HLB value of about 8 to about 10.

10. The slurry of claim 9 further comprising from about 0.1 to about 2% based on the total weight of the slurry of an amine composition.

11. A slurry composition for use in thickening a paint formulation comprising:

(a) polymer particles capable of swelling in the presence of water, wherein said polymer particles are suspended in a hydrocarbon carrier liquid, wherein the hydrocarbon carrier liquid is present in sufficient amounts to coat the polymer particles;

(b) a defoamer composition, said defoamer composition adapted to actively reduce foam when the slurry is in the paint formulation;

(c) fumed silica;

(d) a non-ionic surfactant.

12. The slurry of claim 11, wherein the polymer particles capable of swelling in the presence of water are selected from the group consisting of hydroxyethyl cellulose, carboxy methyl cellulose, hydroxylpropyl methyl cellulose, hydroxylpropyl cellulose, methylcellulose, hydroxylethyl ethylcellulose, methylethyl hydroxyethyl cellulose, ethoxylated cellulose, cellulose ether, cellulose acetate, cellulose acetate propronate, cellulose tricetate, cellulose nitrate, microcrystalline cellulose, hydroxypropyl guar, guar gum, polyacrylic polymer, carboxyvinyl polymer, hydrophobically modified polyacrylic polymer, alkali-swellable polyacrylate, polyquaternium-10, xantham gum, colodial magnesium aluminum silicate, and acrylic copolymer.

13. The slurry of claim 11, wherein the polymer particles are hydroxyethyl cellulose.

14. The slurry of claim 11, wherein the defoamer comprises mineral oil treated with hydrophobic silica.

15. A slurry composition for use in thickening an aqueous system comprising:

(a) a mixture of water-swelling polymer particles having various average molecular weights dispersed in mineral oil;

(b) a surfactant;

(c) a thickening agent;

(d) a defoamer, wherein the defoamer actively reduces foam in the aqueous system.

16. The slurry as recited in claim 15, wherein the mixture comprises a high molecular weight water-swelling polymer having a viscosity of about 2400 cP to about 300 cP in a 2% by weight solution with water.

17. The slurry as recited in claim 15, wherein the mixture comprises a low molecular weight water-swelling polymer having a viscosity of about 300 cP to about 400 cP in a 2% by weight solution with water.

18. The slurry as recited in claim 15 wherein the surfactant is a non-ionic surfactant.

19. The slurry as recited in claim 15 wherein the surfactant has an HLB value of about 8 to about 12.

20. The slurry as recited in claim 15 wherein the surfactant has an HLB value of about 8 to about 10.

21. The slurry as recited in claim 15 wherein the thickening agent comprises fumed silica.

22. The slurry as recited in claim 15 wherein the defoamer comprises hydrophobic silica dispersed in mineral oil.

23. The slurry as recited in claim 15 further comprising an amine.

24. The slurry as recited in claim 23 wherein the amine is selected from the group consisting of 2-amino-2-methyl-1-propanol, ammonium hydroxide, monoethanolamine, diethanolamine, N,N dimethylethanolamine, triethanolamine.

25. A composition adapted to modify the rheological properties of an aqueous system, upon dilution with water, the composition comprising:

(a) polymer particles which swell in the presence of water;

(b) a water-insoluble, non-oxygenated, liquid carrier which is a non-solvent for said polymer particles;

(c) a non-ionic surfactant present in sufficient amounts to allow said polymer particles to substantially disperse in the aqueous system prior to swelling;

(d) a thickening agent present in amounts sufficient to retard settling of the polymer particles in the composition; and

(e) a defoamer, wherein said defoamer is adapted to be active upon dilution of the composition with water,

wherein the polymer particles remain suspended in the liquid carrier during storage.

