Apparatus and method for measuring fuel dilution of lubricant

• US 20060192122A1
• Filed: 02/28/2005
• Published: 08/31/2006
• Est. Priority Date: 02/28/2005
• Status: Abandoned Application

• Current Assignee: On-Site Analysis, Inc. (Spectro Scientific, Inc.)
• Original Assignee: On-Site Analysis, Inc. (Spectro Scientific, Inc.)
• Inventors: Chen, Yu-Min, Asher, William
• Application Number:
  US11/068,402
• Publication Number:
  US 20060192122A1
• Time in Patent Office: Days
• US Class Current: 250/339.13
• CPC Class Codes: G01N 21/0332 with temperature control control of temperature G05D23/00; cryostats F17C3/08
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 33/2888 Lubricating oil characteristics, e.g. deterioration lubricating properties G01N33/30

Abstract

An apparatus and methods for spectroscopic analysis of a petroleum product, including detecting and quantifying fuel dilution in an oil sample are disclose. The apparatus includes a sample reservoir for receiving a liquid sample of a petroleum product, a heater for heating a sample in the sample reservoir, a vapor collector for collecting vapors released by heating the liquid sample, and a spectrometer for analyzing the released vapors.

Claims

1. An apparatus for spectroscopic analysis of a petroleum product, comprising:

a sample reservoir for receiving a liquid sample of the petroleum product;

a heater for heating a sample in the sample reservoir;

a vapor collector for collecting vapors released by heating the liquid sample; and

a spectrometer for analyzing the released vapors.

2. The apparatus of claim 1, wherein the spectrometer further comprises a photodetector to detect a spectroscopic signature of at least one volatile hydrocarbon in the petroleum product.

3. The apparatus of claim 1, wherein the heater is a conductive heater and heats the sample reservoir.

4. The apparatus of claim 1, wherein the heater is a radiant heater and heats the sample via radiation.

5. The apparatus of claim 1, wherein the sample reservoir and vapor collector form a sealable chamber such that vapors released by heating of the petroleum product are captured in the vapor collector for spectroscopic analysis.

6. The apparatus of claim 1, wherein the apparatus is further adapted to receive a used motor oil sample and detect fuel contamination in the sample.

7. The apparatus of claim 1, wherein the apparatus further comprises a temperature sensor.

8. The apparatus of claim 1, wherein the apparatus further comprises at least one sensor and a controller responsive to the sensor.

9. The apparatus of claim 1, wherein the apparatus further comprises a light source and an infrared detector.

10. The apparatus of claim 1, wherein the apparatus further comprises a light source and multiple infrared detectors position to analyze vapor in the vapor collection area.

11. The apparatus of claim 10, wherein the distance between the light source and a first detector is longer than between the light source and a second detector.

12. The apparatus of claim 11, wherein the first detector detects diesel fuel vapors and the second detector detects gasoline fuel vapors.

13. The apparatus of claim 10, wherein the light source is mechanically or electrically pulsed at a stable frequency in the range of about 3 Hz to 100 Hz.

14. An apparatus for spectroscopic analysis of motor oil, comprising:

a receptacle for a disposable sample reservoir;

a heater for heating a disposable sample reservoir;

a vapor collector chamber adapted for collecting vapors released by heating a liquid sample; and

an infrared spectrometer for analyzing vapors in the vapor collector.

15. The apparatus of claim 14, including at least one disposable sample reservoir.

16. The apparatus of claim 14, wherein the spectrometer further comprises an infrared light source and an infrared detector designed to detect the spectroscopic signature of hydrocarbon vapor.

17. The apparatus of claim 16, wherein the apparatus further comprises a data processor for analyzing spectroscopic data and quantifying an amount of fuel contamination present in a motor oil sample.

18. The apparatus of claim 14, wherein the receptacle for receiving the disposable sample reservoir is adapted to slide at least partially out of the vapor collection chamber.

19. The apparatus of claim 14, wherein the vapor collection chamber includes a resealable door.

20. A method for spectroscopic analysis of motor oil, comprising:

delivering a motor oil sample containing a volatile contaminant to a sampling reservoir;

heating the sample to increase the vapor-phase concentration of the volatile contaminant; and

spectroscopically analyzing the vapor-phase.

21. The method of claim 20, wherein the petroleum sample is heated a temperature sufficient to at least partially vaporize fuel contaminants present in a motor oil sample.

22. The method of claim 20, wherein the heater heats the sample to a temperature in the range of about 55°

C. and 120°

C.

23. The method of claim 20, wherein spectroscopically analyzing the vapor-phase data includes synchronous demodulation.

24. The method of claim 20, wherein the method further comprises comparing spectroscopic data with known values for fuel contaminants.

25. The method of claim 20, wherein the method further comprises quantifying fuel contaminants present in the motor oil sample based on the spectroscopic investigation of the vapor-phase components.

26. The method of claim 20, further comprising calibrating the device using at least one known standard sample.

27. The method of claim 26, wherein the calibrating procedure comprising spectroscopically analyzing a series of oil samples doped with known amounts of gasoline or diesel fuel.

28. The method of claim 26, wherein the standard sample comprises at least one hydrocarbon with a known vapor spectrum, and the step of calibrating the device further comprises dividing the motor oil sample into at least two portions and adding the hydrocarbon to one of the portions.

29. The method of claim 28, further comprising spectroscopically analyzing the at least two portions of the sample and using the data collected from the sample containing the hydrocarbon as a reference.