26. The composition of claim 25 wherein said polymer particles are selected from the group consisting of hydroxyethyl cellulose, carboxy methyl cellulose, hydroxylpropyl methyl cellulose, hydroxylpropyl cellulose, methylcellulose, hydroxylethyl ethylcellulose, methylethyl hydroxyethyl cellulose, ethoxylated cellulose, cellulose ether, cellulose acetate, cellulose acetate propronate, cellulose tricetate, cellulose nitrate, microcrystalline cellulose, hydroxypropyl guar, guar gum, polyacrylic polymer, carboxyvinyl polymer, hydrophobically modified polyacrylic polymer, alkali-swellable polyacrylate, polyquaternium-10, xantham gum, colodial magnesium aluminum silicate, and acrylic copolymer.

27. The composition of claim 25 wherein said polymer particles are hydroxyethyl cellulose.

28. The composition of claim 25 wherein the liquid carrier comprises mineral oil.

29. The composition of claim 25 wherein the defoamer comprises a mineral oil based defoamer.

30. The composition of claim 25 wherein the surfactant has an HLB value of about 8-12.

31. A composition for thickening a paint formulation, said composition comprising:

a first particulate hydroxyethyl cellulose having a first average molecular weight;

a second particulate hydroxyethyl cellulose having a second average molecular weight;

a hydrocarbon carrier liquid;

a defoamer composition, wherein said defoamer composition actively reduces foam in the paint formulation;

a surfactant; and

a thickening agent in sufficient amounts to retard stratification of the first and second particulate hydroxyethyl cellulose in the slurry.

32. A method for thickening a paint formulation, said method comprising the steps of:

preparing a first slurry comprising;

about 42% by weight of hydroxyethyl cellulose;

about 25% by weight of a paraffinic mineral oil;

about 28% to about 29% by weight of a mineral oil based defoamer;

about 4% by weight of a non-ionic surfactant; and

less than about 1% by weight of fumed silica;

preparing a second slurry comprising;

about 45% by weight of a hydroxyethyl cellulose having a higher molecular weight than the hydroxyethyl cellulose in the first slurry;

about 24% to about 25% by weight of paraffinic mineral oil;

about 26% by weight of a mineral oil based defoamer;

about 4% by weight of a non-ionic surfactant; and

less than about 1% by weight of fumed silica;

adding said first slurry and said second slurry to a paint base.

33. The method as recited in claim 32 wherein the first slurry comprises about 66% of the composition and the second slurry comprises about 34% of the total slurry weight.

34. The method as recited in claim 32 wherein the first slurry comprises 66.32% of the composition and the second slurry comprises about 33.68% of the total slurry weight.

35. The method as recited in claim 32 wherein the non-ionic surfactant has an HLB value of about 8 to about 12.

36. A method of preparing a slurry for use in thickening a paint formulation, the method comprising the steps of:

combining particulate hydroxyethyl cellulose, mineral oil, a non-ionic surfactant, fumed silica, and a mineral oil based defoamer;

mixing said hydroxyethyl cellulose, mineral oil, non-ionic surfactant, fumed silica, and defoamer under high shear conditions until a homogeneous slurry is achieved.

37. A method for thickening a paint formulation, said method comprising:

preparing at least one slurry comprising a particulate water-swelling polymer, mineral oil, a surfactant, fumed silica, and a defoamer, wherein said defoamer is adapted to actively reduce foam when the slurry is added to the paint formulation and wherein said slurry is capable of being stored without hard settling for at least seven weeks;

preparing a paint base;

adding said slurry to said paint base;

mixing said slurry and said paint base to achieve a homogeneous dispersion.

38. The method as recited in claim 37, wherein the particulate water-swelling polymer comprises hydroxyethyl cellulose.

39. The method as recited in claim 37, wherein the at least one slurry comprises two slurries.

40. The method as recited in claim 39, wherein the two slurries comprise a first slurry and a second slurry and wherein the second slurry comprises a water-swelling polymer that has a higher average molecular weight than a water-swelling polymer in the first slurry.

41. The method as recited in claim 37, wherein the surfactant is a non-ionic surfactant.

42. The method as recited in claim 41, wherein the surfactant has an HLB value of about 8 to about 12.

43. The method as recited in claim 37, wherein the defoamer comprises hydrophobic silica dispersed in mineral oil.